Preparing method of alloy catalyst using polydopamine coating and alloy catalyst thereby

Patent metadata

Field	Value
Publication number	US-9711802-B2
Application number	US-201414579841-A
Country	US
Kind code	B2
Filing date	Dec 22, 2014
Priority date	Mar 10, 2014
Publication date	Jul 18, 2017
Grant date	Jul 18, 2017

Abstract

Provided is a method for preparing an alloy catalyst for fuel cells having excellent catalytic activity and high durability. The method includes coating a platinum or platinum-transition metal catalyst supported on carbon with polydopamine as a capping agent. The method for preparing an alloy catalyst supported on carbon uses polydopamine as a capping agent for a platinum or platinum-transition metal catalyst supported on carbon, and thus provides a binary or ternary platinum alloy catalyst supported on carbon having a small particle size and high alloying degree despite the subsequent high-temperature heat treatment. In addition, polydopamine (PDA) is a highly adhesive material and allows thin and uniform coating, and thus inhibits particle size growth during heat treatment while allowing easy diffusion of a transition metal into the metal. As a result, it is possible to provide an alloy catalyst provided with a core-shell structure having a surface layer formed of platinum alone and showing a high alloying degree. Finally, it is possible to provide an alloy catalyst having excellent catalytic activity and durability. Further, since polydopamine (PDA) is capable of self-polymerization at room temperature, PDA coating is carried out without additional reagents or equipment. Thus, the method has high processability and cost-efficiency.

First claim

What is claimed is:

1. A method for preparing an alloy catalyst supported on carbon, comprising a step of coating the surface of a platinum catalyst supported on carbon with polydopamine.

2. The method for preparing an alloy catalyst supported on carbon according to claim 1 , which further comprises:
allowing the polydopamine-coated platinum catalyst supported on carbon to be impregnated with a transition metal salt; and
heat treating the transition metal salt-impregnated polydopamine-coated platinum catalyst supported on carbon.

3. The method for preparing an alloy catalyst supported on carbon according to claim 1 , wherein the carbon is at least one selected from the group consisting of carbon black, carbon nanotubes, carbon nanofibers, carbon nanocoils and carbon nanocages.

4. The method for preparing an alloy catalyst supported on carbon according to claim 2 , wherein the transition metal salt is at least one selected from the group consisting of nitrates, sulfates, acetates, chlorides and oxides containing gold, silver, cobalt, iron, nickel, palladium, ruthenium, titanium, vanadium or chrome.

5. The method for preparing an alloy catalyst supported on carbon according to claim 2 , wherein the heat treatment is carried out at 700-1000° C.

6. The method for preparing an alloy catalyst supported on carbon according to claim 1 , wherein the polydopamine is coated with a thickness of 0.5-5.0 nm.

7. A method for preparing an alloy catalyst supported on carbon, comprising a step of coating the surface of a platinum-transition metal catalyst supported on carbon with polydopamine.

8. The method for preparing an alloy catalyst supported on carbon according to claim 7 , which further comprises:
allowing the polydopamine-coated platinum-transition metal catalyst supported on carbon to be impregnated with a transition metal salt; and
heat treating the transition metal salt-impregnated polydopamine-coated platinum-transition metal catalyst supported on carbon.

9. The method for preparing an alloy catalyst supported on carbon according to claim 7 , wherein the carbon is at least one selected from the group consisting of carbon black, carbon nanotubes, carbon nanofibers, carbon nanocoils and carbon nanocages, and
the platinum-transition metal comprises platinum and at least one selected from the group consisting of gold, silver, cobalt, iron, nickel, palladium, ruthenium, titanium, vanadium and chrome.

10. The method for preparing an alloy catalyst supported on carbon according to claim 8 , wherein the transition metal salt is at least one selected from the group consisting of nitrates, sulfates, acetates, chlorides and oxides containing gold, silver, cobalt, iron, nickel, palladium, ruthenium, titanium, vanadium or chrome.

11. The method for preparing an alloy catalyst supported on carbon according to claim 8 , wherein the heat treatment is carried out at 700-1000° C.

12. The method for preparing an alloy catalyst supported on carbon according to claim 7 , wherein the polydopamine is coated with a thickness of 0.5-5.0 nm.

13. An alloy catalyst supported on carbon obtained by the method as defined in claim 1 , which is provided with a core-shell structure having a surface layer comprising platinum and a core comprising platinum and the transition metal.

14. An alloy catalyst supported on carbon obtained by the method as defined in claim 7 , which is provided with a core-shell structure having a surface layer comprising platinum and a core comprising platinum and the transition metal.

15. An electrode for fuel cells comprising the alloy catalyst supported on carbon as defined in claim 13 .

16. An electrode for fuel cells comprising the alloy catalyst supported on carbon as defined in claim 14 .

17. A fuel cell comprising the electrode as defined in claim 15 .

18. A fuel cell comprising the electrode as defined in claim 16 .

Assignees

• Industry-Academic Cooperation Foundation Yonsei Univ

Inventors

• Kim Hansung

Classifications

• H01M4/8892

  Impregnation or coating of the catalyst layer, e.g. by an ionomer · CPC title

• H01M4/921

  Alloys or mixtures with metallic elements · CPC title

• H01M4/8882

  Heat treatment, e.g. drying, baking · CPC title

• H01M4/926 Primary

  on carbon or graphite · CPC title

• H01M4/8663

  Selection of inactive substances as ingredients for catalytic active masses, e.g. binders, fillers · CPC title