Highly branched lipophilic polymer, and photopolymerizable composition containing the same

Patent metadata

Field	Value
Publication number	US-9708486-B2
Application number	US-201514955803-A
Country	US
Kind code	B2
Filing date	Dec 1, 2015
Priority date	Mar 18, 2011
Publication date	Jul 18, 2017
Grant date	Jul 18, 2017

Abstract

There is provided a highly branched lipophilic polymer that is excellent in blending and dispersing properties in a matrix resin, and is possible to provide surface modification properties such as excellent lipophilicity (anti-fingerprint property) and the like to a coating that is obtained from the resin composition while the intrinsic transparency of the resin is not impaired; and a photopolymeizable composition comprising the highly branched lipophilic polymer. A highly branched lipophilic polymer obtained by polymerizing a monomer A containing two or more radically polymerizable double bonds per molecule and a monomer B containing a C 6-30 alkyl group or a C 3-30 alicyclic group and at least one radically polymerizable double bond per molecule in the presence of 5 to 200 mol % of a polymerization initiator C relative to the number of moles of the monomer A. A photopolymeizable composition comprising the highly branched lipophilic polymer.

First claim

The invention claimed is:

1. A photopolymerizable composition comprising a highly branched lipophilic polymer (a), a photopolymerizable compound (b), and a photopolymerization initiator (c),
wherein the highly branched lipophilic polymer (a) is obtained by polymerizing (i) a monomer A containing two or more radically polymerizable double bonds per molecule, (ii) a monomer B containing an unsubstituted C 6-30 alkyl group or an unsubstituted C 3-30 alicyclic group and at least one radically polymerizable double bond per molecule, and optionally (iii) a monomer D that is different from the monomer A and the monomer B, in the presence of 5 to 200 mol % of a polymerization initiator C relative to the number of moles of the monomer A.

2. The photopolymerizable composition according to claim 1 , wherein a content of the highly branched lipophilic polymer (a) is 0.01 to 20 parts by mass relative to 100 parts by mass of the photopolymerizable compound (b).

3. The photopolymerizable composition according to claim 2 , wherein the photopolymerizable compound (b) is a multifunctional (meth)acrylate compound.

4. The photopolymerizable composition according to claim 3 , wherein the photopolymerizable compound (b) is dipentaerythritol hexa(meth)acrylate.

5. A resin shaped product prepared by photopolymerization of the photopolymerizable composition as claimed in claim 1 .

6. The photopolymerizable composition according to claim 1 , wherein the monomer A is a compound containing either or both of a vinyl group and a (meth)acrylic group.

7. The photopolymerizable composition according to claim 6 , wherein the monomer A is a divinyl compound or a di(meth)acrylate compound.

8. The photopolymerizable composition according to claim 7 , wherein the monomer A is a compound containing a C 3-30 alicyclic group.

9. The photopolymerizable composition according to claim 8 , wherein the monomer A is tricyclo[5.2.1.0 2,6 ]decane dimethanol di(meth)acrylate.

10. The photopolymerizable composition according to claim 7 , wherein the monomer A is a compound of Formula [1]:

(where R 1 is a hydrogen atom or a methyl group; L 1 is a C 2-12 alkylene group that is optionally substituted with a hydroxy group; and m is an integer of 1 to 30).

11. The photopolymerizable composition according to claim 10 , wherein L 1 is an ethylene group.

12. The photopolymerizable composition according to claim 1 , wherein the highly branched lipophilic polymer is obtained using 5 to 300 mol % of the monomer B relative to the number of moles of the monomer A.

13. The photopolymerizable composition according to claim 12 , wherein the monomer B is a compound of Formula [2]:

(where R 2 is a hydrogen atom or a methyl group; R 3 is a C 6-30 alkyl group or a C 3-30 alicyclic group; L 2 is a C 2-6 alkylene group; and n is an integer of 0 to 30).

14. The photopolymerizable composition according to claim 13 , wherein n is 0.

15. The photopolymerizable composition according to claim 13 , wherein L 2 is an ethylene group.

16. The photopolymerizable composition according to claim 1 , wherein the polymerization initiator C is an azo polymerization initiator.

17. The photopolymerizable composition according to claim 16 , wherein the polymerization initiator C is 2,2′-azobis(2,4-dimethylvaleronitrile).

18. The photopolymerizable composition according to claim 16 , wherein the polymerization initiator C is dimethyl 1,1′-azobis(1-cyclohexanecarboxylate).

Assignees

• Nissan Chemical Ind Ltd

Inventors

• Matsuyama Motonobu
• Haraguchi Masayuki
• Ozawa Masaaki

Classifications

• C09D133/06

  of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical · CPC title

• C08F265/06

  Polymerisation of acrylate or methacrylate esters on to polymers thereof · CPC title

• C08F267/06

  on to polymers of esters · CPC title

• C08F4/04

  Azo-compounds · CPC title

• C08F22/10

  Esters · CPC title