Electrochemical co-production of products with carbon-based reactant feed to anode

Patent metadata

Field	Value
Publication number	US-9708722-B2
Application number	US-201414463430-A
Country	US
Kind code	B2
Filing date	Aug 19, 2014
Priority date	Jul 26, 2012
Publication date	Jul 18, 2017
Grant date	Jul 18, 2017

Abstract

The present disclosure is a system and method for producing a first product from a first region of an electrochemical cell having a cathode and a second product from a second region of the electrochemical cell having an anode. The method may include a step of contacting the first region with a catholyte comprising carbon dioxide. The method may include another step of contacting the second region with an anolyte comprising a recycled reactant and at least one of an alkane, haloalkane, alkene, haloalkene, aromatic compound, haloaromatic compound, heteroaromatic compound or halo-heteroaromatic compound. Further, the method may include a step of applying an electrical potential between the anode and the cathode sufficient to produce a first product recoverable from the first region and a second product recoverable from the second region.

First claim

What is claimed is:

1. A system for electrochemical co-production of products, comprising:
an electrochemical cell including:
a first region;
a cathode associated with the first region;
a second region;
an anode associated with the second region; and
a separator for selectively controlling a flow of ions between the first region and the second region;

a carbon dioxide source, the carbon dioxide source in flow communication with the first region to supply carbon dioxide to the first region;
a carbon-based reactant source, the carbon-based reactant source in flow communication with the second region to supply a carbon-based reactant to said second region;
a recycled reactant source, the recycled reactant source in flow communication with the second region to supply a recycled reactant to the second region, the recycled reactant is AX where X is selected from the group consisting of F, Cl, Br, I and mixtures thereof, and A is selected from the group consisting of H, Li, Na, K, Cs and mixtures thereof; and
an energy source for applying a current across the anode and the cathode, wherein when current is applied, a first product recoverable from the first region and a second product is recoverable from the second region.

2. The system according to claim 1 , wherein the carbon-based reactant includes at least one of an alkane, haloalkane, alkene, haloalkene, aromatic compound, haloaromatic compound, heteroaromatic compound or halo-heteroaromatic compound.

3. The system according to claim 1 , wherein the first product recoverable from the first region includes a carbon dioxide reduction product.

4. The system according to claim 1 , wherein the second product recoverable from the second region includes a halogenated compound.

5. The system according to claim 1 , wherein the separator selectively controls a flow of ions between the first region and the second region at a temperature less than 600 degrees C.

6. The system according to claim 1 , wherein the separator includes an ion permeable barrier.

7. The system according to claim 6 , wherein the ion permeable barrier includes at least one of a solid polymer conductor electrolyte material and a perfluorinated sulfonic acid based membrane, a sodium super-conducting ionic conductor type ceramics.

Assignees

• Liquid Light Inc
• Avantium Knowledge Centre Bv

Inventors

• Teamey Kyle
• Kaczur Jerry J

Classifications

• C25B3/04

  Chemistry & Metallurgy · mapped topic

• C25B1/00

  Electrolytic production of inorganic compounds or non-metals · CPC title

• C07C29/149

  with hydrogen or hydrogen-containing gases · CPC title

• C25B9/10

  Chemistry & Metallurgy · mapped topic

• C25B1/24

  Halogens or compounds thereof · CPC title