Reduced salt precipitation in carbohydrate containing binder compositions

Patent metadata

Field	Value
Publication number	US-9718981-B2
Application number	US-201615195496-A
Country	US
Kind code	B2
Filing date	Jun 28, 2016
Priority date	Apr 16, 2013
Publication date	Aug 1, 2017
Grant date	Aug 1, 2017

Abstract

Methods of reducing salt precipitation from a binder composition are described. The methods may include the steps of providing an aqueous binder solution having one or more carbohydrates. They may also include adding a sequestrant for one or more multivalent ions to the aqueous binder solution. The sequestrant reduces a precipitation rate for the multivalent ions from the binder composition. The binder composition may include a polymerization catalyst. Exemplary sequestrants may include polycarboxylic acids or anhydrides. Exemplary sequestrant concentrations may range from about 2 wt. % or less of the aqueous binder solution.

First claim

What is claimed is:

1. A method of reducing salt precipitation from a binder composition, the method comprising:
providing an aqueous binder solution comprising one or more carbohydrates; and
adding a sequestrant for one or more multivalent ions to the aqueous binder solution, wherein the sequestrant reduces a precipitation rate for the multivalent ions from the binder composition, wherein the binder composition comprises a polymerization catalyst.

2. The method of claim 1 , wherein the carbohydrate comprises a reducing sugar.

3. The method of claim 2 , wherein the reducing sugar is selected from at least one of the group consisting of dextrose and fructose.

4. The method of claim 1 , wherein the carbohydrate is selected from at least one of the group consisting of starch, cellulose, and hemicellulose.

5. The method of claim 1 , wherein the sequestrant is selected from at least one of the group consisting of a polycarboxylic acid compound, a polyphosphonic acid compound, and a polyphosphoric acid compound.

6. The method of claim 5 , wherein the sequestrant comprises a polycarboxylic acid compound comprising three or more carboxylic acid groups.

7. The method of claim 6 , wherein the sequestrant comprises a polycarboxylic acid compound selected from at least one of the group consisting of ethylenediaminetetraacetic acid and citric acid.

8. The method of claim 1 , wherein the sequestrant comprises a sequestrant solution that is mixed with the aqueous binder solution.

9. The method of claim 1 , wherein the one or more multivalent ions are selected from at least one of the group consisting of calcium ions, magnesium ions, barium ions, aluminum ions, and iron ions.

10. The method of claim 1 , wherein the binder composition further comprises a crosslinking agent.

11. The method of claim 10 , wherein the crosslinking agent comprises a reaction product of a urea compound and an aldehyde-containing compound.

12. The method of claim 10 , wherein the crosslinking agent comprises a reaction product of urea and glyoxal.

13. The method of claim 12 , wherein the reaction product of the urea and the glyoxal comprises 4,5-dihydroxyimidazolidin-2-one.

14. The method of claim 1 , wherein the polymerization catalyst is selected from at least one of the group consisting of a Lewis acid, a protic acid, and a latent acid.

15. The method of claim 14 , wherein the Lewis acid is selected from at least one of the group consisting of aluminum sulfate, ferric sulfate, aluminum chloride, ferric chloride, aluminum phosphate, and ferric phosphate.

16. The method of claim 14 , wherein the protic acid is selected from at least one of the group consisting of sulfuric acid, phosphoric acid, hydrochloric acid, nitric acid, toluene sulfonic acid, methane sulfonic acid, and a carboxylic acid.

17. The method of claim 14 , wherein the latent acid comprises at least one of ammonium sulfate, ammonium hydrogen sulfate, monoammonium phosphate, diammonium phosphate, ammonium chloride, and ammonium nitrate.

18. A method of reducing salt precipitation from a binder composition, the method comprising:
providing an aqueous binder solution comprising a reducing sugar; and
adding a sequestrant for one or more multivalent ions to the aqueous binder solution, wherein the sequestrant comprises a polycarboxylic acid or anhydride, and wherein the sequestrant reduces a precipitation level for the multivalent ions from the binder composition wherein the binder composition comprises a polymerization catalyst.

19. The method of claim 18 , wherein the reducing sugar comprises dextrose.

20. The method of claim 18 , wherein the sequestrant is selected from at least one of the group consisting of ethylenediaminetetraacetic acid, citric acid, polyacrylic acid, polyphosphonic acid, and styrene maleic anhydride.

21. The method of claim 18 , wherein the binder composition further comprises a crosslinking agent comprising a reaction product of urea and glyoxal.

22. A method of reducing salt precipitation from a binder composition, the method comprising:
providing an aqueous binder solution comprising one or more carbohydrates; and
adding a sequestrant for one or more multivalent ions to the aqueous binder solution, wherein the sequestrant is added in an amount ranging from about 2 wt. % or less of the aqueous binder solution, and wherein the sequestrant reduces a precipitation level for the multivalent ions from the binder composition wherein the binder composition comprises a polymerization catalyst.

23. The method of claim 22 , wherein the sequestrant is added in an amount ranging from about 0.1 wt. % to about 2 wt. % of the aqueous binder solution.

24. The method of claim 22 , wherein the sequestrant is added in an amount ranging from about 0.2 wt. % or less of the aqueous binder solution.

25. The method of claim 22 , wherein the carbohydrate comprises a reducing sugar.

26. The method of claim 22 , wherein the sequestrant comprises ethylenediaminetetraacetic acid.

27. The method of claim 22 , wherein the sequestrant comprises polyphosphonic acid.

28. The method of claim 22 , wherein the binder composition further comprises a crosslinking agent comprising a reaction product of urea and glyoxal.

Assignees

• Johns Manville

Inventors

• Alavi Kiarash
• Miele Philip Francis
• Lester Uranchimeg
• Asrar Jawed

Classifications

• D04H1/587

  characterised by the bonding agents used · CPC title

• D04H1/643

  characterised by a combination of the chemical composition and the impregnation or treatment process or apparatus · CPC title

• C09D185/02

  containing phosphorus · CPC title

• C03C25/321

  Starch; Starch derivatives · CPC title

• C03C25/26

  Macromolecular compounds or prepolymers · CPC title