Low equivalent weight polymers

Patent metadata

Field	Value
Publication number	US-9711816-B2
Application number	US-201214234464-A
Country	US
Kind code	B2
Filing date	Jul 27, 2012
Priority date	Aug 4, 2011
Publication date	Jul 18, 2017
Grant date	Jul 18, 2017

Abstract

Described herein is a composition comprising: a polymer derived from (a) a fluorinated olefin monomer; (b) a highly fluorinated sulfur-containing monomer of the formula: CX 1 X 2 ═CX 3 [(CX 4 X 5 ) w —O—R 1 —SO 2 Y] where X 1 , X 2 , X 3 , X 4 , and X 5 are independently selected from H, Cl, or F; w is 0 or 1; R 1 is a non-fluorinated or fluorinated alkylene group; and Y is selected from F, Cl, Br, I, or OM, where M is a cation; and (c) a polyfunctional monomer comprising at least two functional groups, wherein the functional groups are selected from the group consisting of: (i) a fluorovinyl ether group, (ii) a fluoroallyl ether group, (iii) a fluorinated olefinic group, and (iv) combinations thereof; articles thereof; and a method of making such polymers.

First claim

What is claimed is:

1. A composition comprising: a polymer derived from
(a) a fluorinated olefin monomer;
(b) a highly fluorinated or perfluorinated sulfur-containing monomer of the formula:
CX 1 X 2 ═CX 3 [(CX 4 X 5 ) w —O—R 1 —SO 2 Y]

where each X 1 , X 2 , X 3 , X 4 , and X 5 is independently selected from H, Cl, or F; w is 0 or 1; R 1 is a fluorinated divalent carbon-containing group, optionally comprising oxygen atoms; and Y is selected from F, Cl, Br, I, or OM, where M is a cation, wherein highly fluorinated refers to a compound wherein at least 75% of the C—H bonds are replaced by C—F bonds and perfluorinated refers to a compound wherein all C—H bonds are replaced by C—F bonds; and
(c) a polyfunctional monomer comprising at least two functional groups, wherein the at least two functional groups are selected from: (i) at least two fluorovinyl ether groups, (ii) at least two fluoroallyl ether groups, (iii) a fluorovinyl group and a fluorinated olefinic group, (iv) a fluoroallyl ether group and a fluorinated olefinic group, (v) a fluorovinyl ether group and a fluoroallyl ether group, and (vi) combinations thereof.

2. The composition of claim 1 , wherein the highly fluorinated or perfluorinated sulfur-containing monomer is selected from the group consisting of: CF 2 ═CF—O—(CF 2 ) z —SO 2 F; CF 2 ═CFCF 2 —O—(CF 2 ) z —SO 2 F; CF 2 ═CF—O—CF 2 CF(CF 3 )—O—(CF 2 ) z —SO 2 F; and CF 2 ═CFCF 2 —O—CF(CF 3 )CF 2 —O—(CF 2 ) z —SO 2 F, and hydrolyzed versions thereof, wherein z is 1-10.

3. The composition of claim 1 , wherein the polyfunctional monomer is a perfluorodivinyl alkylether, optionally selected from the group consisting of: CF 2 ═CF—O—(CF 2 ) b —O—CF═CF 2 ; CF 2 ═CFCF 2 —O—(CF 2 ) b —O—CF 2 CF═CF 2 ; CF 2 ═CF—CF 2 —O—(CF 2 ) b —O—CF═CF 2 ; and CF 2 ═CF—(CF 2 ) m —O—R—O—(CF 2 ) e —CF═CF 2 , where b is 2-10, m is 0-2, e is 0-2, and R is an aryl or fluorinated aryl.

4. The composition of claim 1 , wherein the polyfunctional monomer is a perfluorodiallyl alkylether, optionally selected from
CF 2 ═CF—(CF 2 ) z —O—[CF(CF 3 )CF 2 —O] a (CF 2 ) b —[(CF 2 ) c —O] d —[CF(CF 3 )CF 2 —O] a —(CF 2 ) e CF═CF 2

where z is 0-5; a is 0-5; b is 0-5; c is 0-5; d is 0-5, and e is 0-5; and wherein a+b+c+d≧1.

