Recycling gas to heat the hydrodesulphurization section

Patent metadata

Field	Value
Publication number	US-9708235-B2
Application number	US-201414787316-A
Country	US
Kind code	B2
Filing date	May 6, 2014
Priority date	May 6, 2013
Publication date	Jul 18, 2017
Grant date	Jul 18, 2017

Abstract

In one aspect, the present invention provides a method for recycling natural gas during a reformer startup in a methanol plant. The method comprises recycling natural gas from a point before entry into the natural gas saturator where the natural gas is recycled until the natural gas reaches a desired temperature.

First claim

What is claimed is:

1. A method for recycling natural gas during a reformer startup in a methanol plant comprising:
a) suctioning natural gas by a suction drum;
b) boosting natural gas by a natural gas booster downstream of the suction drum;
c) heating a steam reformer to heat a reformer feed gas downstream of the natural gas booster;
d) heating a hydrogenerator downstream of the steam reformer;
e) heating a sulfur adsorber downstream of the hydrogenerator;
f) recycling natural gas by a recirculation line downstream of the sulfur adsorber and upstream of the reformer;
g) cooling the recycled natural gas by a heat exchanger downstream of the sulfur adsorber; and
h) suctioning the cooled recycled natural gas into the suction drum downstream of the heat exchanger;
wherein the natural gas is recycled until the reformer feed gas reaches a desired temperature.

2. The method according to claim 1 , wherein the desired temperature of the natural gas ranges from 350° C. to 380° C.

3. The method according to claim 1 , comprising directing no natural gas to a flare.

4. The method according to claim 1 , further comprising determining if the natural gas has been heated to the desired temperature by measuring a temperature of the natural gas after said natural gas passes through a steam reformer and before the natural gas is recycled.

5. The method according to claim 1 , further comprising, after the natural gas has reached the desired temperature, directing the natural gas to the natural gas saturator to form saturated natural gas.

6. The method according to claim 5 , further comprising forming syngas from the saturated natural gas, and forming methanol from the syngas.

7. The method according to claim 1 , wherein the recycled natural gas is cooled to 20° C. to 60° C.

8. The method according to claim 1 , wherein the method does not comprise at least one of the following: a natural gas flare step and a partial oxidation step.

9. The method according to claim 1 , wherein the recycled natural gas consists essentially of natural gas.

10. The method according to claim 1 , wherein the recycled natural gas comprises methane, ethane, ethylene, or hydrogen or a combination thereof.

11. The method according to claim 1 , wherein the recycled natural gas consists of natural gas.

12. The method according to claim 1 , wherein the recycled natural gas does not comprise carbon monoxide or carbon dioxide, or a combination thereof.

13. The method according to claim 1 , wherein the method does not comprise recycling a slip stream of natural gas.

14. The method according to claim 1 , wherein the recycled natural gas is recycled back to at least one of a suction drum, a point upstream of a natural gas booster, and a point before entry into the natural gas saturator.

15. The method according to claim 1 further comprising a step, wherein the recycled natural gas heats a hydrodesulphurization section to activate a hydrodesulphurization catalyst.

Assignees

• Saudi Basic Ind Corp

Inventors

• Khurram Shezada
• Al-Hammad Ali Essa

Classifications

• C01B3/38

  using catalysts · CPC title

• C10L3/10

  Working-up natural gas or synthetic natural gas · CPC title

• C07C29/1518 Primary

  one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis · CPC title

• C10L3/106

  of water · CPC title

• C10L2290/06

  Heat exchange, direct or indirect · CPC title