Optimised hydrothermal carbonisation method and facility for implementing same

Patent metadata

Field	Value
Publication number	US-9718717-B2
Application number	US-201414905603-A
Country	US
Kind code	B2
Filing date	Jul 15, 2014
Priority date	Jul 18, 2013
Publication date	Aug 1, 2017
Grant date	Aug 1, 2017

Abstract

A method and facility for the hydrothermal carbonization of pasty products or waste, or sewage sludge, in a pressurized reactor heated to carbonization temperature T0. Before entering the reactor, the products undergo: pressurization, and preheating in an exchanger, by a thermal fluid flowing in a closed loop, and receiving heat from products exiting the reactor; the thermal fluid is heated in the loop by an external heat source, downstream from the exchange with the products exiting the reactor, and upstream from the preheating of the products entering the reactor, and the temperature of the product to be treated, preheated by the thermal fluid, when it enters the reactor, is between the carbonization temperature T0 and T0-100° C. The product to be treated flows in at least one tube, where in at least one location therein, liquid is injected to create a liquid ring against the inner wall, and reduce pressure drops.

First claim

The invention claimed is:

1. A process for hydrothermal carbonization of pasty products or waste, or of treatment plant sludge, in a reactor ( 3 ) under pressure and heated at a carbonization temperature T0, generally between 140° C. and 280° C., process wherein the products to be treated, before being introduced into the reactor, undergo the following steps:
pressurization,
preheating in an exchanger, with a thermal fluid that circulates in a closed loop, and that receives heat originating from the products leaving the reactor,

wherein the thermal fluid is heated in the loop by an external heat source ( 12 ), downstream of the exchange with the products leaving the reactor, and upstream of the preheating of the products entering the reactor,
the temperature of the product to be treated, preheated by the thermal fluid, on entering the reactor ( 3 ) is between the carbonization temperature T0 and T0-100° C.,
and the product to be treated flows through at least one tube ( 1 b ), including through the preheating exchanger, before entering the reactor, and at at least one location of the tube, an injection ( 20 ) of liquid is carried out in order to create a liquid ring (A) against the inner wall of the tube, and to reduce the pressure drops.

2. The process as claimed in claim 1 , wherein the liquid injection step is carried out by at least two diametrically opposed liquid injections.

3. The process as claimed in claim 2 , wherein the dryness of the products to be treated is between 15% and 30%.

4. The process as claimed in 2 , wherein the liquid injected is an acid solution.

5. The process as claimed in claim 2 , wherein the pressure in the reactor is between 20 and 35 bar.

6. The process as claimed in claim 2 , wherein the thermal fluid is oil.

7. The process as claimed in claim 1 , wherein the dryness of the products to be treated is between 15% and 30%.

8. The process as claimed in 1 , wherein the liquid injected is an acid solution.

9. The process as claimed in claim 8 , wherein the injection of acid solution is carried out at various levels of the preheating exchanger, in order to control the clogging of the exchanger.

10. The process as claimed in claim 9 , wherein the pressure drop of the exchanger is controlled, and in the event of an increase in the pressure drop, the amount of acid solution injected for the liquid ring is increased.

11. The process as claimed in claim 9 wherein the exchange coefficient of the exchanger is controlled, and in the event of a reduction in the exchange coefficient, the amount of acid solution injected for the liquid ring is increased.

12. The process as claimed in claim 1 , wherein the pressure in the reactor is between 20 and 35 bar.

13. The process as claimed in claim 1 , wherein the thermal fluid is oil.

14. A facility for hydrothermal carbonization of pasty products or waste, or of treatment plant sludge, comprising:
a reactor ( 3 ) under pressure and heated at a carbonization temperature T0, generally between 140° C. and 280° C.,
a pump ( 1 ) for pressurizing the products in a feed line ( 1 b ) of the reactor,
a heat exchanger ( 2 ) for preheating the product to be treated with a thermal fluid that circulates in a closed loop and that receives heat, in another exchanger ( 4 ), originating from the product leaving the reactor, wherein the facility further comprises a boiler ( 12 ) for heating the thermal fluid of the closed loop, downstream of the exchange with the products leaving the reactor, and upstream of the preheating of the products entering the reactor,

the thermal power supplied by the boiler to the thermal fluid is sufficient so that the temperature of the product at the inlet of the reactor is between T0 and T0-100° C., T0 being the carbonization temperature,
and the product to be treated flows through at least one tube ( 1 b ), including through the preheating exchanger ( 2 ), before entering the reactor, and at at least one location of the tube, at least one transverse branch ( 20 a ) is provided and connected to the tube for an injection ( 20 ) of liquid and to create a liquid ring (A) against the inner wall of the tube.

15. The facility as claimed in claim 14 , wherein the heat exchanger ( 2 ) between the product to be treated and the thermal fluid is a concentric tube heat exchanger, and the product to be treated flows through the inner tube, into which the liquid for forming the liquid ring is injected, the thermal fluid passing through the outer tube.

16. The facility as claimed in claim 14 wherein the reactor ( 3 ) is wall-heated by hot oil, and is baffled.

17. The facility as claimed in claim 14 wherein the reactor is stirred so as to clean the edges of the reactor by scraping.

18. The facility as claimed in claim 17 , further comprising, at the outlet of the boiler ( 12 ), a three-way valve ( 13 ) enabling the wall-heating of the reactor by the hot oil supplied by the boiler, said three-way valve enabling a temperature adjustment via mixing.

19. The facility as claimed in claim 15 wherein the reactor ( 3 ) is wall-heated by hot oil, and is baffled.

20. The facility as claimed in claim 15 wherein the reactor is stirred so as to clean the edges of the reactor by scraping.

Assignees

• Degremont
• Suez Int

Inventors

• Pardo Pierre Emmanuel
• Bourdais Jean Louis

Classifications

• C02F11/10 Primary

  by pyrolysis · CPC title

• C02F2209/03

  Pressure · CPC title

• C02F2301/066

  Overpressure, high pressure · CPC title

• C02F2303/22

  Eliminating or preventing deposits, scale removal, scale prevention (C02F1/042, C02F1/4602, C02F5/00 take precedence) · CPC title

• C02F1/66

  by neutralisation; pH adjustment (for degassing C02F1/20; using ion-exchange C02F1/42; for flocculation or precipitation of suspended impurities C02F1/52; for removing dissolved compounds C02F1/58) · CPC title