Wellbores including carbon quantum dots, and methods of forming carbon quantum dots

Patent metadata

Field	Value
Publication number	US-9715036-B2
Application number	US-201514739629-A
Country	US
Kind code	B2
Filing date	Jun 15, 2015
Priority date	Jun 15, 2015
Publication date	Jul 25, 2017
Grant date	Jul 25, 2017

Abstract

A system for determining at least one property of at least one fluid in at least one subterranean formation comprises a fluid delivery system configured and positioned to deliver a fluid into at least one of at least one subterranean formation and a wellbore extending through the at least one subterranean formation. The system comprises a radiation source within the wellbore, the radiation source configured to generate excitation radiation, carbon quantum dots disposed in the fluid, and a detector within the wellbore, the detector configured to measure at least one fluorescence property of the carbon quantum dots. Related methods of determining a property of a wellbore and methods of forming the carbon quantum dots are also disclosed.

First claim

What is claimed is:

1. A system for determining at least one property of at least one fluid in at least one subterranean formation, the system comprising:
a fluid delivery system configured and positioned to deliver a fluid into at least one of at least one subterranean formation and a wellbore extending through the at least one subterranean formation;
a radiation source within the wellbore, the radiation source configured to generate excitation radiation;
carbon quantum dots comprising a carbon core, the carbon core exhibiting at least one fluorescence property disposed in the fluid, wherein the carbon quantum dots comprise at least:
a first group of carbon quantum dots exhibiting a first fluorescence property responsive to exposure to electromagnetic radiation from the radiation source; and
a second group of carbon quantum dots formulated to exhibit a different fluorescence property than the first fluorescence property exhibited by the first group of carbon quantum dots responsive to exposure to the electromagnetic radiation from the radiation source; and

a detector within the wellbore, the detector configured to measure the at least one fluorescence property of the carbon core of the first group of carbon quantum dots and the second group of carbon quantum dots.

2. The system of claim 1 , wherein at least one of the first group of carbon quantum dots and the second group of carbon quantum dots comprise undoped carbon quantum dots.

3. The system of claim 1 , wherein the first group of carbon quantum dots are doped with one or more of nitrogen, boron, silicon, or phosphorus and the second group of carbon quantum dots are doped with another of nitrogen, boron, silicon, or phosphorus.

4. The system of claim 1 , wherein the first group of carbon quantum dots are dispersed in a first zone of the subterranean formation and the second group of carbon quantum dots are dispersed in a second zone of the subterranean formation.

5. The system of claim 1 , wherein the first group of carbon quantum dots comprises carbon quantum dots having a different size than carbon quantum dots of the second group of carbon quantum dots.

6. The system of claim 1 , wherein the first group of carbon quantum dots are formulated to fluoresce at a wavelength of about 450 nm and the second group of carbon quantum dots are formulated to fluoresce at a wavelength of about 700 nm.

7. The system of claim 1 , wherein at least some of the carbon quantum dots include hydrophilic surfaces and at least some of the carbon quantum dots include hydrophobic surfaces.

8. A system for determining at least one property of at least one subterranean formation fluid, the system comprising:
at least one fiber optic cable within a wellbore extending through at least one subterranean formation, the at least one fiber optic cable including at least one optical fiber comprising carbon quantum dots, the carbon quantum dots comprising a carbon core exhibiting at least one fluorescence property;
a radiation source coupled to the at least one optical fiber, the radiation source configured to generate excitation radiation for transmission through the at least one optical fiber; and
a detector coupled to the at least one fiber optic cable, the detector configured to measure the at least one fluorescence property of the carbon core.

9. The system of claim 8 , wherein the carbon quantum dots are disposed within the at least one optical fiber.

10. The system of claim 8 , wherein the at least one optical fiber comprises a coating of the carbon quantum dots on at least a portion thereof.

11. The system of claim 10 , wherein the coating comprises a monolayer of the carbon quantum dots.

12. The system of claim 8 , wherein the carbon quantum dots comprise a first group of undoped carbon quantum dots and at least a second group of carbon quantum dots doped with one or more of nitrogen, boron, silicon, or phosphorus.

13. The system of claim 8 , further comprising at least another optical fiber coupled to the detector and configured to transmit emitted radiation from the carbon quantum dots to the detector.

14. The system of claim 8 , wherein the carbon quantum dots comprise one or more of nitrogen, boron, silicon, or phosphorus.

15. The system of claim 8 , wherein the detector is configured to measure at least one of an absorption spectrum, an emission spectrum, or a fluorescence intensity of the carbon quantum dots.

16. A method of forming carbon quantum dots, the method comprising:
providing an electrolyte comprising a carbon source and a source of ions to an electrochemical cell;
introducing the electrolyte between platinum electrodes of the electrochemical cell; and
applying electrical current between the platinum electrodes and forming carbon quantum dots including carbon from the carbon source.

17. The method of claim 16 , wherein providing an electrolyte comprising a carbon source comprises forming an electrolyte comprising one or more of ethanol and ethanolamine.

18. The method of claim 16 , further comprising forming the electrolyte from one or more of an amino alcohol, a boron source, or a phosphorus source.

19. The method of claim 16 , further comprising forming at least some carbon quantum dots comprising one of an amino alcohol, boron, silicon, or phosphorus and at least some carbon quantum dots comprising at least another of an amino alcohol, boron, or phosphorus.

20. The method of claim 16 , further comprising forming hydrophilic surfaces on the carbon quantum dots or forming oleophilic surfaces on the carbon quantum dots.

Assignees

• Baker Hughes Inc

Inventors

• Murugesan Sankaran
• Monteiro Othon R
• Khabashesku Valery N

Classifications

• G01N21/643

  non-biological material · CPC title

• G01N2021/6484

  Optical fibres · CPC title

• G01N21/7703

  using reagent-clad optical fibres or optical waveguides (using measurement of total internal reflection or attenuated total reflection G01N21/552; optical fibres or waveguides per se G02B) · CPC title

• C25B1/00 Primary

  Electrolytic production of inorganic compounds or non-metals · CPC title

• G01V8/16 Primary

  using optical fibres · CPC title