Method for producing porous polyimide film, and porous polyimide film

Patent metadata

Field	Value
Publication number	US-9707722-B2
Application number	US-201514811654-A
Country	US
Kind code	B2
Filing date	Jul 28, 2015
Priority date	Mar 26, 2015
Publication date	Jul 18, 2017
Grant date	Jul 18, 2017

Abstract

There is provided a method for producing a porous polyimide film, including a first step of forming a coating film containing a polyimide precursor solution where a polyimide precursor and an organic amine compound are dissolved in an aqueous solvent, and a resin particle incapable of dissolving in the polyimide precursor solution, followed by drying of the coating film to form a coat containing the polyimide precursor and the resin particle, and a second step of heating the coat to imidize the polyimide precursor and form a polyimide film, the second step including a treatment for removing the resin particle.

First claim

What is claimed is:

1. A method for producing a porous polyimide film, comprising:
a first step of forming a coating film containing a polyimide precursor solution where a polyimide precursor and an organic amine compound are dissolved in an aqueous solvent, and a resin particle incapable of dissolving in the polyimide precursor solution, followed by drying of the coating film to form a coat containing the polyimide precursor and the resin particle, and
a second step of heating the coat to imidize the polyimide precursor and form a polyimide film, the second step including a treatment for removing the resin particle.

2. The method for producing a porous polyimide film as claimed in claim 1 ,
wherein the first step is a step of coating a base plate with a resin particle dispersion liquid containing the resin particle, an organic solvent incapable of dissolving the resin particle, and a binder resin capable of dissolving in the organic solvent, drying the coating to form a resin particle layer, impregnating the polyimide precursor solution between resin particles of the resin particle layer to form a coating film containing the resin particle, drying the coating film to form the coat.

3. The method for producing a porous polyimide film as claimed in claim 1 ,
wherein in the first step, a treatment for exposing the resin particle is performed in the process of drying the coating film to form the coat.

4. The method for producing a porous polyimide film as claimed in claim 1 ,
wherein in the second step, a treatment for exposing the resin particle is performed in the process of performing imidization of the polyimide precursor or after the imidization but before the treatment for removing the resin particle.

5. The method for producing a porous polyimide film as claimed in claim 1 ,
wherein the treatment for removing the resin particle is a treatment of removing the resin particle with an organic solvent capable of dissolving said resin particle.

6. The method for producing a porous polyimide film as claimed in claim 1 ,
wherein the treatment for removing the resin particle is a treatment of removing the resin particle by heating.

7. The method for producing a porous polyimide film as claimed in claim 1 ,
wherein the organic amine compound is a tertiary amine compound.

8. The method for producing a porous polyimide film as claimed in claim 1 ,
wherein the organic amine compound is an amine compound having a nitrogen-containing heterocyclic structure.

9. A porous polyimide film produced by the method claimed in claim 1 .

Assignees

• Fuji Xerox Co Ltd

Inventors

• Nukada Katsumi
• Miyamoto Tsuyoshi
• Sasaki Tomoya
• Miyazaki Kana

Classifications

• C08J7/0427

  with only one layer of a composition containing a polymer binder (with more layers C08J7/042) · CPC title

• B29K2105/0073

  Solution · CPC title

• C08J2379/08

  Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors · CPC title

• C08L2203/16

  used for films · CPC title

• B29K2105/0002

  monomers or prepolymers · CPC title