Binder and the use thereof for conditioning waste containing aluminium metal

Patent metadata

Field	Value
Publication number	US-9711248-B2
Application number	US-201414774650-A
Country	US
Kind code	B2
Filing date	Mar 11, 2014
Priority date	Mar 13, 2013
Publication date	Jul 18, 2017
Grant date	Jul 18, 2017

Abstract

The present invention relates to a binder composition comprising (i) a phospho-magnesium cement; (ii) a boron source; (iii) a lithium salt; and (iv) water and to its preparation method. The present invention also relates to the use of such a binder for confining wastes and notably nuclear wastes containing aluminum metal.

First claim

The invention claimed is:

1. A binder composition comprising:
(i) a phospho-magnesium cement;
(ii) a boron source;
(iii) a lithium salt; and
(iv) water.

2. The composition according to claim 1 , wherein said phospho-magnesium cement consists of a magnesium source in the oxidized state and of a phosphate source.

3. The composition according to claim 2 , wherein said magnesium source in the oxidized state is selected from the group consisting of magnesium oxide (MgO), magnesium hydroxide (Mg(OH) 2 ), magnesium carbonate (MgCO 3 ), magnesium hydroxycarbonate (4MgCO 3 .Mg(OH) 2 .5H 2 O) and one of their mixtures.

4. The composition according to claim 2 , wherein said phosphate source is selected from the group consisting of phosphoric acid, aluminium phosphate, sodium phosphate, potassium phosphate, aluminium monohydrogenphosphate, sodium monohydrogenphosphate, potassium monohydrogenphosphate, aluminium dihydrogenphosphate, sodium dihydrogenphosphate, potassium dihydrogenphosphate and one of their mixtures.

5. The composition according to claim 1 , wherein said boron source is selected from the group consisting of boric acid, metaboric acid, borax, a borate salt, a monohydrogenborate salt, a dihydrogenborate salt, a metaborate salt, a polyborate salt and one of their mixtures.

6. The composition according claim 1 , wherein said lithium salt is selected from the group consisting of lithium nitrate, lithium carbonate, lithium sulfate, lithium phosphate, lithium triazole, lithium borate, lithium monohydrogenborate, lithium dihydrogenborate, lithium metaborate, lithium polyborate and one of their mixtures.

7. The composition according to claim 1 , wherein in said composition:
the molar ratio between the elements Mg and P is between 0.5 and 1.5;
the molar ratio between the elements B and Mg is between 0.03 and 0.3;
the molar ratio between the elements Li and Mg is between 0.02 and 0.12; and
the molar ratio between water and the element Mg is between 4 and 7.

8. The composition according to claim 1 , wherein said composition comprises a filler.

9. The composition according to claim 8 , wherein said filler a siliceous filler.

10. The composition according to claim 1 , wherein said composition further comprises sand and optionally granulates.

11. The composition according to claim 7 ,
wherein the molar ratio between the elements Mg and P is between 0.8 and 1.

12. The composition according to claim 7 ,
wherein the molar ratio between the elements B and Mg is between 0.05 and 0.15.

13. The composition according to claim 7 ,
wherein the molar ratio between the elements Li and Mg is between 0.05 and 0.10.

14. The composition according to claim 7 ,
wherein the molar ratio between water and the element Mg is between 5 and 6.

15. The composition according to claim 9 , wherein said siliceous filler is an alumino-siliceous filler.

16. The composition according to claim 15 , wherein said alumino-siliceous filler is a filler, either natural or not, stemming from pozzolan, illite, opaline, cherts, volcanic ashes, pumice stone, schistous clays, calcined diatomaceous earths, baked clay, silica fume or fly ash.

17. A binder composition, comprising:
(i) a phospho-magnesium cement;
(ii) a boron source;
(iii) a lithium salt; and
(iv) water, wherein said binder composition is selected from among
a grout composition formed with
(i) a phospho-magnesium cement formed with magnesium oxide calcined between 1,000 and 1,500° C., with a specific surface area of less than 1 m 2 /g and with potassium dihydrogenphosphate;
(ii) boric acid;
(iii) lithium nitrate;
(iv) a filler consisting of alumino-siliceous fly ash; and
(v) water;

a mortar composition formed with
(i) a phospho-magnesium cement formed with magnesium oxide calcined between 1,000 and 1,500° C., with a specific surface area of less than 1 m 2 /g and with potassium dihydrogenphosphate;
(ii) boric acid;
(iii) lithium nitrate;
(iv) a filler consisting of alumino-siliceous fly ash;
(v) water; and
(vi) siliceous sand with a grain size of less than 2 mm; and

a concrete composition formed with:
(i) a phospho-magnesium cement formed with magnesium oxide calcined between 1,000 and 1,500° C., with a specific surface area of less than 1 m 2 /g and with potassium dihydrogenphosphate;
(ii) boric acid;
(iii) lithium nitrate;
(iv) a filler consisting of alumino-siliceous fly ash;
(v) water;
(vi) siliceous sand with a grain size of less than 2 mm; and
(vii) a siliceous granulate.

18. A method for preparing a binder composition, comprising the steps of:
a) preparing a mixture comprising water, a boron source, a lithium salt, phosphorus-magnesium cement, and a filler; and
b) kneading the obtained mixture subsequently to said step (a).

19. The method according to claim 18 , wherein sand and optionally granulates are added during said step (a), subsequent to said step (a) or subsequent to said step (b).

20. The method of claim 18 , further comprising confining nuclear wastes containing aluminium metal.

21. Packages of wastes confined in a binder with a composition comprising water, a boron source, a lithium salt, and phosphorus-magnesium cement, and conditioned in barrels or caissons.

Assignees

• Commissariat Energie Atomique
• Commissariat A L'Energie Atomique Aux Energies Alternatives

Inventors

• Cau Dit Coumes Celine
• Lambertin David
• Antonucci Pascal
• Charlot Maryline

Classifications

• C04B28/342

  the phosphate binder being present in the starting composition as a mixture of free acid and one or more reactive oxides · CPC title

• G21F9/30 Primary

  Processing (separating different isotopes of the same chemical element B01D59/00) · CPC title

• Y02W30/91

  Use of waste materials as fillers for mortars or concrete · CPC title

• C04B28/346

  the phosphate binder being present in the starting composition as a mixture of free acid and one or more phosphates · CPC title

• C04B40/0028

  Aspects relating to the mixing step of the mortar preparation · CPC title