Method for producing high strength ceramic matrix composites

Patent metadata

Field	Value
Publication number	US-9708226-B2
Application number	US-201414204714-A
Country	US
Kind code	B2
Filing date	Mar 11, 2014
Priority date	Mar 15, 2013
Publication date	Jul 18, 2017
Grant date	Jul 18, 2017

Abstract

A high strength ceramic matrix composite and method for same is provided. A fiber preform is provided that is either self-supporting or is constrained by a tool for subsequent processing. The preform is coated with about 0.1 μm to about 5 μm of silicon carbide. The silicon carbide is coated with about 0.05 μm to about 2 μm boron nitride, carbon, or other interface layer. The interface layer is coated with at least about 0.2 μm to about 40 μm of silicon carbide.

First claim

What is claimed is:

1. A method of making a high strength ceramic matrix composite, the method comprising the steps of:
forming a fiber preform that is either self supporting or is constrained by a tool for subsequent processing, wherein the fiber preform comprises fibers that each have a diameter and that define a fiber volume;
coating the fiber preform with about 0.1 μm to about 5 μm of silicon carbide to form a structural coating on the fibers that increases the diameters of the fibers and effectively increasing the fiber volume, wherein the method further comprises cleaning the fiber preform including the fibers after forming the fiber preform and prior to coating the fiber preform to enhance bonding between the fibers and the structural coating;
coating the structural coating of silicon carbide with about 0.05 μm to about 2 μm boron nitride, carbon or other interface layer to form an interface layer overlying the structural coating; and
coating the interface layer with about 0.2 μm to about 40 μm of silicon carbide.

2. The method of making the high strength ceramic matrix composite of claim 1 , wherein forming the fiber preform comprises forming the fiber preform with the fiber volume of from about 10% to about 45%.

3. The method of making the high strength ceramic matrix composite of claim 1 , wherein forming the fiber preform comprises forming the fiber preform comprising a silicon carbide fiber.

4. The method of making the high strength ceramic matrix composite of claim 1 , wherein the structural coating includes one or more of the following elements (by volume); from 0 to 70% silicon, carbon, nitrogen, boron, oxygen, and from 0 to 40% zirconium, titanium, tantalum, hafnium, erbium, ytterbium, dysprosium, gadolinium, niobium, molybdenum, tantalum, Rhenium, Germanium, Tin, or Selenium.

5. The method of making the high strength ceramic matrix composite of claim 1 , wherein the fiber preform is self supporting having an integrally woven and angled interlock architecture.

6. The method of making the high strength ceramic matrix composite of claim 1 , wherein coating the preform comprises forming the structural coating by a method selected from the group consisting of chemical vapor infiltration, physical vapor deposition, and directed vapor deposition.

7. The method of making the high strength ceramic matrix composite of claim 1 , wherein coating the interface layer with silicon carbide comprises forming a silicon carbide layer overlaying the interface layer, and wherein the method further comprises the step of: coating the silicon carbide layer that overlays the interface layer with one or more additional layers.

8. The method of making the high strength ceramic matrix composite of claim 1 , wherein the fiber preform has the fiber volume of about 36%, and wherein coating the preform comprises forming the structural coating on the fibers to effectively increase the fiber volume to about 39% to about 41%.

9. A method of making a high strength ceramic matrix composite, the method comprising the steps of:
forming a fiber preform that is either self supporting or is constrained by a tool for subsequent processing, wherein the fiber preform comprises fibers that each have a diameter and that define a fiber volume;
coating the fiber preform with about 0.1 μm to about 5 μm of silicon carbide to form a structural coating on the fibers that increases the diameters of the fibers and effectively increasing the fiber volume, wherein the method further comprises cleaning the fiber preform including the fibers after forming the fiber preform and prior to coating the fiber preform to enhance bonding between the fibers and the structural coating; and
coating the structural coating of silicon carbide with about 0.2 μm to about 40 μm of silicon carbide.

10. The method of making the high strength ceramic matrix composite of claim 9 , wherein coating the structural coating comprises coating the structural coating with about 0.5 μm of silicon carbide.

11. The method of making the high strength ceramic matrix composite of claim 9 , wherein forming the fiber preform comprises forming the fiber preform with the fiber volume of from about 10% to about 45%.

12. The method of making the high strength ceramic matrix composite of claim 9 , wherein the fiber preform is self supporting having an integrally woven and angled interlock architecture.

13. The method of making the high strength ceramic matrix composite of claim 9 , wherein the fiber preform has the fiber volume of about 36%, and wherein coating the preform comprises forming the structural coating on the fibers to effectively increase the fiber volume to about 39% to about 41%.

14. The method of making the high strength ceramic matrix composite of claim 13 , wherein coating the preform with the structural coating effectively increases the fiber volume to about 39%.

15. The method of making the high strength ceramic matrix composite of claim 9 , further comprising the step of: forming the high strength ceramic matrix composite by applying a process selected from the group consisting of at least one of chemical vapor infiltration, physical vapor deposition, tape casting, particulate infiltration, pre-ceramic polymer infiltration and pyrolysis, and metal infiltration to form a ceramic matrix.

16. A method of making a high strength ceramic matrix composite, the method comprising the steps of:
forming a silicon carbide fiber preform comprising fibers that each have a diameter and that define a fiber volume of about 36% and assembling the silicon carbide fiber preform in a tool for chemical vapor infiltration;
coating the silicon carbide fiber preform with about 1 μm to about 5 μm of silicon carbide to form a structural coating on the fibers that increases the diameters of the fibers and effectively increasing the fiber volume, wherein the method further comprises cleaning the silicon carbide fiber preform including the fibers after forming the silicon carbide fiber preform and prior to coating the silicon carbide fiber preform to enhance bonding between the fibers and the structural coating;
coating the structural coating of silicon carbide with about 0.5 μm boron nitride interface layer; and
coating the boron nitride interface layer with about 2 μm of silicon carbide.

17. The method of making the high strength ceramic matrix composite of claim 16 , further comprising the step of: forming the ceramic matrix composite through slurry and melt infiltration to form a ceramic matrix.

18. The method of making the high strength ceramic matrix composite of claim 16 , wherein coating the silicon carbide fiber preform comprises coating the silicon carbide fiber preform with about 1 μm to about 5 μm of silicon carbide by chemical vapor infiltration.

19. The method of making the high strength ceramic matrix composite of claim 16 , wherein coating the boron nitride interface layer comprises coating the boron nitride interface layer with about 2 μm of silicon carbide by chemical vapor infiltration.

20. The method of making the high strength ceramic matrix composite of claim 16 , wherein coating the silicon carbide fiber preform comprises forming the structural coating on the fibers to effectively increase the fiber volume to about 39% to about 41%.

Assignees

• Rolls Royce Corp

Inventors

• Lazur Andrew J

Classifications

• C04B2235/3826

  Silicon carbides · CPC title

• C04B35/62884

  by gas phase techniques · CPC title

• C04B2235/614

  Gas infiltration of green bodies or pre-forms · CPC title

• C04B35/62894

  with more than one coating layer · CPC title

• C04B2235/428

  Silicon · CPC title