Process for producing an electrode for an electrochemical energy storage means and electrode

Patent metadata

Field	Value
Publication number	US-9705129-B2
Application number	US-201314403299-A
Country	US
Kind code	B2
Filing date	Apr 24, 2013
Priority date	May 23, 2012
Publication date	Jul 11, 2017
Grant date	Jul 11, 2017

Abstract

The subject matter of the present is a method for manufacturing an electrode for an electrochemical energy reservoir, in particular for a lithium-ion battery, encompassing the method steps of: a) furnishing a mixture of initial substances for formation of a lithium titanate; b) calcining the mixture of initial substances for formation of a lithium titanate; c) adding to the mixture of initial substances for formation of a lithium titanate, before and/or after calcination, a component encompassing sulfur and optionally lithium; and/or d) adding a pore former, before and/or after calcination, to the mixture of initial substances for formation of a lithium titanate; e) sintering the calcined product; and f) optionally removing the pore former from the calcined and optionally sintered product. Electrodes having a particularly defined pore structure can be generated with a method of this kind, thereby making possible particularly good capacity that is stable over the long term. A further subject is an electrode for use in a lithium-ion battery, as well as a lithium-ion battery.

First claim

What is claimed is:

1. A method for manufacturing an electrode for an electrochemical energy reservoir, comprising:
furnishing a mixture of initial substances for formation of a lithium titanate, wherein the mixture of initial substances for formation of the lithium titanate includes at least one of lithium carbonate and titanium dioxide;
calcining the mixture of initial substances for formation of the lithium titanate;
adding to the mixture of initial substances for formation of the lithium titanate at least one of:
at least one of before and after calcination, a component encompassing sulfur, wherein the component is present in the form of particles having a size less than or equal to 20 nm and includes at least one of lithium sulfide and lithium sulfate, and
at least one of before and after calcination, a pore former; and

sintering the calcined product.

2. The method as recited in claim 1 , wherein the electrochemical energy reservoir includes a lithium-ion battery.

3. The method as recited in claim 1 , wherein the component includes lithium.

4. The method as recited in claim 1 , further comprising removing the pore former from the calcined and sintered product.

5. The method as recited in claim 1 , further comprising:
at least one of chemically and electrochemically inserting lithium into the calcined and sintered product.

6. The method as recited in claim 1 , wherein the mixture of initial substances for formation of the lithium titanate includes at least one iron-containing initial material for formation of an iron-doped lithium titanate.

7. The method as recited in claim 5 , wherein a lithium titanate corresponding to the general chemical formula Li 4+x−y Fe 3y Ti 5−2y O 12 is manufactured, where 0<y≦1 and 0≦x≦3.

8. The method as recited in claim 7 , where 0.2≦y≦1.

9. The method as recited in claim 1 , wherein the pore former includes at least one of starch and graphite.

10. The method as recited in claim 1 , further comprising removing the pore former from the calcined and sintered product by being burned out.

11. The method as recited in claim 2 , wherein the manufactured electrode includes a matrix made of the lithium titanate, the matrix including at least partly closed pores in which at least one sulfur component is disposed.

12. The method as recited in claim 11 , wherein the lithium-ion battery includes a lithium-sulfur battery.

13. The method as recited in claim 11 , wherein the lithium titanate has the general formula Li 4+x−y Fe 3y Ti 5−2y O 12 , where 0≦y≦1 and 0≦x≦3.

14. The method as recited in claim 11 , wherein the lithium titanate has the general formula Li 4+x−y Fe 3y Ti 5−2y O 12 , where 0.2≦y≦1 and 0≦x≦3.

15. The method as recited in claim 11 , wherein the component includes lithium.

16. The method as recited in claim 11 , wherein the matrix includes pores having a size in a range of less than or equal to 20 nm.

17. A method for manufacturing an electrode for an electrochemical energy reservoir, comprising:
furnishing a mixture of initial substances for formation of a lithium titanate;
calcining the mixture of initial substances for formation of the lithium titanate;
adding to the mixture of initial substances for formation of the lithium titanate at least one of:
at least one of before and after calcination, a component comprising sulfur, lithium sulfide, or lithium sulfate, wherein the component is present in the form of particles having a size less than or equal to 20 nm, and
at least one of before and after calcination, a pore former; and

sintering the calcined product.

18. A method for manufacturing an electrode for an electrochemical energy reservoir, comprising:
furnishing a mixture of initial substances for formation of a lithium titanate;
calcining the mixture of initial substances for formation of the lithium titanate;
adding to the mixture of initial substances for formation of the lithium titanate at least one of:
at least one of before and after calcination, a component comprising lithium sulfide, wherein the component is present in the form of particles having a size less than or equal to 20 nm, and
at least one of before and after calcination, a pore former; and

sintering the calcined product.

19. A method for manufacturing an electrode for an electrochemical energy reservoir, comprising:
furnishing a mixture of initial substances for formation of a lithium titanate;
calcining the mixture of initial substances for formation of the lithium titanate;
adding to the mixture of initial substances for formation of the lithium titanate at least one of:
at least one of before and after calcination, a component comprising sulfur, lithium sulfide, or lithium sulfate, and
at least one of before and after calcination, a pore former;

sintering the calcined product; and
at least one of chemically and electrochemically inserting lithium into the calcined and sintered product, wherein chemically inserting lithium into the calcined and sintered product comprises adding butyllithium to the calcined and sintered product.

20. A method for manufacturing an electrode for an electrochemical energy reservoir, comprising:
furnishing a mixture of initial substances for formation of a lithium titanate;
calcining the mixture of initial substances for formation of the lithium titanate;
adding to the mixture of initial substances for formation of the lithium titanate, at least one of before and after calcination, a pore former comprising a thermoplastic polymer; and
sintering the calcined product.

Assignees

• Bosch Gmbh Robert

Inventors

• Tenzer Martin
• Grimminger Jens
• Schumann Bernd
• Eisele Ulrich
• Sorhage Constanze
• Kerkamm Ingo

Classifications

• H01M2004/028

  Positive electrodes · CPC title

• H01M4/485

  of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy (H01M4/505, H01M4/525 take precedence) · CPC title

• H01M4/0471

  involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis · CPC title

• H01M10/052

  Li-accumulators · CPC title

• H01M10/0562

  Solid materials · CPC title