Methods and systems for treating caustic materials

Patent metadata

Field	Value
Publication number	US-9718712-B2
Application number	US-201313940705-A
Country	US
Kind code	B2
Filing date	Jul 12, 2013
Priority date	Jul 12, 2013
Publication date	Aug 1, 2017
Grant date	Aug 1, 2017

Abstract

Methods and systems for treating caustic materials are disclosed. In one exemplary embodiment, a method for treating caustic materials includes the steps of providing a first caustic solution stream including phenolic constituents and naphthenic constituents, mixing the first caustic solution stream with an acid solution, and separating phenolic acids from the first caustic solution stream. The method further includes further mixing the first caustic solution stream with additional acid solution and separating naphthenic acids from the first caustic solution stream. Still further, the method includes providing a second caustic solution stream including sulfidic constituents, mixing the first caustic solution stream with the second caustic solution stream to form a combined caustic solution stream, and oxidizing the sulfidic constituents of the combined caustic solution stream.

First claim

What is claimed is:

1. A method for treating caustic materials comprising the steps of:
providing a first caustic solution stream comprising phenolic constituents and naphthenic constituents, the first caustic solution stream having a pH greater than about 7.0;
mixing the first caustic solution stream with an acid solution to reduce the pH of the first caustic solution stream to a pH of about 3.5 to about 4.5, thereby chemically transforming the phenolic constituents of the first caustic solution stream to phenolic acids;
separating the phenolic acids from the first caustic solution stream to form a first separated caustic solution stream and a phenolic acid stream;
further mixing the first separated caustic solution stream with an additional acid solution to reduce the pH of the first caustic solution stream to a pH of about 1.5 to about 2.5, thereby chemically transforming the naphthenic constituents of the first caustic solution stream to naphthenic acids;
separating the naphthenic acids from the first separated caustic solution stream to form a naphthenic acid stream and a first remaining caustic solution stream having a pH of from about 1.5 to about 2.5;
providing a second caustic solution stream comprising sulfidic constituents, the second caustic solution stream having a pH greater than about 7.0;
mixing the first remaining caustic solution stream with the second caustic solution stream to form a combined caustic solution stream, the combined caustic solution stream having a pH that is more neutral than either the first remaining caustic solution or the second caustic solution streams individually; and
oxidizing the sulfidic constituents of the combined caustic solution stream.

2. The method of claim 1 , further comprising bypassing a portion of the first remaining caustic solution stream, subsequent to separating the phenolic acids therefrom, but prior to mixing the first remaining caustic solution stream with the second caustic solution stream.

3. The method of claim 2 , further comprising rejoining the portion of the first remaining caustic solution stream with the combined caustic solution stream subsequent to oxidizing the sulfidic constituents of the combined caustic solution stream.

4. The method of claim 1 , further comprising acidifying the combined solution stream prior to oxidizing the sulfidic constituents of the combined caustic solution stream.

5. The method of claim 4 , wherein acidifying the combined solution stream comprises mixing the combined solution stream with a carbon dioxide gas.

6. The method of claim 1 , wherein mixing the first caustic solution stream with the acid solution comprises mixing the first caustic solution stream with a mineral acid solution.

7. The method of claim 1 , wherein oxidizing the sulfidic constituents of the combined caustic solution stream comprises oxidizing the sulfidic constituents of the combined caustic solution stream at a pH of about 6.5 to about 7.5.

8. The method of claim 1 , further comprising venting the combined caustic solution stream subsequent to oxidizing the sulfidic constituents of the combined solution stream.

9. The method of claim 1 , wherein separating the phenolic acids from the first caustic solution stream comprises skimming the phenolic acids from the first caustic solution stream.

10. The method of claim 1 , wherein separating the naphthenic acids from the first separated caustic solution stream comprises skimming the naphthenic acids from the first separated caustic solution stream.

11. A method for treating caustic materials comprising the steps of:
providing a first caustic solution stream comprising phenolic constituents and naphthenic constituents from a first caustic solution source, the first caustic solution stream having a pH greater than about 10.0;
mixing the first caustic solution stream with an acid solution in an acidification unit to reduce the pH of the first caustic solution stream to a pH of about 3.5 to about 4.5, thereby chemically transforming the phenolic constituents of first caustic solution stream to phenolic acids;
separating the phenolic acids from the first caustic solution stream using a liquid/liquid separation system associated with the acidification unit to form a first separated caustic solution stream and a phenolic acid stream;
further mixing the first separated caustic solution stream with an additional acid solution in the acidification unit to reduce the pH of the first caustic solution stream to a pH of about 1.5 to about 2.5, thereby chemically transforming the naphthenic constituents of the first caustic solution stream to naphthenic acids;
separating the naphthenic acids from the first separated caustic solution stream using the liquid/liquid separation system to form a naphthenic acid stream and a first remaining caustic solution stream having a pH from about 1.5 to about 2.5;
providing a second caustic solution stream comprising sulfidic constituents from a second caustic solution source, the second caustic solution stream having a pH greater than about 10.0;
mixing the first remaining caustic solution stream with the second caustic solution stream using a mixing valve to form a combined caustic solution stream, the combined caustic solution stream having a pH that is more neutral than either the first remaining caustic solution or second caustic solution streams individually;
if the pH of the combined caustic solution stream is greater than about 7.5, acidifying the combined solution stream by injecting an acidifying gas into the combined caustic solution stream;
if the pH of the combined caustic solution stream is less than about 6.5, bypassing a portion of the first remaining caustic solution stream, subsequent to separating the phenolic acids therefrom, but prior to mixing the first remaining caustic solution stream with the second caustic solution stream;
if the pH of the combined caustic solution stream is less than about 7.5 and greater than about 6.5 the pH is not adjusted; and
oxidizing the sulfidic constituents of the combined caustic solution stream in a sulfide oxidation unit.

12. The method of claim 11 , further comprising mixing a sour water stream with the first caustic solution stream prior to mixing the first caustic solution stream with the acid solution in the acidification unit.

Assignees

• Uop Llc

Inventors

• Laricchia Luigi
• Rios Javier

Classifications

• C02F2301/043

  Treatment of partial or bypass streams · CPC title

• C02F1/725

  by catalytic oxidation · CPC title

• C02F1/66 Primary

  by neutralisation; pH adjustment (for degassing C02F1/20; using ion-exchange C02F1/42; for flocculation or precipitation of suspended impurities C02F1/52; for removing dissolved compounds C02F1/58) · CPC title

• C02F2103/365

  from petrochemical industry (e.g. refineries) · CPC title