Blends containing photoactive additive

Patent metadata

Field	Value
Publication number	US-9708447-B2
Application number	US-201514701704-A
Country	US
Kind code	B2
Filing date	May 1, 2015
Priority date	Dec 20, 2012
Publication date	Jul 18, 2017
Grant date	Jul 18, 2017

Abstract

Polymeric blends having improved flame retardance properties and good ductility at low temperatures are disclosed. The blend is formed from (A) a photoactive additive containing a photoactive group derived from a monofunctional benzophenone; and (B) a polymer resin which is different from the photoactive additive. The additive can be a compound, oligomer, or polymer. When exposed to ultraviolet light, crosslinking will occur between the photoactive additive and the polymer resin, enhancing the chemical resistance and flame retardance while maintaining ductility.

First claim

The invention claimed is:

1. A polymeric blend, comprising:
a photoactive additive which is a cross-linkable polycarbonate resin containing a photoactive endcap group derived from a monofunctional benzophenone; and
a polymer resin which is different from the photoactive additive.

2. The blend of claim 1 , wherein the polymer resin is a polyester, a polysiloxane-co-bisphenol-A polycarbonate, a polyesteramide, a polyimide, a polyetherimide, a polyamideimide, a polyether, a polyethersulfone, a polyepoxide, a polylactide, a polylactic acid (PLA), or any combination thereof.

3. The blend of claim 1 , wherein the polymer resin is a vinyl polymer, a rubber-modified graft copolymer, an acrylic polymer, polyacrylonitrile, a polystyrene, a polyolefin, a polyester, a polyesteramide, a polysiloxane, a polyurethane, a polyamide, a polyamideimide, a polysulfone, a polyepoxide, a polyether, a polyimide, a polyetherimide, a polyphenylene ether, a polyphenylene sulfide, a polyether ketone, a polyether ether ketone, an acrylonitrile-butadiene-styrene (ABS) resin, an acrylic-styrene-acrylonitrile (ASA) resin, a polyethersulfone, a polyphenylsulfone, a poly(alkenylaromatic) polymer, a polybutadiene, a polyacetal, a polycarbonate, a polyphenylene ether, an ethylene-vinyl acetate copolymer, a polyvinyl acetate, a liquid crystal polymer, an ethylene-tetrafluoroethylene copolymer, an aromatic polyester, a polyvinyl fluoride, a polyvinylidene fluoride, a polyvinylidene chloride, tetrafluoroethylene, a polylactide, a polylactic acid (PLA), a polycarbonate-polyorganosiloxane block copolymer, or a copolymer comprising: (i) an aromatic ester, (ii) an estercarbonate, and (iii) carbonate repeat units.

4. The blend of claim 1 , wherein the polymer resin is a homopolycarbonate, a copolycarbonate, a polycarbonate-polysiloxane copolymer, a polyester-polycarbonate, or a p-cumyl phenol capped poly(isophthalate-terephthalate-resorcinol ester)-co-(bisphenol-A carbonate) copolymer.

5. The blend of claim 1 , wherein the polymer resin is a p-cumyl phenol capped poly(isophthalate-terephthalate-resorcinol ester)-co-(bisphenol-A carbonate) polymer or a polycarbonate-polysiloxane copolymer having a polysiloxane content from 0.4 wt % to 25 wt %.

6. The blend of claim 5 , wherein the polycarbonate-polysiloxane copolymer is a siloxane block co-polycarbonate comprising from about 6 wt % siloxane (±10%) to about 20 wt % siloxane (±10%), and having a siloxane chain length of 10 to 200.

7. The blend of claim 1 , wherein the polymer resin is a polyphosphonate polymer, a polyphosphonate copolymer, or a poly(polyphosphonate)-co-(BPA carbonate) copolymer.

8. The blend of claim 1 , wherein the polymer resin is selected from the group consisting of a polycarbonate-polysiloxane copolymer; a polycarbonate resin having an aliphatic chain containing at least two carbon atoms as a repeating unit in the polymer backbone; an ethylene-acrylic ester-glycidyl acrylate terpolymer; a polyethylene terephthalate polymer; a bisphenol-A homopolymer; a polystyrene polymer; a poly(methyl methacrylate) polymer; a thermoplastic polyester; a polybutylene terephthalate polymer; a methyl methacrylate-butadiene-styrene copolymer; an acrylonitrile-butadiene-styrene copolymer; or a dimethyl bisphenol cyclohexane-co-bisphenol-A copolymer.

