Method for producing acid gas separation composite membrane, and acid gas separation membrane module

Patent metadata

Field	Value
Publication number	US-9718030-B2
Application number	US-201514862664-A
Country	US
Kind code	B2
Filing date	Sep 23, 2015
Priority date	Mar 29, 2013
Publication date	Aug 1, 2017
Grant date	Aug 1, 2017

Abstract

Coating a hydrogel-state coating liquid containing at least a hydrophilic compound and an acid gas carrier on one surface of a hydrophobic porous body having three-dimensional network structure formed through intersecting, coupling or branching of a plurality of fibrils, and a large number of pores formed of microscopic interstices divided by the plurality of fibrils to form a facilitated transport membrane thereon. The hydrophobic porous body has an average inter-fibril distance of 0.001 μm or more and 2 μm or less inside a plane in parallel to a surface on which the acid gas separation facilitated transport membrane is formed, an average fibril length of 0.01 μm or more and 2 μm or less inside the plane, and an average inter-fibril distance of 0.001 μm or more and 2 μm or less in a direction perpendicular to the surface.

First claim

What is claimed is:

1. A method for producing an acid gas separation composite membrane provided with, on a support having a hydrophobic porous body at least on one surface, a facilitated transport membrane containing at least a hydrophilic compound and an acid gas carrier that reacts with an acid gas inside a gas to be separated, comprising;
arranging of the hydrophobic porous body having three-dimensional network structure formed through intersecting, coupling or branching of a plurality of fibrils, and a large number of pores formed of microscopic interstices divided by the plurality of fibrils, in which,
in the three-dimensional network structure, an average inter-fibril distance inside a plane in parallel to a surface having the facilitated transport membrane of the support is 0.001 μm or more and 2 μm or less, an average fibril length inside the plane is 0.01 μm or more and 2 μm or less, and an average inter-fibril distance in a direction perpendicular to the surface is 0.001 μm or more and 2 μm or less,
preparing of a hydrogel-state coating liquid containing at least the hydrophilic compound and the acid gas carrier, and
applying of the coating liquid onto one surface of the hydrophobic porous body.

2. The method for producing the acid gas separation composite membrane according to claim 1 , wherein an average fibril diameter of the plurality of fibrils is 0.01 μm or more and 5 μm or less.

3. The method for producing the acid gas separation composite membrane according to claim 1 , wherein a contact angle between water and the one surface of the hydrophobic porous body is 100 degrees or more.

4. The method for producing the acid gas separation composite membrane according to claim 1 , wherein the hydrophobic porous body is composed of a fluorine-based resin.

5. The method for producing the acid gas separation composite membrane according to claim 4 , wherein the fluorine-based resin is polytetrafluoroethylene.

6. The method for producing the acid gas separation composite membrane according to claim 1 , wherein the coating liquid is applied onto the one surface of the hydrophobic porous body through a hydrophobic intermediate layer having gas permeability.

7. The method for producing the acid gas separation composite membrane according to claim 6 , wherein the intermediate layer is a silicone resin layer.

8. A facilitated transport type module for acid gas separation for separating a fed gas to be separated into an acid gas and a remaining gas other than the acid gas and discharge the resultant gases, comprising;
a member for fed gas flow channel through which the gas to be separated and the remaining gas are transmitted,
an acid gas separation composite membrane produced by the method for producing the acid gas separation composite membrane according to claim 1 , and
a member for transmitted gas flow channel through which the acid gas that is resulted from a reaction with the acid gas carrier and transmitted through the acid gas separation composite membrane flows.

Assignees

• Fujifilm Corp

Inventors

• Aburaya Yoshihiro

Classifications

• B01D2257/2045

  Hydrochloric acid · CPC title

• B01D67/0002 Primary

  Organic membrane manufacture · CPC title

• B01D2257/30

  Sulfur compounds · CPC title

• B01D53/228

  characterised by specific membranes · CPC title

• B01D69/12

  Composite membranes; Ultra-thin membranes · CPC title