Method for removing sulfur compounds from a hydrocarbon fluid using an adsorbent

Patent metadata

Field	Value
Publication number	US-9708546-B2
Application number	US-201514927107-A
Country	US
Kind code	B2
Filing date	Oct 29, 2015
Priority date	Oct 29, 2015
Publication date	Jul 18, 2017
Grant date	Jul 18, 2017

Abstract

A method of removing sulfur compounds from a hydrocarbon fluid. The method includes contacting the hydrocarbon fluid with an adsorbent comprising a carbonaceous material doped with nanoparticles of uranyl oxide (UO 3 ) to reduce the concentrations of the sulfur compounds. The carbonaceous material is at least one selected from the group consisting of activated carbon and carbon nanotubes, and the adsorbent has a weight ratio of C to U in the range from 9:1 to 17:1, and a weight ratio of C to O in the range from 5:1 to 13:1.

First claim

The invention claimed is:

1. A method of removing sulfur compounds from a hydrocarbon fluid, comprising:
contacting the hydrocarbon fluid with an adsorbent comprising at least one carbonaceous material selected from the group consisting of activated carbon and carbon nanotubes doped with nanoparticles of uranyl oxide (UO 3 ),
wherein the contacting forms a treated hydrocarbon fluid having a lower concentration of the sulfur compounds relative to the hydrocarbon fluid, and
wherein the adsorbent has a weight ratio of C to U in the range from 9:1 to 17:1, and a weight ratio of C to O in the range from 5:1 to 13:1.

2. The method of claim 1 , wherein the carbonaceous material is carbon nanotubes doped with nanoparticles of uranyl oxide (UO 3 ), and the carbon nanotubes are multi-walled carbon nanotubes.

3. The method of claim 2 , wherein the adsorbent comprises multi-walled carbon nanotubes doped with nanoparticles of uranyl oxide, and wherein the multi-walled carbon nanotubes doped with the nanoparticles of uranyl oxide have a BET surface area of greater than about 200 m 2 /g.

4. The method of claim 1 , wherein the carbonaceous material is doped with the nanoparticles of uranyl oxide by incipient wetness impregnation.

5. The method of claim 1 , wherein the hydrocarbon fluid comprises at least one selected from the group consisting of n-hexane, diesel, jet fuel, marine gas oil, and used motor oil, and wherein the sulfur compounds are at least one selected from the group consisting of benzothiophene (BT), alkyl-benzothiophene (alkyl-BT), dibenzothiophene (DBT), alkyl-dibenzothiophene (alkyl-DBT), and thiophene and derivatives thereof.

6. The method of claim 5 , wherein the adsorbent comprises activated carbon doped with nanoparticles of uranyl oxide, the hydrocarbon fluid is n-hexane, the sulfur compounds are dibenzothiophene (DBT), and wherein the adsorbent removes at least about 95% of the DBT from the n-hexane.

7. The method of claim 5 , wherein the adsorbent comprises carbon nanotubes doped with nanoparticles of uranyl oxide, the hydrocarbon fluid is n-hexane, the sulfur compounds are dibenzothiophene (DBT), and wherein the adsorbent removes at least about 75% of the DBT from the n-hexane.

8. The method of claim 1 , wherein the concentration of the adsorbent contacting the hydrocarbon fluid ranges from about 8 g/L to 20 g/L of the hydrocarbon fluid.

9. The method of claim 1 , wherein the adsorbent is disposed in a fixed bed reactor or fluidized bed reactor and the contacting involves passing the hydrocarbon fluid through the fixed bed reactor or fluidized bed reactor.

10. The method of claim 9 , wherein the fixed bed reactor comprises a cartridge.

11. The method of claim 10 , wherein the cartridge further comprises at least one adsorbent selected from the group consisting of a zeolite, activated alumina, and activated carbon.

12. The method of claim 1 , wherein the adsorbent has a form selected from the group consisting of a granule, a pellet, a sphere, a powder, a woven fabric, a non-woven fabric, a mat, a felt, a block, and a honeycomb.

13. The method of claim 1 , wherein the carbon nanotubes have an outer diameter ranging from about 10 nm to 20 nm.

14. The method of claim 1 , wherein the nanoparticles of uranyl oxide have a diameter ranging from about 10 nm to 80 nm.

15. The method of claim 1 , wherein the adsorbent comprises activated carbon doped with nanoparticles of uranyl oxide, and wherein the activated carbon doped with the nanoparticles of uranyl oxide has a BET surface area of greater than about 900 m 2 /g.

16. The method of claim 1 , wherein the adsorbent comprises activated carbon doped with nanoparticles of uranyl oxide, and wherein the activated carbon doped with the nanoparticles of uranyl oxide has a total pore volume of greater than about 0.37 cm 3 /g.

17. The method of claim 1 , further comprising removing the sulfur compounds from the hydrocarbon fluid by at least one removal method selected from the group consisting of hydrodesulfurization, biodesulfurization, oxidative desulfurization, and adsorptive desulfurization using at least one other adsorbent.

18. The method of claim 1 , wherein the hydrocarbon fluid is contacted with the adsorbent at a temperature of about 10-40° C. and a pressure of about 1-50 bar.

19. The method of claim 1 , further comprising removing the adsorbent from the treated hydrocarbon fluid.

20. A method of removing sulfur compounds from a hydrocarbon fluid, comprising:
(a) supplying the hydrocarbon fluid to a hydrotreating unit, the hydrotreating unit comprising a catalyst bed and a hydrogen gas source, said catalyst bed comprising a desulfurization catalyst, wherein contacting the hydrocarbon fluid with the desulfurization catalyst produces a partially desulfurized hydrocarbon fluid stream,
(b) removing gaseous products from the partially desulfurized hydrocarbon fluid stream to produce a gas-free partially desulfurized hydrocarbon fluid stream,
(c) then supplying the gas-free partially desulfurized hydrocarbon fluid stream after removing the gaseous products to at least one adsorption unit, said at least one adsorption unit comprising an adsorbent for the removal of the sulfur compounds, the adsorbent comprising at least one carbonaceous material selected from the group consisting of activated carbon and carbon nanotubes doped with nanoparticles of uranyl oxide (UO 3 ), wherein the adsorbent has a weight ratio of C to U in the range from 9:1 to 17:1, and a weight ratio of C to O in the range from 5:1 to 13:1, and
(d) contacting the adsorbent with the gas-free partially desulfurized hydrocarbon fluid stream to substantially remove the sulfur compounds therefrom to produce a desulfurized hydrocarbon fluid stream.

Assignees

• Univ King Fahd Pet & Minerals

Inventors

• KHALED Mazen Mohammad
• Nazal Mazen Khaled

Classifications

• C10G25/006

  of waste oils, e.g. PCB's containing oils · CPC title

• C10G67/02

  plural serial stages only · CPC title

• C10G25/003 Primary

  Specific sorbent material, not covered by C10G25/02 or C10G25/03 · CPC title

• C10G67/12

  including oxidation as the refining step in the absence of hydrogen · CPC title

• C10G67/06

  including a sorption process as the refining step in the absence of hydrogen · CPC title