Process for the separation of an alkylene glycol

Patent metadata

Field	Value
Publication number	US-9718752-B2
Application number	US-201414893273-A
Country	US
Kind code	B2
Filing date	May 28, 2014
Priority date	May 31, 2013
Publication date	Aug 1, 2017
Grant date	Aug 1, 2017

Abstract

The invention provides a process for the recovery of an alkylene glycol from an aqueous stream comprising the alkylene glycol and the corresponding dialkylene glycol, said process comprising the steps of providing the aqueous stream comprising the alkylene glycol and the corresponding dialkylene glycol, providing a first solvent stream, combining said aqueous stream comprising the alkylene glycol and the corresponding dialkylene glycol with said first solvent stream and recovering at least a portion of the alkylene glycol by liquid-liquid extraction, wherein said solvent comprises an amine.

First claim

That which is claimed is:

1. A process for the recovery of an alkylene glycol from an aqueous stream comprising an alkylene glycol and a corresponding dialkylene glycol, said process comprising the steps of providing the aqueous stream comprising the alkylene glycol and the corresponding dialkylene glycol, providing a first solvent stream, combining said aqueous stream comprising the alkylene glycol and the corresponding dialkylene glycol with said first solvent stream and recovering at least a portion of the alkylene glycol by liquid-liquid extraction, wherein said solvent stream comprises an amine selected from the group consisting of dimethyl-cyclohexyl amine, methyl cyclohexyl amine, 1-methyl piperidine, triethylamine, tripropylamine, or a combination thereof.

2. A process according to claim 1 , wherein at least a portion of the alkylene glycol is recovered by liquid-liquid extraction by a process comprising the steps of extracting a portion of the alkylene glycol into the solvent and separating an alkylene glycol and solvent rich stream, leaving a first residual stream.

3. A process according to claim 2 , wherein dialkylene glycol is subsequently recovered from the first residual stream by a process comprising the steps of providing the first residual stream, providing a solvent stream, combining said first residual stream with said solvent stream and recovering at least a portion of the dialkylene glycol by liquid-liquid extraction, wherein said solvent stream comprises the amine.

4. A process according to claim 3 , wherein at least a portion of the dialkylene glycol is recovered by liquid-liquid extraction by a process comprising the steps of extracting a portion of the dialkylene glycol into the solvent and separating a dialkylene glycol and solvent rich stream, leaving a second residual stream.

5. A process according to claim 4 , wherein at least one higher alkylene glycol is subsequently recovered from the second residual stream by a process comprising the steps of providing the second residual stream, providing a solvent stream, combining said second residual stream with said solvent stream and recovering at least a portion of the at least one higher alkylene glycol by liquid-liquid extraction, wherein the solvent stream comprises the amine.

6. A process according to claim 5 , wherein at least a portion of the at least one higher alkylene glycol is recovered by liquid-liquid extraction by a process comprising the steps of extracting a portion of the at least one higher alkylene glycol into the solvent and separating a higher alkylene glycol or glycols and solvent rich stream, leaving a third residual stream.

7. A process according to claim 2 , wherein the alkylene glycol and solvent rich stream is then separated into an alkylene glycol rich stream and a solvent rich stream by distillation.

8. A process according to claim 7 , wherein the solvent in the solvent rich stream is separated from any water present therein by a process comprising phase separation.

9. A process according to claim 1 , wherein dialkylene glycol is recovered from the aqueous stream comprising the alkylene glycol and the corresponding dialkylene glycol alongside the alkylene glycol.

10. A process according to claim 9 , wherein at least a portion of the alkylene glycol and dialkylene glycol are recovered by liquid-liquid extraction by a process comprising the steps of extracting a portion of the alkylene glycol and dialkylene glycol into the first solvent stream and separating a glycol and solvent rich stream, leaving a first residual stream, and the glycol and solvent rich stream is subsequently subjected to at least one distillation step to separate the amine and the alkylene glycol and the dialkylene from each other.

11. A process according to claim 1 , wherein the alkylene glycol is monoethylene glycol.

12. A process according to claim 3 , wherein the dialkylene glycol is diethylene glycol.

13. A process according to claim 5 , wherein the at least one higher alkylene glycol comprises triethylene glycol.

14. A process according to claim 1 , wherein the solvent is selected from the group consisting of triethylamine, tripropylamine, or a combination thereof.

15. A process for the recovery of monoethylene glycol from an aqueous stream comprising monoethylene glycol and diethylene glycol, said process comprising:
combining the aqueous stream comprising monoethylene glycol and diethylene glycol with a first solvent stream comprising an amine selected from the group consisting of dimethyl-cyclohexyl amine, methyl cyclohexyl amine, 1-methyl piperidine, triethylamine, tripropylamine, or a combination thereof; and recovering at least a portion of the monoethylene glycol by liquid-liquid extraction.

16. A process according to claim 15 , wherein recovering at least a portion of the monoethylene glycol by liquid-liquid extraction comprises: extracting a portion of the monoethylene glycol into the first solvent stream; and separating a monoethylene glycol and solvent rich stream, leaving a first residual stream comprising diethylene glycol.

17. A process according to claim 16 , wherein diethylene glycol is subsequently recovered from the first residual stream by a process comprising: combining the first residual stream with a solvent stream comprising the amine; and recovering at least a portion of the diethylene glycol by liquid-liquid extraction.

18. A process according to claim 17 , wherein recovering at least a portion of the diethylene glycol by liquid-liquid extraction comprises: extracting a portion of the diethylene glycol into the solvent stream; and separating a diethylene glycol and solvent rich stream, leaving a second residual stream comprising at least one higher ethylene glycol.

19. A process according to claim 18 , wherein at least one higher ethylene glycol is subsequently recovered from the second residual stream by a process comprising: combining the second residual stream comprising the at least one higher ethylene glycol with a solvent stream comprising the amine; and recovering at least a portion of the at least one higher ethylene glycol by liquid-liquid extraction.

Assignees

• Shell Oil Co

Inventors

• Fischer Kai Jürgen
• Koot Wouter
• Wesenhagen Arlette
• Bastings Roel Guillaume Hubertus Leonardus

Classifications

• C07C29/80

  by distillation · CPC title

• C07C31/202

  Ethylene glycol · CPC title

• C07C29/86

  by liquid-liquid treatment · CPC title

• C07C41/38 Primary

  by liquid-liquid treatment · CPC title

• C07C43/11

  Polyethers containing —O—(C—C—O—)n units with ≤ 2 n≤ 10 · CPC title