Thermoplastic Resin Composition and Molded Article Manufactured Therefrom
US-2024376301-A1 · Nov 14, 2024 · US
US9708460B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9708460-B2 |
| Application number | US-201214368479-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 1, 2012 |
| Priority date | Dec 26, 2011 |
| Publication date | Jul 18, 2017 |
| Grant date | Jul 18, 2017 |
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Mechanical strength of a composite material is enhanced by a simple process. In a composite material comprising a resin or a rubber and an oxide glass, the resin or the rubber is dispersed in the oxide glass, or the oxide glass is dispersed in the resin or the rubber, and the oxide glass is softened and fluidized by heating at or lower than a heat decomposition temperature of the resin or the rubber.
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The invention claimed is: 1. A composite material comprising a resin or a rubber and an oxide glass, wherein the resin or the rubber is dispersed in the oxide glass, or the oxide glass is dispersed in the resin or the rubber; the oxide glass contains Ag and at least two of Te, P, and V; the oxide glass is a lead-free glass; the temperature difference between the softening point of the oxide glass and the glass transition point of the resin or the rubber is within 100° when the resin or rubber comprises an amorphous portion and not a crystalline portion; the temperature difference between the softening point of the oxide glass and the melting point of the resin or the rubber is within 100° C. when the resin or the rubber comprises a crystalline portion; and the resin comprises one of polyethylene, polyvinyl chloride, polypropylene, polystyrene, polyvinyl acetate, ABS resin, AS resin, polyacetal resin, polyimide, polycarbonate, modified polypheylene ether (PPE), polybutylene terephthalate (PBT), polyarylate, polysulfone, polyphenvlene sulfide, polyether ether ketone, polyimide resin, fluoro resin, polyamideimide, polyether ether ketone, epoxy resin, phenolic resin, polyester, and polyvinyl ester. 2. The composite material according to claim 1 , wherein the oxide glass contains Te, V, and Ag. 3. The composite material according to claim 2 , wherein the oxide glass contains Ag 2 O, V 2 O 5 , and TeO 2 , and the content of Ag 2 O, V 2 O 5 , and TeO2 in total is 75 mass % or more. 4. The composite material according to claim 3 , wherein the oxide glass contains 10 to 60 mass % of Ag 2 O, 5 to 65 mass % of V 2 O 5 , and 15 to 50 mass% of TeO2. 5. The composite material according to claim 4 , wherein the Ag 2 O content of the oxide glass is 2.6 times or less the V 2 O 5 content. 6. The composite material according to claim 5 , wherein the sum of the Ag 2 O content and the V 2 O 5 content of the oxide glass is 40 to 80 mass %. 7. The composite material according to claim 1 further comprising an organic solvent, wherein the composite material and the organic solvent form a coating material. 8. A glass fiber reinforced resin in which the composite material according to claim 1 and glass fibers are composited. 9. An electric conductive package comprising the composite material according to claim 1 . 10. A blade for wind power generation comprising the glass fiber reinforced resin according to claim 8 .
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