Process for the conversion of low polymer wax to paraffin wax, microcrystalline wax, lube and grease base stocks using organic peroxides or hydroperoxides and metal oxides

Patent metadata

Field	Value
Publication number	US-9714385-B2
Application number	US-201514974906-A
Country	US
Kind code	B2
Filing date	Dec 18, 2015
Priority date	Jan 7, 2015
Publication date	Jul 25, 2017
Grant date	Jul 25, 2017

Abstract

The present invention relates to a process for the conversion of a low molecular weight polymeric byproduct obtained during production of high density polyethylene (HDPE), commonly known as low polymer wax (LPW) or polymer mud, into different products like different grades of paraffin wax, microcrystalline wax, lube and grease base stocks by a process comprising of thermal treatment in an inert atmosphere in the presence of organic peroxides or hydroperoxides and metal oxides. The end product depends upon the suitable selection of various process parameters like type of peroxides or hydroperoxides, metal oxides, temperature and duration of reaction.

First claim

We claim:

1. A process for the conversion of low polymer wax (LPW) to paraffin and microcrystalline waxes, lube and grease base stocks using organic peroxides or hydroperoxides and metal oxides comprising the steps of:
a) charging low polymer wax in the form of flakes or granules in a feed to volume of reactor ratio in the range of 300-750 grams/liter together with copper strips with the ratio of LPW to copper strips in a ratio in the range of 1.25:1 to 1.5:1 on weight basis in a reactor along with additives organic peroxide or hydroperoxide having a half life greater than 5 minutes at 100° C. in the range of 0.5 to 10 weight percent of feed together with transition metal oxide in the range 2 to 10 weight percent of feed to allow liquid phase free radical degradation of low polymer wax in the temperature range of 300-450° C. in an inert atmosphere;
b) maintaining the temperature for a period of 4-20 hours;
c) completing reaction and allowing reactor to cool to 90-100° C.; and
d) extracting degraded products from the reactor by a method sufficient obtain paraffin wax or microcrystalline wax or lube base stock or grease base stock.

2. A process as claimed in claim 1 , wherein low polymer wax is a low molecular weight polymeric by product of a HDPE plant having molecular weight in the range of 2000-50,000.

3. A process as claimed in 1 , wherein organic peroxides or hydroperoxides are selected from the group consisting of dicumyl peroxide, t-butyl-peroxy benzoxide, benzoyl peroxide, lauroyl peroxide, di-isobutyl peroxide, di-tert-butyl-peroxide, t-butyl-cumyl-peroxide, t-butyl-hydroperoxide, and t-amyl-hydroperoxide.

4. A process as claimed in claim 1 , wherein transition metal oxide is selected from the group consisting of ZnO, CuO, Al 2 O 3 , MoO, TiO 2 , MgO, and CaO.

5. A process as claimed in claim 1 , wherein a microcrystalline wax is formed when, the additive is an organic peroxide or hydroperoxide selected from butyl peroxide or benzoyl peroxide having a half life of 5 minutes to 1 hour at 100° C. and the metal oxide is MgO or CaO, the temperature is 350-400° C., the duration of reaction is 4-6 hours, and the feed to volume of reactor ratio is 500-750 grams/liter.

6. A process as claimed in claim 1 , wherein a paraffin wax is formed when, the additive is organic peroxide or hydroperoxide selected from lauroyl peroxide or dicumyl peroxide having a half life of more than 1 hour at 100° C. and the metal oxide is TiO 2 or ZnO, the temperature is 350-450° C., the reaction duration is 4-6 hours, and the feed to volume of reactor ratio is 300-500 grams/liter.

7. A process as claimed in claim 1 , wherein a base oil/grease base stock is formed when the additive is organic peroxide or hydroperoxide selected from lauroyl peroxide or dicumyl peroxide having a half life of more than 1 hour at 100° C. and the metal oxide is TiO 2 or ZnO, the temperature is 400-450° C., the duration is 4-8 hours, and the feed to volume of reactor ratio of 300-500 grams/liter.

8. A process as claimed in claim 1 , wherein 100% conversion of low polymer wax is obtained resulting into 60-85% paraffin waxes or microcrystalline wax or base oils or grease base stocks.

9. A process as claimed in claim 1 , wherein 5-10% of LPW is converted to hydrocarbon gases which is used as fuel and 10-30% of LPW to lower molecular weight liquid hydrocarbon which is used as fuel oil or further reformed to obtain various value added products.

Assignees

• Council Scient Ind Res
• Gail (India) Ltd

Inventors

• Khan Hayat Ullah
• Sahai Manisha
• Kumar Sanat
• Kumar Ajay
• Thakre Gananath Doulat
• Kaul Savita
• Nanoti Shrikant Madhusudan
• Shukla Bal Mukand
• Garg Madhukar Onkarnath
• Thrissokaran Paulose Anthony
• Chaturvedi Ajit Kumar

Classifications

• C10N2050/10

  semi-solid; greasy · CPC title

• C10G1/10 Primary

  from rubber or rubber waste · CPC title

• C10L3/00

  Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas · CPC title

• C10M2205/163

  used as base material · CPC title

• C10M107/02

  Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation · CPC title