Exhaust gas purification catalyst and exhaust gas purification catalyst structure

Patent metadata

Field	Value
Publication number	US-9713805-B2
Application number	US-201415035576-A
Country	US
Kind code	B2
Filing date	Nov 10, 2014
Priority date	Dec 4, 2013
Publication date	Jul 25, 2017
Grant date	Jul 25, 2017

Abstract

A catalyst for exhaust gas purification includes a carrier and a platinum group element supported on the carrier. The carrier includes a modified aluminum borate which contains an aluminum borate and at least one of oxides of an element selected from the group consisting of Zr, Si, Fe, and Ti. The modified aluminum borate contains the oxide in a concentration of 0.06% to 18% by mass relative to the mass of the modified aluminum borate.

First claim

The invention claimed is:

1. A catalyst for exhaust gas purification comprising a carrier and a platinum group element supported on the carrier,
the carrier comprising a modified aluminum borate which contains aluminum borate and at least one oxide of an element selected from the group consisting of Zr, Si, Fe, and Ti, and
the modified aluminum borate containing the oxide in a concentration of 0.06% to 18% by mass relative to the mass of the modified aluminum borate.

2. The catalyst for exhaust gas purification according to claim 1 , wherein the platinum group element supported on the carrier is at least one of Pd, Pt, Rh, and Ru.

3. A catalyst structure for exhaust gas purification comprising: a catalyst support made of a ceramics or a metallic material; and a layer of the catalyst for exhaust gas purification according to claim 2 supported on the catalyst support.

4. A catalyst structure for exhaust gas purification comprising: a catalyst support made of a ceramics or a metallic material; and a layer of the catalyst for exhaust gas purification according to claim 1 supported on the catalyst support.

5. The catalyst structure for exhaust gas purification according to claim 4 , wherein the platinum group element supported on the carrier comprises Pd.

6. The catalyst structure for exhaust gas purification according to claim 5 , further comprising a second catalyst layer that comprises Rh overlying said layer comprising Pd.

7. The catalyst structure for exhaust gas purification according to claim 4 , wherein the modified aluminum borate has a cage structure.

8. The catalyst structure for exhaust gas purification according to claim 4 , wherein the modified aluminum borate is in the form of particles having a log differential pore volume distribution peak in a pore volume diameter range of from 20 nm to 100 nm in a pore size distribution measured with a mercury porosimeter.

9. The catalyst structure for exhaust gas purification according to claim 8 , wherein said pore volume diameter range is from 25 nm to 70 nm.

10. The catalyst structure for exhaust gas purification according to claim 4 , wherein the modified aluminum borate contains the oxide in a concentration of 0.10% to 10% by mass relative to the mass of the modified aluminum borate.

11. The catalyst structure for exhaust gas purification according to claim 4 , wherein the platinum group element is present in an amount of 0.1% to 5% by mass relative to the mass of the carrier.

12. The catalyst structure for exhaust gas purification according to claim 4 , wherein the platinum group element is present in an amount of 0.2% to 4% by mass relative to the mass of the carrier.

13. The catalyst for exhaust gas purification according to claim 1 , wherein the platinum group element supported on the carrier comprises Pd.

14. The catalyst for exhaust gas purification according to claim 1 , wherein the modified aluminum borate has a cage structure.

15. The catalyst for exhaust gas purification according to claim 1 , wherein the modified aluminum borate is in the form of particles having a log differential pore volume distribution peak in a pore volume diameter range of from 20 nm to 100 nm in a pore size distribution measured with a mercury porosimeter.

16. The catalyst for exhaust gas purification according to claim 15 , wherein said pore volume diameter range is from 25 nm to 70 nm.

17. The catalyst for exhaust gas purification according to claim 1 , wherein the modified aluminum borate contains the oxide in a concentration of 0.10% to 10% by mass relative to the mass of the modified aluminum borate.

18. The catalyst for exhaust gas purification according to claim 1 , wherein the platinum group element is present in an amount of 0.1% to 5% by mass relative to the mass of the carrier.

19. The catalyst for exhaust gas purification according to claim 1 , wherein the platinum group element is present in an amount of 0.2% to 4% by mass relative to the mass of the carrier.

Assignees

• Mitsui Mining & Smelting Co
• Univ Kumamoto

Inventors

• Nagao Yuki
• Iwakura Hironori
• Inoue Michiyo
• Nakahara Yunosuke
• Machida Masato

Classifications

• B01J2523/824

  Palladium · CPC title

• B01D2255/20707

  Titanium · CPC title

• B01J23/8906

  Iron and noble metals · CPC title

• B01D2255/1026

  Ruthenium · CPC title

• B01J37/0248

  Coatings comprising impregnated particles · CPC title