Plastic substrate, method for producing the same and touch screen panel containing the same

Patent metadata

Field	Value
Publication number	US-9706649-B2
Application number	US-201214368998-A
Country	US
Kind code	B2
Filing date	Dec 26, 2012
Priority date	Dec 26, 2011
Publication date	Jul 11, 2017
Grant date	Jul 11, 2017

Abstract

The present invention provides a plastic substrate, including: a polyimide film; a hard coating layer formed on one side of the polyimide film; and a transparent electrode layer formed on the other side of the polyimide film. The plastic substrate has excellent light transmittance high hardness characteristics, superior ITO processability and flexibility. Further, the plastic substrate can function as both a window film and an electrode film when it is applied to a touch screen panel. Thus, the present invention provides a touch screen panel which can be slimmed by reducing the number of laminated films including the plastic substrate.

First claim

The invention claimed is:

1. A plastic substrate, comprising:
a polyimide film including a polyimide resin which is obtained by copolymerizing monomers comprising an aromatic dianhydride, an aromatic dicarbonyl compounds and an aromatic diamine, wherein the polyimide resin comprises a unit structure derived from the aromatic dianhydride, a unit structure derived from the aromatic dicarbonyl compound, and a unit structure derived from the aromatic diamine; and wherein the polyimide film has a yellowness of 5 or less and satisfying a light transmittance of 80% or more at a wavelength of 550 nm, measured by a UV spectrometer;
a first hard coating layer formed on one side of the polyimide film; and
a transparent electrode layer formed on the other side of the polyimide film.

2. The plastic substrate of claim 1 , wherein the first hard coating layer includes a polysilazane or silica, and an acrylic resin or polyurethane resin.

3. The plastic substrate of claim 1 , wherein the transparent electrode layer includes at least one selected from the group consisting of ITO, IZO, Ag and Ag nanowire.

4. The plastic substrate of claim 1 , wherein the polyimide film is surface-modified.

5. The plastic substrate of claim 4 , wherein the surface modification of the polyimide film is conducted by plasma treatment or corona treatment.

6. The plastic substrate of claim 1 , further comprising: an inorganic layer formed between the polyimide film and the transparent electrode layer, wherein the inorganic layer contains at least one selected from the group consisting of silicon oxide and silicon nitride.

7. The plastic substrate of claim 1 , further comprising: a first organic layer formed on at least one side of the transparent electrode layer, wherein the organic layer is a cured layer of an active energy ray-curable composition including: polyurethane (meth)acrylate obtained by reacting a (meth)acrylate compound containing (meth)acrylate having one hydroxyl group in one molecule thereof; and a compound having one (meth)acryloyl group.

8. The plastic substrate of claim 1 , further comprising: a second organic layer formed on the hard coating layer, wherein the organic layer is a cured layer of an active energy ray-curable composition including: polyurethane (meth)acrylate obtained by reacting a (meth)acrylate compound containing (meth)acrylate having one hydroxyl group in one molecule thereof; and a compound having one (meth)acryloyl group.

9. The plastic substrate of claim 1 , further comprising: a second hard coating layer formed between the polyimide film and the transparent electrode layer.

10. The plastic substrate of claim 1 , wherein the first hard coating layer has a thickness of 1-50 μm.

11. The plastic substrate of claim 1 , wherein the transparent electrode layer has a thickness of 1-100 nm.

12. The plastic substrate of claim 7 , wherein the first organic layer has a thickness of 1-10 μm.

13. The plastic substrate of claim 6 , wherein the inorganic layer has a thickness of 1-100 nm.

14. The plastic substrate of claim 1 , wherein the polyimide resin comprises: a unit structure derived from at least one aromatic dianhydride selected from the group consisting of 2,2-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride, 4-(2,5-dioxotetrahydrofuran-3-yl)-1,2,3,4-tetrahydronaphthalene-I,2-dicarboxylic anhydride, 9,9-bis(trifluoromethyl)-2,3,6,7-xanthene tetracarboxyl dianhydride and 4,4′-(4,4′-isoproylidenediphenoxy)bis(phthalic anhydride), a unit structure derived from at least one aromatic dianhydride selected from the group consisting of pyromellitic dianhydride, biphenyltetracarboxylic dianhydride and oxydiphthalic dianhydride; a unit structure derived from at least one aromatic diamine selected from the group consisting of 2,2-bis[4-(4-aminophenoxy)-phenyl]propane, 2,2′-bis(trifluoromethyl)-4,4′-diaminobiphenyl, 3,3′-bis(trifluoromethyl)-4,4′-diaminobiphenyl, 4,4′-bis(3-aminophenoxy)diphenylsulfone, bis(3-aminophenyl)sulfone, bis(4-aminophenyl)sulfone, 1,3-bis(3-aminophenoxy)benzene, 1,4-bis(4-aminophenoxy)benzene, 2,2′-bis[3(3-aminophenoxy)phenyl]hexafluoropropane, 2,2′-bis[4(4-aminophenoxy)phenyl]hexafluoropropane, 2,2′-bis(3-aminophenyl)hexafluoropropane (3,3′-6F), 2,2′-bis(4-aminophenyl)hexafluoropropane (4,4′-6F) and oxydianiline; and a unit structure derived from at least one aromatic dicarbonyl compound selected from the group consisting of p-terephthaloyl chloride, terephthalic acid, iso-phthaloyl dichloride and 4,4′-benzoyl chloride.

15. The plastic substrate of claim 1 , wherein the polyimide film has an average linear expansion coefficient of 30.0 ppm/° C. or less, which was measured at a temperature range of 50-250° C. by thermo-mechanical analysis based on a thickness of 50-200 μm.

16. The plastic substrate of claim 1 , wherein the plastic substrate has a surface resistance of 50 Ω/sq. or less, when a thickness of the transparent electrode layer is 100 nm.

17. A method of manufacturing a plastic substrate, comprising the steps of:
forming a hard coating layer on one side of a polyimide film including imides of polyimide resin precursors prepared by a polymerization of aromatic dianhydrides, aromatic dicarbonyl compounds and aromatic dimaines, having a yellowness of 5 or less, and satisfying a light transmittance of 80% or more at a wavelength of 550 nm, as measured by a UV spectrometer; and
forming a transparent electrode layer on the other side of the polyimide film,
wherein the step of forming the transparent electrode layer includes a step of depositing the transparent electrode layer on the other side of the polyimide film and heat-treating the deposited transparent electrode layer, wherein the deposition or heat treatment is performed at 100 to 250° C.

18. A touch screen panel, comprising the plastic substrate of claim 1 .

19. The plastic substrate of claim 9 , wherein the hard coating layer has a thickness of 1-50 μm.

20. The plastic substrate of claim 8 , wherein the organic layer has a thickness of 1-10 μm.

21. The plastic substrate of claim 9 , wherein the second hard coating layer has a thickness of 1-50 μm.

22. The plastic substrate of claim 8 , wherein the organic layer has a thickness of 1-10 μm.

Assignees

• Kolon Inc

Inventors

• Jung Hak Gee
• Park Hyo Jun
• Ju Chul Ha

Classifications

• C08J7/0423

  with at least one layer of inorganic material and at least one layer of a composition containing a polymer binder · CPC title

• C08J2433/06

  of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical · CPC title

• H01B3/30

  plastics; resins; waxes · CPC title

• C08J2379/08

  Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors · CPC title

• C08J2475/04

  Polyurethanes · CPC title