Methane conversion apparatus and process using a supersonic flow reactor

Patent metadata

Field	Value
Publication number	US-9707530-B2
Application number	US-201313967391-A
Country	US
Kind code	B2
Filing date	Aug 15, 2013
Priority date	Aug 21, 2012
Publication date	Jul 18, 2017
Grant date	Jul 18, 2017

Abstract

Apparatus and methods are provided for converting methane in a feed stream to acetylene. A hydrocarbon stream is introduced into a supersonic reactor and pyrolyzed to convert at least a portion of the methane to acetylene. The reactor effluent stream may be treated to convert acetylene to another hydrocarbon process.

First claim

The invention claimed is:

1. An apparatus for producing acetylene from a feed stream comprising methane comprising:
a supersonic reactor for receiving the methane feed stream and heating the methane feed stream to a pyrolysis temperature;
a reactor shell of the supersonic reactor for defining a reactor chamber;
a combustion zone of the supersonic reactor for combusting a fuel source to provide a high temperature carrier gas passing through the reactor space at supersonic speeds to heat and accelerate the methane feed stream to a pyrolysis temperature;
an outer layer of the reactor shell for providing structural support thereto; and
an inner layer of the reactor shell having a thermal conductivity of between about 200 and about 500 W/m-K for conducting heat from the reactor chamber the inner layer comprising at least copper chrome, copper chrome zinc, copper chrome niobium, copper nickel and copper nickel tungsten and mixtures thereof.

2. The apparatus of claim 1 , wherein the inner layer comprises a coating.

3. The apparatus of claim 1 , wherein the reactor shell is a composite having the inner and outer layers.

4. The apparatus of claim 1 , wherein the inner layer includes an internal diameter coating formed on a mandrel.

5. The apparatus of claim 1 , wherein the inner layer includes a coating that is formed by hot isostatic pressing.

6. The apparatus of claim 1 , wherein the inner layer includes coating that is formed by cladding.

7. The apparatus of claim 1 , wherein the inner layer and outer layers comprise separate castings and the castings are brazed together.

8. The apparatus of claim 1 , further comprising one or more intermediate layers between the outer layer and the inner layer.

9. The apparatus of claim 1 , further comprising one or more layers positioned outside of the outer layer.

10. The apparatus of claim 1 , further comprising one or more layers positioned inside of the inner layer.

Assignees

• Uop Llc

Inventors

• Bedard Robert L
• Naunheimer Christopher
• Towler Gavin P
• Leonard Laura E
• Woodcock Gregory O
• Mittendorf Donald L

Classifications

• B01J2219/00123

  adding a temperature modifying medium to the reactants · CPC title

• C10G2300/1025

  Natural gas · CPC title

• C07C2/78

  Processes with partial combustion · CPC title

• B01J19/26

  Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles · CPC title

• B01J2219/0263

  Ceramic · CPC title