Nano-nano-composite optical ceramic lenses

Patent metadata

Field	Value
Publication number	US-9709699-B2
Application number	US-201213365588-A
Country	US
Kind code	B2
Filing date	Feb 3, 2012
Priority date	Feb 3, 2012
Publication date	Jul 18, 2017
Grant date	Jul 18, 2017

Abstract

An optical component, for example a lens, integrally formed of a nano/nano class nanocomposite optical ceramic (NNCOC) material. The constituent nanograin materials of the NNCOC material are selected to tailor the thermal and optical properties of the lens so as to provide a lens with a substantially constant focal length over an operating temperature range and/or an optical system in which the image position does not change appreciably over the operating temperature range.

First claim

What is claimed is:

1. An optical system comprising at least one athermal lens integrally formed of a nano-nano composite optical ceramic (NNCOC) material having a crystalline structure and comprising a first plurality of nanograins of a first component nanograin material having a first coefficient of thermal expansion, a first thermo-optic coefficient, and a first index of refraction, and a separate, second plurality of nanograins of a different second component nanograin material having a second coefficient of thermal expansion, a second thermo-optic coefficient, and a second index of refraction, each of the first and second pluralities of nanograins having a sub-micron grain size in a direction of light transmission through the at least one athermal lens, and a volumetric ratio of the first and second pluralities of nanograins in the nano-nano composite optical ceramic material being substantially non-varying throughout the at least one athermal lens and selected to achieve a substantially constant focal length of the optical system over an operating temperature range from about −40° C. to about 70° C., and based on a first relationship between the first coefficient of thermal expansion and the first index of refraction and a rate of change of the first index of refraction over the operating temperature range, and a second relationship between the second coefficient of thermal expansion and the second index of refraction and a rate of change of the second index of refraction over the operating temperature range, the crystalline structure of the nano-nano composite optical ceramic material obtained by sintering the first component nanograin material and the second component nanograin material and applying a hot isostatic press.

2. The optical system of claim 1 , wherein the NNCOC material is substantially transparent in the infrared spectral band.

3. The optical system of claim 1 , wherein the first and second component nanograin materials are selected from a group consisting of ZrO 2 —Y 2 O 3 , Magnesium fluoride (MgF 2 ), Strontium fluoride (SrF 2 ), quartz, and Calcium Fluoride (CaF 2 ).

4. The optical system of claim 1 , wherein the NNCOC material consists of first and second component nanograin materials with no host matrix material, and wherein the sub-micron grain size of each component nanograin material is less than approximately one tenth of a wavelength of light transmitted by the at least one athermal lens.

5. The optical system of claim 4 , wherein the sub-micron grain size of each component nanograin material is approximately 100 nanometers.

6. The optical system of claim 1 , further comprising a mount configured to hold the at least one athermal lens.

7. The optical system of claim 6 , wherein the mount has a coefficient of thermal expansion, and wherein the volumetric ratio of the first and second pluralities of nanograins is selected to provide the at least one athermal lens with a thermo-optic coefficient that is substantially equal and opposite to the coefficient of thermal expansion of the mount.

8. The optical system of claim 1 , wherein the volumetric ratio of the first and second pluralities of nanograins is selected to achromatize the optical system over a waveband of interest.

9. The optical system of claim 8 , wherein the at least one athermal lens is a lens system including a first positive-powered athermal lens having a first optical power and a second negative-powered athermal lens having a second optical power, an optical power of the optical system being equal to the sum of the first optical power of the first lens and the second optical power of the second lens.

10. The optical system of claim 8 , wherein the waveband of interest includes at least a portion of the visible spectral band.

11. The optical system of claim 1 , wherein the first and second component nanograin materials are selected from the group consisting of Barium Fluoride (BaF 2 ), Gallium Phosphide (GaP), and Gallium Arsenide (GaAs).

12. A method of producing an athermal lens from a nano-nano-composite optical ceramic powder, the method comprising:
determining a desired thermo-optic coefficient of the athermal lens;
selecting at least two different component nanograin materials including a first plurality of nanograins of one of the at least two different component nanograin materials, each nanograin of the first plurality of nanograins having a first coefficient of thermal expansion, a first thermo-optic coefficient, and a first index of refraction, and a separate, second plurality of nanograins of another of the at least two different component nanograin materials, each nanograin of the second plurality of nanograins having a second coefficient of thermal expansion, a second thermo-optic coefficient, and a second index of refraction, and selecting a volumetric ratio of the at least two different component nanograin materials to achieve the desired thermo-optic coefficient based on a first relationship between the first thermo-optic coefficient and the first coefficient of thermal expansion, the first index of refraction, and a rate of change of the first index of refraction over an operating temperature range, and a second relationship between the second thermo-optic coefficient and the second coefficient of thermal expansion, the second index of refraction, and a rate of change of the second index of refraction over the operating temperature range;
combining and processing the at least two different component nanograin materials to form the nano-nano-composite optical ceramic powder including the first plurality of nanograins of one of the at least two different component nanograin materials, and the separate, second plurality of nanograins of another of the at least two different component nanograin materials; and
processing the nano-nano-composite optical ceramic powder to form the athermal lens, wherein the volumetric ratio of the at least two different component nanograin materials is substantially non-varying throughout the formed athermal lens and processing comprises sintering the at least two different component nanograin materials and applying a hot isostatic press to form a crystalline structure.

13. The method of claim 12 , wherein determining the desired thermo-optic coefficient of the athermal lens further includes determining a coefficient of thermal expansion of a mount configured to hold the athermal lens, and selecting the thermo-optic coefficient of the athermal lens to be approximately matched to the coefficient of thermal expansion of the mount.

14. The method of claim 12 , wherein combining and processing the at least two different component nanograin materials includes using a flame spray pyrolysis method to form the nano-nano-composite optical ceramic powder.

15. An optical system comprising at least one reflective athermal optical component integrally formed of a crystalline nano-nano composite optical ceramic (NNCOC) material having a crystalline structure and comprising at least two separate pluralities of nanograins formed of different component nanograin materials, including a first plurality of nanograins having a first coefficient of thermal expansion, a first thermo-optic coefficient, and a first index of refraction, and a second plurality of nanograins having a second coefficient of thermal expansion, a second thermo-optic coefficient, and a second index of refraction, each nanograin material having a sub-micron grain size, and a volumetric ratio of the at least two different nanograin materials in the crystalline nano-nano composite optical ceramic material being substantially non-varying throughout the a

Assignees

• Sunne Wayne L
• Hanson Jacob A
• Fest Eric C
• Roncone Ronald L
• Raytheon Co

Inventors

• Sunne Wayne L
• Hanson Jacob A
• Fest Eric C
• Roncone Ronald L

Classifications

• Y10S977/811

  Of specified metal oxide composition, e.g. conducting or semiconducting compositions such as ITO, ZnOx · CPC title

• G02B5/10

  with curved faces · CPC title

• G02B2207/101

  Nanooptics · CPC title

• G02B9/10

  one + and one - component · CPC title

• G02B1/00 Primary

  Optical elements characterised by the material of which they are made; Optical coatings for optical elements · CPC title