9. The blend of claim 1 , wherein the weight ratio of the photoactive additive to the polymer resin is from 1:99 to 99:1.

10. The blend of claim 1 , wherein the weight ratio of the photoactive additive to the polymer resin is from about 50:50 to about 85:15.

11. The blend of claim 1 , wherein the photoactive additive is formed from the reaction of:
the monofunctional benzophenone;
a first linker moiety comprising a plurality of linking groups, wherein each linking group reacts with the functional group of the first photoactive moiety; and
a chain extender.

12. The blend of claim 11 , wherein the functional group of the monofunctional benzophenone is a hydroxyl group, an amino group, or a carboxylate group or equivalent thereof.

13. The blend of claim 11 , wherein the monofunctional benzophenone is a monohydroxybenzophenone.

14. The blend of claim 11 , wherein the reaction that forms the photoactive additive further comprises a second end-capping agent that does not contain a ketone group.

15. The blend of claim 11 , wherein the monofunctional benzophenone is 2-hydroxybenzophenone, 3-hydroxybenzophenone, or 4-hydroxybenzophenone.

16. The blend of claim 1 , wherein the photoactive additive has a weight average molecular weight of 15,000 or greater.

17. The blend of claim 1 , further comprising a flame retardant.

18. The blend of claim 17 , wherein the flame retardant is potassium perfluorobutane sulfonate (Rimar salt), potassium diphenyl sulfone-3-sulfonate (KSS), or a combination thereof.

19. The blend of claim 17 , wherein the flame retardant is Rimar salt which is present in an amount of about 0.05 wt % to about 0.085 wt %, based on the total weight of the composition, and wherein the plaque comprising the composition has a transparency of 70 to 90% at a thickness of 3.2 mm, measured according to ASTM-D1003-00.

20. The blend of claim 17 , wherein the flame retardant is present in an amount of about 0.06 wt % to about 0.08 wt %.

21. The blend of claim 17 , further comprising a heat stabilizer and a mold release agent.

22. The blend of claim 1 , further comprising an impact modifier, UV stabilizer, colorant, flame retardant, heat stabilizer, plasticizer, lubricant, mold release agent, filler, reinforcing agent, antioxidant agent, antistatic agent, blowing agent, anti-drip agent, or radiation stabilizer.

23. The blend of claim 1 , wherein the polymer resin is a polycarbonate-polysiloxane copolymer having the following structure:

wherein E is an endcap; m is a molar amount of polycarbonate; n is a molar amount of polysiloxane; and m:n is the molar ratio of polycarbonate to polysiloxane in the copolymer.

24. The blend of claim 23 , wherein the polycarbonate-polysiloxane copolymer has a siloxane content of from about 4 wt % to about 8 wt %, based on the total weight of the blend.

25. The blend of claim 1 , wherein a plaque formed from the blend achieves a UL94 5VA rating at a thickness of 1.5 mm (±10%).

26. An article formed from the blend of claim 1 .

27. The article of claim 26 , wherein the article is at least one of an automotive bumper, an automotive exterior component, an automobile mirror housing, an automobile grille, an automobile pillar, an automobile wheel cover, an automobile instrument panel or trim, an automobile glove box, an automobile door hardware or other interior trim, an automobile exterior light, an automobile part within the engine compartment, an agricultural tractor or device part, a construction equipment vehicle or device part, a construction or agricultural equipment grille, a marine or personal water craft part, an all terrain vehicle or all terrain vehicle part, plumbing equipment, a valve or pump, an air conditioning heating or cooling part, a furnace or heat pump part, a computer part, a computer router, a desk top printer, a large office/industrial printer, an electronics part, a projector part, an electronic display part, a copier part, a scanner part, an electronic printer toner cartridge, a hair d

Assignees

• Sabic Global Technologies Bv

Inventors

• Morizur Jean-Francois
• Sybert Paul Dean
• Johnson Peter
• Evans Thomas L
• Hoover James Franklin
• Flores Amanda Marie

Classifications

• C08G64/14

  containing a chain-terminating or -crosslinking agent · CPC title

• C08L69/00 Primary

  Compositions of polycarbonates; Compositions of derivatives of polycarbonates · CPC title

• C08G79/04

  Phosphorus linked to oxygen or to oxygen and carbon · CPC title

• C08G64/1666 Primary

  containing silicon · CPC title

• C08L2205/03

  containing three or more polymers in a blend · CPC title