Golf ball with excellent interlayer adhesion between adjacent differing layers

Patent metadata

Field	Value
Publication number	US-9713748-B2
Application number	US-201514943314-A
Country	US
Kind code	B2
Filing date	Nov 17, 2015
Priority date	Nov 17, 2015
Publication date	Jul 25, 2017
Grant date	Jul 25, 2017

Abstract

Golf ball and method for making it, comprising a first layer that comprises a first polymeric composition and is surrounded by and adjacent to a second layer comprising a second polymeric composition different than the first polymeric composition; with one of these layers further comprising at least one silane-containing adhesion promoter such as organosilanes and/or organosiloxanes throughout in an amount of from about 0.1 wt. % to about 5.0 wt. % of the entire layer. Neither layer is surface treated with at least one silane-containing adhesion promoter. The second layer may be the layer comprising the silane-containing adhesion promoter throughout, surrounded by a third layer that comprises a third polymeric composition that differs from the second polymeric composition and does not incorporate any silane-containing adhesion promoter. Strong interlayer bonding is therefore created both between the second layer and the first layer and between the second layer and the third layer.

First claim

What is claimed is:

1. A golf ball comprising a first layer that comprises an ionomer composition and is surrounded by and adjacent to a second layer comprising a thermoset polyurethane composition;
wherein only the second layer further comprises at least one silane-containing adhesion promoter throughout and in an amount of from about 0.1 wt. % to about 5.0 wt. %; and
wherein the first layer and the second layer are not surface treated with any adhesion promoter at an interface between the first layer and second layer.

2. The golf ball of claim 1 , wherein the at least one silane-containing adhesion promoter is selected from the group consisting of organosilanes and organosiloxanes.

3. The golf ball of claim 1 , wherein the at least one silane-containing adhesion promoter is mixed with a prepolymer of the thermoset polyurethane composition to form a silane-containing prepolymer that is mixed with a curative.

4. The golf ball of claim 1 , wherein the at least one silane-containing adhesion promoter is mixed with a curative of the thermoset polyurethane composition to form a silane-containing curative that is mixed with a prepolymer.

5. The golf ball of claim 1 , wherein the second layer comprises a silane-containing master batch and the thermoset polyurethane composition.

6. The golf ball of claim 1 , wherein the composition is combined with the at least one silane-containing adhesion promoter by adding it to at least one pellet comprising the thermoset polyurethane composition.

7. The golf ball of claim 6 , wherein the at least one pellet is soaked or dipped in a solution comprising the at least one silane-containing adhesion promoter.

8. The golf ball of claim 1 , wherein the at least one silane-containing adhesion promoter is mixed with the thermoset polyurethane composition by compounding.

9. The golf ball of claim 1 , wherein the first layer is at least one of opaque, transparent and translucent and the second layer is at least one of transparent and translucent.

10. The golf ball of claim 1 , wherein the first layer surrounds a core comprising polybutadiene.

11. The golf ball of claim 1 , wherein the at least one silane-containing adhesion promoter has at least two functional groups.

12. The golf ball of claim 1 , wherein the second layer comprising the at least one silane-containing adhesion promoter is surrounded by and adjacent to a third layer that consists of a polymeric composition that is not surface treated with nor comprised of at least one silane-containing adhesion promoter.

13. A method of making a golf ball comprising
providing a first layer comprising an ionomer composition;
forming a second layer about and adjacent to the first layer wherein the second layer comprises a thermoset polyurethane composition;
wherein only the second layer further comprises at least one silane-containing adhesion promoter throughout in an amount of from about 0.1 wt. % to about 5.0 wt. %; and
wherein the first layer and the second layer are not surface treated with any adhesion promoter at an interface between the first layer and second layer.

14. The method of making a golf ball of claim 13 , wherein the at least one silane-containing adhesion promoter is selected from the group consisting of organosilanes and organosiloxanes.

15. The method of making a golf ball of claim 13 , wherein the at least one silane-containing adhesion promoter is mixed with a prepolymer of the thermoset polyurethane composition to form a silane-containing prepolymer that is then mixed with a curative.

16. The method of making a golf ball of claim 13 , wherein the at least one silane-containing adhesion promoter is mixed with a curative of the thermoset polyurethane composition to form a silane-containing curative that is then mixed with a prepolymer.

17. The method of making a golf ball of claim 13 , wherein the second layer is formed from a master batch comprising the at least one silane-containing adhesion promoter and the thermoset polyurethane composition.

18. The method of making a golf ball of claim 13 , wherein the thermoset polyurethane composition is combined with the silane-containing adhesion promoter by adding the silane-containing adhesion promoter to at least one pellet comprised of the composition thermoset polyurethane.

19. The method of making a golf ball of claim 18 , wherein the at least one pellet is soaked or dipped in a solution comprising the silane-containing adhesion promoter.

20. The method of making a golf ball of claim 13 , wherein the at least one silane-containing adhesion promoter is mixed with the thermoset polyurethane composition by compounding.

21. The method of making a golf ball of claim 13 , wherein the second layer comprising the at least one silane-containing adhesion promoter is surrounded by and adjacent to a third layer that consists of a third polymeric composition different than the thermoset polyurethane composition and is not surface treated with nor comprises at least one silane-containing adhesion promoter.

22. The method of making a golf ball of claim 13 , wherein the first layer and the second layer are formed by a molding process selected from the group consisting of compression molding; injection molding; and casting.

Assignees

• Acushnet Co

Inventors

• Binette Mark L
• Comeau Brian
• Michalewich Michael
• Ricci Shawn

Classifications

• B29C67/246

  Moulding high reactive monomers or prepolymers, e.g. by reaction injection moulding [RIM], liquid injection moulding [LIM] (casting monomers B29C39/006, mixing construction B29B7/74) · CPC title

• B29L2031/546

  Golf balls · CPC title

• B29K2105/0005

  containing compounding ingredients (releasing, lubricating or separating agents B29C33/56, fibers B29K2105/08, B29K2105/12; fillers B29K2105/16, recycled material B29K2105/26) · CPC title

• C08L83/00

  Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers · CPC title

• B29K2075/00

  Use of {PU, i.e.} polyureas or polyurethanes {or derivatives thereof}, as moulding material · CPC title