Method for producing rubber wet masterbatch, rubber wet masterbatch, and rubber composition including rubber wet masterbatch

Patent metadata

Field	Value
Publication number	US-9714325-B2
Application number	US-201214350309-A
Country	US
Kind code	B2
Filing date	Sep 18, 2012
Priority date	Jan 19, 2012
Publication date	Jul 25, 2017
Grant date	Jul 25, 2017

Abstract

A method for producing a rubber wet masterbatch includes a solidifying step of mixing a slurry solution containing a filler and a dispersing solvent with a rubber latex solution, and solidifying the resultant mixture to produce a filler-containing rubber solidified product, a dehydrating step of using a first uniaxial extruder to dehydrate the filler-containing rubber solidified product while the solidified product is heated into the range of 100 to 180° C., thereby producing a rubber wet masterbatch, and a drying plasticizing step of using a second uniaxial extruder to plasticize the rubber wet masterbatch while the masterbatch is heated into the range of 120 to 180 C, thereby producing the rubber wet masterbatch further decreased in water content by percentage. The method does not have cooling step between the dehydrating step and the drying plasticizing step.

First claim

The invention claimed is:

1. A method for producing a rubber wet masterbatch obtained by use of at least a filler, a dispersing solvent, and a rubber latex solution as raw materials,
comprising a solidifying step of mixing a slurry solution containing the filler and the dispersing solvent with the rubber latex solution, and solidifying the resultant mixture to produce a filler-containing rubber solidified product,
a dehydrating step of using a first uniaxial extruder to dehydrate the filler-containing rubber solidified product while the solidified product is heated into the range of 100 to 180° C., thereby producing a rubber wet masterbatch, and
a drying plasticizing step of using a second uniaxial extruder to plasticize the rubber wet masterbatch while the rubber wet masterbatch is heated into the range of 120 to 180° C., thereby producing the rubber wet masterbatch further decreased in water content by percentage,
the method having no cooling step between the dehydrating step and the drying plasticizing step,
wherein in the drying plasticizing step, a mechanical energy of 70 Wh/kg or less is applied to the rubber wet masterbatch inside the second uniaxial extruder.

2. The method for producing the rubber wet masterbatch according to claim 1 , wherein the water content by percentage of the rubber wet masterbatch obtained through the dehydrating step is from 1 to 10%.

3. The method for producing the rubber wet masterbatch according to claim 1 , wherein the water content by percentage of the rubber wet masterbatch obtained through the drying plasticizing step is 0.9% or less.

4. The method for producing the rubber wet masterbatch according to claim 1 , wherein the first uniaxial extruder and the second uniaxial extruder are connected to each other.

5. The method for producing the rubber wet masterbatch according to claim 1 , wherein when the rubber wet masterbatch is plasticized in the drying plasticizing step, an anti-aging agent is added and blended thereinto.

6. The method for producing the rubber wet masterbatch according to claim 1 , comprising, after the drying plasticizing step, a shaping plasticizing step of using a mixer further to plasticize the rubber wet masterbatch.

7. The method for producing the rubber wet masterbatch according to claim 6 , wherein in the shaping plasticize step, a mechanical energy of 70 W/kg or less is applied to the rubber wet masterbatch inside the mixer.

8. The method for producing the rubber wet masterbatch according to claim 6 , wherein the mixer is an open roll or a uniaxial extruder.

9. The method for producing the rubber wet masterbatch according to claim 1 , wherein the solidifying step comprises step (I) of adding, when the filler is dispersed into the dispersing solvent, at least one portion of the rubber latex solution thereto, thereby producing the slurry solution that is a slurry solution containing the filler to which rubber latex particles adhere,
step (II) of mixing the slurry solution with the rest of the rubber latex solution, thereby producing the rubber latex solution containing the rubber-latex-particle-adhering filler, and
step (III) of solidifying the rubber latex solution containing the rubber-latex-particle-adhering filler to produce the filler-containing rubber solidified product.

10. The method for producing the rubber wet masterbatch according to claim 9 , wherein when the filler is dispersed in the dispersing solvent in step (I) of producing the slurry solution, an anti-aging agent is added and blended thereinto.

Assignees

• Toyo Tire & Rubber Co

Inventors

• Miyasaka Takashi

Classifications

• C08K3/013

  Fillers, pigments or reinforcing additives · CPC title

• C08J2321/02

  Latex · CPC title

• C08J3/22 Primary

  using masterbatch techniques · CPC title

• C08J3/2053

  the additives only being premixed with a liquid phase · CPC title

• C08L21/02

  Latex · CPC title