Low-temperature sintering dielectric composition and multilayer ceramic capacitor formed thereof

Patent metadata

Field	Value
Publication number	US-9708222-B2
Application number	US-201514949408-A
Country	US
Kind code	B2
Filing date	Nov 23, 2015
Priority date	Dec 16, 2014
Publication date	Jul 18, 2017
Grant date	Jul 18, 2017

Abstract

A low-temperature sintering dielectric composition contains barium titanate (BaTiO 3 ) as a main ingredient and accessory ingredients including 1.0 to 2.0 mol % of barium carbonate (BaCO 3 ), 0.5 to 1.0 mol % of at least one rare earth oxide selected from the group consisting of Y 2 O 3 , Ho 2 O 3 , Dy 2 O 3 , and Yb 2 O 3 , 0.1 to 1.0 mol % of manganese oxide (MnO), and 1.0 to 2.0 mol % of borosilicate based glass, based on 100 mol % of the main ingredient.

First claim

What is claimed is:

1. A low-temperature sintering dielectric composition comprising:
barium titanate (BaTiO 3 ) as a main ingredient and accessory ingredients,
wherein the accessory ingredients include 1.0 to 2.0 mol % of barium carbonate (BaCO 3 ), 0.5 to 1.0 mol % of a rare earth oxide, 0.1 to 1.0 mol % of manganese oxide (MnO), and 1.0 to 2.0 mol % of borosilicate based glass, based on 100 mol % of the main ingredient, and
the rare earth oxide is at least one selected from the group consisting of Y 2 O 3 , Ho 2 O 3 , Dy 2 O 3 , and Yb 2 O 3 ,
the borosilicate based glass contains boron oxide (B 2 O 3 ) and silicon dioxide (SiO 2 ) as basic ingredients, and further contains an alkali metal oxide, and an alkaline earth metal fluoride, and
when the sum of the number of moles of respective ingredients of the borosilicate based glass is 100, a content of boron oxide (B 2 O 3 ) is 10 to 30, a content of silicon dioxide (SiO 2 ) is 50 to 80, a content of the alkali metal oxide is 2 to 10, and a content of the alkaline earth metal fluoride is 1 to 5.

2. The low-temperature sintering dielectric composition of claim 1 , wherein a ratio of the borosilicate based glass to the barium carbonate (BaCO 3 ) is in a range of 1.0:1.5 to 1.5:1.0.

3. The low-temperature sintering dielectric composition of claim 1 , wherein an average particle size of barium titanate (BaTiO 3 ) is 100 nm to 200 nm.

4. The low-temperature sintering dielectric composition of claim 1 , wherein the borosilicate based glass further contains an alkaline earth metal oxide, and
when the sum of the number of moles of respective ingredients of the borosilicate based glass is 100, a content of the alkaline earth metal oxide is less than or equal to 30.

5. The low-temperature sintering dielectric composition of claim 1 , wherein the dielectric composition is sintered at a low temperature of 1000° C. to 1100° C.

Assignees

• Samsung Electro Mech

Inventors

• Hong Min Hee

Classifications

• H01G4/0085

  Fried electrodes · CPC title

• H01G4/30

  Stacked capacitors (H01G4/33 takes precedence) · CPC title

• H01G4/1227

  based on alkaline earth titanates · CPC title

• H01G4/232

  electrically connecting two or more layers of a stacked or rolled capacitor · CPC title

• C04B2235/3208

  Calcium oxide or oxide-forming salts thereof, e.g. lime · CPC title