Catalyst for preparing isobutene by dissociation of methyl tert-butyl ether, preparation method and use thereof

Patent metadata

Field	Value
Publication number	US-9708229-B2
Application number	US-201214353366-A
Country	US
Kind code	B2
Filing date	Oct 24, 2012
Priority date	Oct 25, 2011
Publication date	Jul 18, 2017
Grant date	Jul 18, 2017

Abstract

Disclosed is a catalyst for preparing isobutene by dissociation of methyl tert-butyl ether, the catalyst comprising amorphous silica alumina and a silicalite-1 molecular sieve, wherein the total IR acid amount of weak acids in the catalyst is in a range from 0.020 to 0.080 mmol/g, and the ratio of B acid/L acid of the weak acids is in a range from 2.5:1 to 4.0:1. Also provided is a method of preparing the catalyst and the use thereof. The catalyst has a high selectivity with respect to isobutene, and high conversion of methyl tert-butyl ether, and can also effectively inhibit formation of the by-product dimethyl ether.

First claim

The invention claimed is:

1. A method for preparing isobutene by a dissociation reaction of methyl tert-butyl ether (MTBE), comprising:
contacting a feedstock with a catalyst in a reactor; and
obtaining an effluent from the reactor,
wherein the feedstock comprises MTBE and water,
wherein the effluent comprises an isobutene product stream, and wherein the catalyst comprises amorphous silica alumina and a silicalite-1 molecular sieve.

2. The method of claim 1 , wherein a liquid hourly space velocity of MTBE in the reactor is in a range from 0.7 to 6.0 h −1 , a liquid hourly space velocity of water in the reactor is in a range from 0 to 1.0 h −1 , a temperature in the reactor is in a range from 180 to 360° C., and a pressure in the reactor is in a range from the atmospheric pressure to 1.0 MPa.

3. The method of claim 2 , wherein the liquid hourly space velocity of MTBE is in a range from 2.0 to 4.0 h −1 , the liquid hourly space velocity of water is in a range from 0.1 h −1 to 0.5 h −1 , the temperature is in a range from 210 to 270° C., and the pressure is in a range from the atmospheric pressure to 0.6 MPa.

4. The method of claim 1 , wherein the catalyst has a total IR acid amount of weak acids in a range from 0.020 to 0.080 mmol/g, and a ratio of B acid/L acid of the weak acids is in a range from 2.5:1 to 4.0:1.

5. The method of claim 1 , wherein the catalyst a mass ratio of the amorphous silica-alumina to the silicalite-1 is in a range from 9.5:1 to 1:1.

6. The method of claim 5 , wherein the mass ratio of the amorphous silica-alumina to the silicalite-1 is in a range from 8:1 to 4:1.

7. The method of claim 1 , wherein in said amorphous silica-alumina, a content of SiO 2 is in a range from 60 wt % to 99 wt %, and a content of Al 2 O 3 is in a range from 1 wt % to 40 wt %.

8. The method of claim 7 , wherein in said amorphous silica-alumina, the content of silica is in a range from 80 wt % to 95 wt %, and the content of alumina is in a range from 5 wt % to 20 wt %.

9. The method of claim 1 , wherein the catalyst further comprises an active metal component selected from the group consisting of Group IIA metals and Group VIII metals.

10. The method of claim 9 , wherein a content of said active metal component, calculated based on elemental metal, is in a range from 0.3 wt % to 2.0 wt % of a total weight of the catalyst.

11. The method of claim 10 , the active metal component is selected from the group consisting of Be, Mg, Ca, Ni, Pd, and Pt.

12. The method of claim 1 , wherein the isobutene product comprises less that 0.30 wt % of dimethyl ether.

13. The method of claim 1 , wherein a selectivity of isobutene of the MTBE dissociation reaction is about 99.9%.

14. The method of claim 1 , wherein a conversion of MTBE in the MTBE dissociation reaction is about 99.9%.

Assignees

• China Petroleum & Chem Corp
• Fushun Res Inst Petroleum & Petrochemicals Sinopec

Inventors

• Zhang Shumei
• Qiao Kai
• Chen Ming
• Zhai Qingtong
• Guo Changxin
• Wang Chunmei

Classifications

• C07C2529/035

  Crystalline silica polymorphs, e.g. silicalites · CPC title

• B01J29/035

  {Microporous crystalline materials not having base exchange properties, such as} silica polymorphs, e.g. silicalites · CPC title

• B01J2029/062

  Mixtures of different aluminosilicates · CPC title

• C07C2521/12

  Silica and alumina · CPC title

• C07C2529/06

  Crystalline aluminosilicate zeolites; Isomorphous compounds thereof · CPC title