Chemical looping fluidized-bed concentrating solar power system and method

Patent metadata

Field	Value
Publication number	US-9702348-B2
Application number	US-201414243775-A
Country	US
Kind code	B2
Filing date	Apr 2, 2014
Priority date	Apr 3, 2013
Publication date	Jul 11, 2017
Grant date	Jul 11, 2017

Abstract

A concentrated solar power (CSP) plant comprises a receiver configured to contain a chemical substance for a chemical reaction and an array of heliostats. Each heliostat is configured to direct sunlight toward the receiver. The receiver is configured to transfer thermal energy from the sunlight to the chemical substance in a reduction reaction. The CSP plant further comprises a first storage container configured to store solid state particles produced by the reduction reaction and a heat exchanger configured to combine the solid state particles and gas through an oxidation reaction. The heat exchanger is configured to transfer heat produced in the oxidation reaction to a working fluid to heat the working fluid. The CSP plant further comprises a power turbine coupled to the heat exchanger, such that the heated working fluid turns the power turbine, and a generator coupled to and driven by the power turbine to generate electricity.

First claim

What is claimed is:

1. A concentrating solar power plant comprising:
a receiver containing a solid metal oxide (solid Me x O y ), the receiver configured to receive thermal energy from sunlight and transfer the thermal energy to the solid Me x O y ;
a fluidized-bed heat exchanger containing a reduced solid metal oxide (solid Me x O y-2 ) and the solid Me x O y , the fluidized-bed heat exchanger configured to transfer heat from at least one of the solid Me x O y or the solid Me x O y-2 to a working fluid in a working fluid circuit;
a first gas that fluidizes the solid Me x O y and the solid Me x O y-2 in the fluidized-bed heat exchanger;
a first turbine fluidly coupled to the working fluid circuit; and
a second turbine fluidly coupled to the fluidized-bed heat exchanger, wherein:
the thermal energy from sunlight converts in the receiver at least a portion of the solid Me x O y to the solid Me x O y-2 resulting in the storage of chemical energy in the solid Me x O y-2 and the formation of an oxygen (O 2 ) stream,
at least a portion of the O 2 stream is delivered to the fluidized-bed heat exchanger to form at least a portion of the first gas, and is ignited and reacted with the solid Me x O y-2 in the fluidized-bed heat exchanger to convert at least a portion of the solid Me x O y-2 to the solid Me x O y and a heated second gas,
the conversion of the solid Me x O y-2 to the solid Me x O y releases at least a portion of the chemical energy to form the heat transferred to the working fluid,
the working fluid is directed to the first turbine such that the first turbine produces a first source of electricity, and
the heated second gas is directed to the second turbine such that the second turbine produces a second source of electricity.

2. A method comprising:
directing sunlight to a receiver containing a solid metal oxide (solid Me x O y );
transferring thermal energy from the sunlight to the solid Me x O y such that at least a portion of the solid Me x O y is converted to oxygen (O 2 ) and a reduced solid metal oxide (solid Me x O y-2 ) containing stored chemical energy;
in a fluidized-bed heat exchanger, fluidizing the solid Me x O y-2 with a first gas comprising O 2 produced in the transferring such that the fluidizing results in the igniting and reacting, in the fluidized-bed heat exchanger, of at least a portion of the solid Me x O y-2 with at least a portion of the O 2 produced in the transferring to form the solid Me x O y and a heated second gas, such that the reacting results in the converting of a portion of the stored chemical energy to heat;
transferring at least a portion of the heat to a working fluid to form a heated working fluid;
generating a first portion of electricity by passing the heated working fluid through a first turbine; and
directing the heated second gas through a second turbine resulting in the generating of a second portion of electricity.

3. The method of claim 2 , further comprising:
after the fluidizing, separating the second gas from the solid Me x O y ;
storing the separated solid Me x O y ; and
selectively delivering at least a portion of the separated solid Me x O y to the receiver for the transferring of the thermal energy from the sunlight to the separated solid Me x O y .

4. The method of claim 2 , further comprising:
before the fluidizing, compressing the first gas; and
delivering the compressed first gas to the fluidized-bed heat exchanger to perform the fluidizing.

Assignees

• Alliance Sustainable Energy

Inventors

• Ma Zhiwen

Classifications

• F28D20/003

  using thermochemical reactions · CPC title

• Y02E10/46

  Conversion of thermal power into mechanical power, e.g. Rankine, Stirling or solar thermal engines · CPC title

• F03G6/067 Primary

  Binary cycle plants where the fluid from the solar collector heats the working fluid via a heat exchanger · CPC title

• F03G6/064 Primary

  having a gas turbine cycle, i.e. compressor and gas turbine combination · CPC title

• C01B13/08

  from air with the aid of metal oxides, e.g. barium oxide, manganese oxide {(C01B13/0292 takes precedence)} · CPC title