Polymer containing silane groups

Patent metadata

Field	Value
Publication number	US-9714316-B2
Application number	US-201314402939-A
Country	US
Kind code	B2
Filing date	May 22, 2013
Priority date	May 23, 2012
Publication date	Jul 25, 2017
Grant date	Jul 25, 2017

Abstract

The invention relates to low-viscosity polymers containing silane groups, the polymers curing rapidly under the effect of moisture to form an elastic material with good heat resistance and being in particular suitable for elastic adhesives and sealants. The polymers containing silane groups are based on special hydoxysilanes which carry a secondary OH group. They are in particular obtained by reacting epoxysilanes with secondary amines.

First claim

The invention claimed is:

1. A polymer with end groups of formula (I), which is free of isocyanate groups,

wherein
R 1 and R 2
either individually each represents an alkyl radical having 1 to 12 C atoms, which optionally comprises heteroatoms in the form of ether oxygen, thioether sulfur or tertiary amine nitrogen,
or together stand for an alkylene radical having 2 to 12 C atoms, which optionally comprises heteroatoms in the form of ether oxygen, thioether sulfur or tertiary amine nitrogen;

R 3 represents a linear or a branched alkylene or cycloalkylene radical having 1 to 12 C atoms, optionally with aromatic portions, and optionally with one or more heteroatoms;
R 4 represents an alkyl group having 1 to 6 C atoms;
R 5 represents an alkyl group having 1 to 10 C atoms, which optionally comprises one or more ether oxygens; and
x is 0 or 1; wherein the polymer comprises polyoxyalkylene units.

2. The polymer according to claim 1 , wherein R 1 and R 2 either individually each represents an alkyl radical having 3 to 10 C atoms, which optionally comprises one or two ether oxygens, or together represent an alkylene radical having 4 to 8 C atoms, which optionally comprises a heteroatom in the form of ether oxygen or thioether sulfur, and thereby, including the nitrogen atom, form a 5- or 6- or 7 ring.

3. The polymer according to claim 1 , wherein R 3 represents a linear or branched alkylene radical having 1 to 6 C atoms.

4. The polymer according to claim 1 , wherein x is 0.

5. The polymer according to claim 1 , wherein the polymer has a number average molecular weight(M n ), as determined by GPC using polystyrene as a standard, in the range from 1,000 to 30,000 g/mol.

6. The polymer according to claim 1 , wherein the end groups of formula (I) are bound to cycloaliphatic radicals.

7. The polymer according to claim 1 , wherein the polymer has 1 to 4 end groups of formula (I).

8. A crosslinked plastic obtained by the reaction of at least one polymer according to claim 1 with moisture.

9. A process for producing a polymer according to claim 1 , wherein at least one hydroxysilane of formula (II) is reacted with at least one polyurethane polymer containing isocyanate groups,

wherein
R 1 and R 2
either individually each represents an alkyl radical having 1 to 12 C atoms, which optionally comprises heteroatoms in the form of ether oxygen, thioether sulfur or tertiary amine nitrogen;
or they together represent an alkylene radical having 2 to 12 C atoms, which optionally comprises heteroatoms in the form of ether oxygen, thioether sulfur or tertiary amine nitrogen;

R 3 represents a linear or a branched alkylene or cycloalkylene radical having 1 to 12 C atoms, optionally with aromatic portions, and optionally with one or more heteroatoms;
R 4 represents an alkyl group having 1 to 6 C atoms;
R 5 represents an alkyl group having 1 to 10 C atoms, which optionally comprises one or more ether oxygens; and
x is 0 or 1.

10. An isocyanatosilane of formula (III),

wherein
R 1 and R 2
either individually each represents an alkyl radical having 1 to 12 C atoms, which optionally comprises heteroatoms in the form of ether oxygen, thioether sulfur or tertiary amine nitrogen,
or together they represent an alkylene radical having 2 to 12 C atoms, which optionally comprises heteroatoms in the form of ether oxygen, thioether sulfur or tertiary amine nitrogen;

R 3 represents a linear or branched alkylene or cycloalkylene radical having 1 to 12 C atoms, optionally with aromatic portions, and optionally with one or more heteroatoms;
R 4 represents an alkyl group having 1 to 6 C atoms;
R 5 represents an alkyl group having 1 to 10 C atoms, which optionally comprises one or more ether oxygens;
R 6 represents a divalent hydrocarbon radical having 4 to 16 C atoms; and
x is 0 or 1.

11. A moisture-curing composition containing at least one polymer according to claim 1 and at least one additional component.

12. A method comprising: applying the moisture-curing composition according to claim 11 as elastic adhesive and/or elastic sealant.

13. A cured composition obtained from the curing of the composition according to claim 11 with moisture.

Assignees

• Sika Tech Ag

Inventors

• Kramer Andreas
• Burckhardt Urs

Classifications

• C08G18/4866 Primary

  having a low unsaturation value · CPC title

• C08G18/6692

  with compounds of group C08G18/34 · CPC title

• C07F7/1836

  Chemistry & Metallurgy · mapped topic

• C08G18/837 Primary

  by silicon containing compounds · CPC title

• C07F7/1804

  Compounds having Si-O-C linkages (Si-O-acyl linkages C07F7/1896) · CPC title