5. The composition of claim 1 , wherein the composition has an equivalent weight of less than 700.

6. The composition of claim 1 , wherein the highly fluorinated or perfluorinated sulfur-containing monomer is:
CF 2 ═CF—(CF 2 ) m —O—[CF(CF 3 )CF 2 —O] n —[(CF 2 ) r —O] p —(CF 2 ) z —SO 2 Y

where m is 0 or 1; n is 0-5; r is 1-9; p is 0-5, z is 1-10, and Y is selected from F, Cl, Br, I, or OM.

7. The composition of claim 1 , wherein the polyfunctional monomer is at least one of perfluorodiallyl alkylether and a perfluorodivinyl alkylether.

8. The composition of claim 1 , wherein the polymer is derived from 5-40 mole % of the highly fluorinated sulfur-containing monomer versus the total monomer present.

9. The composition of claim 1 , wherein the polymer is derived from 0.1-0.01 wt % of the polyfunctional monomer versus the total monomer present.

10. The composition of claim 1 , wherein the fluorinated olefin monomer is selected from at least one of: tetrafluoroethylene, vinylidene fluoride, and hexafluoropropylene.

11. The composition of claim 1 , wherein the polymer is derived from at least 0.5 mol % and at most 12 mol % of the polyfunctional monomer versus the total monomer present.

12. The composition of claim 1 , wherein the composition further comprises an additive, wherein the additive is selected from at least one of a manganese and cerium.

13. The composition of claim 1 , wherein the polymer has a melt flow index at 265° C./5 kg of between 0.01 g/10 min to 50 g/10 min.

14. The composition of claim 1 , wherein the polymer is derived from at least 65 mole % Of the fluorinated olefin monomer.

15. An article comprising the composition of claim 1 , wherein the article is a membrane or an electrode.

16. The membrane electrode assembly comprising the membrane of claim 15 .

17. A fuel cell comprising the membrane electrode assembly of claim 16 .

18. A method comprising:
(I) providing a mixture comprising
(a) a fluorinated olefin monomer;
(b) a highly fluorinated or perfluorinated sulfur-containing monomer
CX 1 X 2 ═CX 3 [(CX 4 X 5 ) w —O—R 1 —SO 2 Y)

where X 1 , X 2 , X 3 , X 4 , and X 5 are each independently selected from H, Cl, or F; w is 0 or 1; R 1 is a non-fluorinated or fluorinated alkylene group; and Y is selected from F, Cl, Br, I, or OM, where M is a cation wherein highly fluorinated refers to a compound wherein at least 75% of the C—H bonds are replaced by C—F bonds, and perfluorinated refers to a compound wherein all C—H bonds are replaced by C—F bonds; and
(c) a polyfunctional monomer, comprising at least two functional groups, wherein the at least two functional groups are is selected from: (i) at least two fluorovinyl ether groups, (ii) at least two fluoroallyl ether groups, (iii) a fluorovinyl group and a fluorinated olefinic group, (iv) a fluoroallyl ether group and a fluorinated olefinic group, (v) a fluorovinyl ether group and a fluoroallyl ether group, and (vi) combinations thereof; and

(II) polymerizing the mixture to form a polymer.

19. The method of claim 18 , further comprising converting the polymer into a membrane.

Assignees

• Lochhaas Kai H
• Hamrock Steven J
• Hintzer Klaus
• 3M Innovative Properties Co

Inventors

• Lochhaas Kai H
• Hamrock Steven J
• Hintzer Klaus

Classifications

• H01M8/1039

  halogenated, e.g. sulfonated polyvinylidene fluorides · CPC title

• H01M8/102 Primary

  characterised by the chemical structure of the main chain of the ion-conducting polymer · CPC title

• C08J5/2237

  containing fluorine · CPC title

• H01M8/1072

  by chemical reactions, e.g. in situ polymerisation or in situ crosslinking · CPC title

• H01M8/1032

  having sulfur, e.g. sulfonated-polyethersulfones [S-PES] · CPC title