Process for producing purified polysaccharide fibers, purified polysaccharide fibers and tires

Patent metadata

Field	Value
Publication number	US-9702062-B2
Application number	US-201414892246-A
Country	US
Kind code	B2
Filing date	May 21, 2014
Priority date	May 21, 2013
Publication date	Jul 11, 2017
Grant date	Jul 11, 2017

Abstract

A process for producing purified polysaccharide fiber of the present invention includes bringing a polysaccharide solution, which is obtained by dissolving a polysaccharide raw material in a liquid containing an ionic liquid, into contact with a solidification liquid containing an ionic liquid, and performing dry-wet spinning on polysaccharide, in which the concentration of the ionic liquid in the solidification liquid is 0.4% by weight to 70% by weight, and a distance D from a site where the polysaccharide solution is extruded in the form of fiber to a site where the extruded polysaccharide solution comes into contact with the solidification liquid is 50 mm to 120 mm.

First claim

What is claimed is:

1. A process for producing purified polysaccharide fiber, comprising:
bringing a polysaccharide solution, which is obtained by dissolving a polysaccharide raw material in a liquid containing an ionic liquid, into contact with a first solidification liquid containing an ionic liquid in a first solidification bath; and
performing dry-wet spinning on polysaccharide,
bringing polysaccharide into contact with a second solidification liquid containing an ionic liquid in a second solidification bath,
wherein the concentration of the ionic liquid in the first solidification liquid is 0.4% by weight to 70% by weight and the concentration of the ionic liquid in the second solidification liquid is less than the concentration of the ionic liquid in the first solidification liquid, and
a distance D from a site where the polysaccharide solution is extruded in the form of fiber to a site where the extruded polysaccharide solution comes into contact with the first solidification liquid is 50 mm to 120 mm.

2. The process for producing purified polysaccharide fiber according to claim 1 ,
wherein the concentration of the ionic liquid in the first solidification liquid is 20% by weight to 40% by weight.

3. The process for producing purified polysaccharide fiber according to claim 1 ,
wherein each of the ionic liquid in the polysaccharide solution and the ionic liquid in the first and second solidification liquids is composed of a cationic portion and an anionic portion, and
the anionic portion contains one or more kinds of ions selected from the group consisting of a phosphinate ion represented by the following Formula (C2), a phosphate ion, and a phosphonate ion,

in the formula, each of X 1 and X 2 independently represents a hydrogen atom, a hydroxyl group, or an alkoxy group having 1 to 4 carbon atoms.

4. The process for producing purified polysaccharide fiber according to claim 3 ,
wherein the cationic portion is an imidazolium ion represented by the following Formula (C1),

in the formula, R 1 represents an alkyl group having 1 to 4 carbon atoms or an alkenyl group having 2 to 4 carbon atoms; R 2 represents a hydrogen atom or a methyl group; and R 3 represents an alkyl group having 1 to 8 carbon atoms or an alkenyl group having 2 to 8 carbon atoms.

5. The process for producing purified polysaccharide fiber according to claim 1 ,
wherein at least one of the ionic liquid in the polysaccharide solution and the ionic liquid in the first solidification liquid is 1-ethyl-3-methylimidazolium diethylphosphate.

6. The process for producing purified polysaccharide fiber according to claim 1 ,
wherein the process comprises two or more solidification baths and a relationship between a concentration X n of the ionic liquid in the n th solidification bath and a concentration X n+1 of the ionic liquid in the (n+1) th solidification bath satisfies X n+1 ≦0.8X n .

7. The process for producing purified polysaccharide fiber according to claim 1 ,
wherein the process comprises two or more solidification baths and a relationship between a concentration X n of the ionic liquid in the n th solidification bath and a concentration X n+1 of the ionic liquid in the (n+1) th solidification bath satisfies X n+1 ≦0.6X n .

8. The process for producing purified polysaccharide fiber according to claim 1 ,
wherein the process comprises two or more solidification baths and a relationship between a concentration X n of the ionic liquid in the n th solidification bath and a concentration X n+1 of the ionic liquid in the (n+1) th solidification bath satisfies X n+1 ≦0.4X n .

Assignees

• Bridgestone Corp

Inventors

• Sugimoto Kenichi
• Koide Mitsuharu

Classifications

• C08L2205/16

  Fibres; Fibrils · CPC title

• B29L2031/731

  Filamentary material, i.e. comprised of a single element, e.g. filaments, strands, threads, fibres (cables B29L2031/707) · CPC title

• B29K2005/00

  Use of polysaccharides or derivatives as moulding material · CPC title

• D01D5/06

  Wet spinning methods {(D01D5/0046 takes precedence)} · CPC title

• C08L1/02

  Cellulose; Modified cellulose · CPC title