Method of preparing superabsorbent polymer

Patent metadata

Field	Value
Publication number	US-9708452-B2
Application number	US-201414390303-A
Country	US
Kind code	B2
Filing date	May 9, 2014
Priority date	May 9, 2013
Publication date	Jul 18, 2017
Grant date	Jul 18, 2017

Abstract

This disclosure relates to a method for preparing superabsorbent polymer. The method for preparing superabsorbent polymer according to one aspect of the invention comprises obtaining hydrogel polymer during the process of preparing superabsorbent polymer, and then, spraying a surface crosslinking solution comprising a surface crosslinker, alcohol, and ionic liquid to crosslink the surface of the pulverized polymer. The method for preparing superabsorbent polymer may use ionic liquid without using lower alcohol, or if lower alcohol is used together, may minimize the amount, and thus, reduce cost and additional drying treatment, and may control swelling of gel to prepare superabsorbent polymer with excellent product properties.

First claim

The invention claimed is:

1. A method for preparing superabsorbent polymer, comprising:
thermally polymerizing or photopolymerizing a monomer composition comprising water-soluble ethylene unsaturated monomers and a polymerization initiator to form hydrogel polymer;
drying the hydrogel polymer;
pulverizing the dried hydrogel polymer to form a pulverized polymer; and
spraying a surface crosslinking solution comprising a surface crosslinker, water and ionic liquid having a liquid state at 15 to 40° C. on to the pulverized polymer to crosslink the surface of the pulverized polymer,

wherein:
the ionic liquid is used in the amount of 0.05 to 1.0 parts by weight, based on 100 parts by weight of the pulverized polymer,
the crosslinking solution does not include a monohydric lower alcohol or further comprises monohydric lower alcohol of 0.1 to 2.0 parts by weight, based on 100 parts by weight of the pulverized polymer,
the ionic liquid consists of cations and anions, and is neutral,
the cation is selected from the group consisting of imidazole, pyridine, pyrazole, thiazole, isothiazole, azathiazole, oxothiazole, oxaine, oxazoline, oxazoborole, dithiozole, triazole, selenozole, oxaphosphole, pyrrole, borole, furan, thiophene, phosphole, pentazole, indole, indoline, oxazole, isoxazole, isotriazole, tetrazole, benzofuran, dibenzofuran, benzothiophene, dibenzothiophene, thiadiazole, pyrimidine, pyrazine, pyridazine, piperazine, piperidine, morpholene, pyrane, anoline, phthalazine, quinazoline, quinoxaline, quinoline, isoquinoline, tazine, oxazine, aza annulene, alkali metal, alkali earth metal, and transition metal cations,
the anion is selected from the group consisting of anions constituting chloride salt, borate, nitrate, sulfate, triflate, halogenated copper salt, antimonite, carborane, polyoxometallate, metal borane, and carboxylate, and
the surface crosslinker is at least one selected from the group consisting of a polyhydric alcohol compound, an epoxy compound, a polyamine compound, a haloepoxy compound, condensate of a haloepoxy compound, an oxazoline compound, a mono-, di-, or polyoxazolidinone compound, a cyclic urea compound, a multivalent metal salt, and an alkylene carbonate compound.

2. The method for preparing superabsorbent polymer according to claim 1 , wherein the cation is selected from the group consisting of N-alkylpyridinium and N,N-dialkylimidazolium.

3. The method for preparing superabsorbent polymer according to claim 1 , wherein the anion is selected from the group consisting of Cl − , BF 4 − , PF 6 − , CF 3 SO 3 − , CF 3 COO − , SbF 6 − , [CuCl 2 ] − , SO 4 − , CF 3 CH 2 CH 2 COO − , (CF 3 SO 2 )C − , CF 3 (CF 2 ) 3 SO 3 − , and [CF 3 SO 2 ] 2 N − .

4. The method for preparing superabsorbent polymer according to claim 1 , wherein the ionic liquid includes acidic ionic liquid prepared from a salt including cation of alkali metal or alkali earth metal, and anion of carboxylic acid bonded thereto.

5. The method for preparing superabsorbent polymer according to claim 1 , wherein the surface crosslinker is added in the amount of 0.1 to 2.0 parts by weight, based on 100 parts by weight of the pulverized polymer.

6. The method for preparing superabsorbent polymer according to claim 1 , wherein the moisture content of the thermally polymerized or photopolymerized hydrogel polymer is 40 to 80 wt %.

7. The method for preparing superabsorbent polymer according to claim 1 , wherein the moisture content of the dried polymer is 0.1 to 10 wt %.

8. The method for preparing superabsorbent polymer according to claim 1 , wherein the pulverization of the dried polymer is progressed such that the pulverized polymer has weight average particle diameter of 150 to 850 μm.

9. The method for preparing superabsorbent polymer according to claim 1 , wherein the surface crosslinking is progressed at 100 to 250° C. for 1 to 120 minutes.

Assignees

• Lg Chemical Ltd

Inventors

• Lee Sang Gi
• Park Sung Soo
• Ryu Chul Hee
• Won Tae Young

Classifications

• C08J3/28

  Treatment by wave energy or particle radiation · CPC title

• C08F220/06 Primary

  Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof · CPC title

• C08J3/245 Primary

  Differential crosslinking of one polymer with one crosslinking type, e.g. surface crosslinking · CPC title

• C08J3/122

  Pulverisation by spraying · CPC title

• C08J2333/02

  Homopolymers or copolymers of acids; Metal or ammonium salts thereof · CPC title