Materials and methods for dispersing nano particles in matrices with high quantum yields and stability

Patent metadata

Field	Value
Publication number	US-9701897-B2
Application number	US-201314373497-A
Country	US
Kind code	B2
Filing date	Jan 25, 2013
Priority date	Feb 3, 2012
Publication date	Jul 11, 2017
Grant date	Jul 11, 2017

Abstract

The invention provides a process for the production of a solid polymer with embedded luminescent nano particles, comprising (1) mixing luminescent nano particles with an outer surface coated with capping molecules comprising a first functional group and a second functional group and a precursor of a solid polymer, and (2) allowing the solid polymer to be formed; wherein the first functional group is configured to bind to the outer surface of the quantum dot and the second functional group is miscible with the precursor of the solid polymer and/or is able to react with the precursor of the solid polymer. The invention also provides a luminescent polymeric article comprising a solid polymer with in the polymer article embedded luminescent nano particles with an outer surface coated with capping molecules comprising a first functional group and a second functional group.

First claim

The invention claimed is:

1. A process for the production of a solid polymer with embedded luminescent nano particles, the process comprising:
mixing luminescent nano particles having outer surfaces coated with capping molecules, the capping molecules comprising a first functional group and a second functional group, with a precursor of the solid polymer; and
allowing the solid polymer to be formed, thereby producing the solid polymer with embedded nano particles;
wherein the first functional group is configured to bind to the outer surfaces of the luminescent nano particles and wherein the second functional group has one or more functions selected from the group consisting of being miscible with the precursor of the solid polymer and being able to react with the precursor of the solid polymer,
wherein the capping molecules comprise two types of capping molecules, wherein the first functional group of the first type of capping molecules comprises a metal ion having a coordinating functionality, and wherein the first functional group of the second type of capping molecules has a Lewis base functionality.

2. The process according to claim 1 , wherein the second functional group of the first type of capping molecules and the second functional group of the second type of capping molecules are the same.

3. The process according to claim 1 , wherein the precursor of a solid polymer comprises monomers that are able to form the polymer upon polymerization.

4. The process according to claim 1 , wherein the precursor of the solid polymer comprises a polymer mixed with a solvent.

5. The process according to claim 1 , wherein the second functional group is one of a siloxane, a styrene, and an acrylate.

6. The process according to any claim 1 , wherein the nano particles are selected from the group consisting of CdS, CdSe, CdTe, ZnS, ZnSe, ZnTe, HgS, HgSe, HgTe, CdSeS, CdSeTe, CdSTe, ZnSeS, ZnSeTe, ZnSTe, HgSeS, HgSeTe, HgSTe, CdZnS, CdZnSe, CdZnTe, CdHgS, CdHgSe, CdHgTe, HgZnS, HgZnSe, HgZnTe, CdZnSeS, CdZnSeTe, CdZnSTe, CdHgSeS, CdHgSeTe, CdHgSTe, HgZnSeS, HgZnSeTe and HgZnSTe.

7. A luminescent polymeric article comprising a solid polymer within the polymer article, wherein the solid polymer contains embedded luminescent nano particles with outer surfaces coated with capping molecules, the capping molecules comprising a first functional group and a second functional group,
wherein the first functional group of a first type of capping molecules comprises a metal ion having a coordinating functionality, and wherein the first functional group of a second type of capping molecules has a Lewis base functionality.

8. The polymeric article according to claim 7 , wherein at least part of the second functional group is interwoven with polymer chains of the solid polymer.

9. The polymeric article according to claim 7 , wherein at least part of the second functional group is part of a polymer chain of the solid polymer.

10. The polymeric article according to claim 7 , wherein the molar ratio of the first type of capping molecules to the second type of capping molecules is in the range of 0.8-1.2.

11. The polymeric article according to claim 7 , wherein the second functional group is one of a siloxane, a styrene, and an acrylate.

12. The polymeric article according to claim 7 , wherein the nano particles are selected from the group consisting of CdS, CdSe, CdTe, ZnS, ZnSe, ZnTe, HgS, HgSe, HgTe, CdSeS, CdSeTe, CdSTe, ZnSeS, ZnSeTe, ZnSTe, HgSeS, HgSeTe, HgSTe, CdZnS, CdZnSe, CdZnTe, CdHgS, CdHgSe, CdHgTe, HgZnS, HgZnSe, HgZnTe, CdZnSeS, CdZnSeTe, CdZnSTe, CdHgSeS, CdHgSeTe, CdHgSTe, HgZnSeS, HgZnSeTe and HgZnSTe, and wherein the polymeric article is selected from the group consisting of a coating, a self supporting layer, and a plate, and wherein the polymeric article is transmissive for light having a wavelength selected from the range of 380-750 nm.

13. A lighting unit comprising a light source configured to generate light source light and a light converter configured to convert at least part of the light source light into converter light, wherein the light converter comprises a solid polymer or a polymeric article containing embedded luminescent nano particles,
wherein the luminescent nano particles have outer surfaces coated with capping molecules, the capping molecules comprising a first functional group and a second functional group, and
wherein the first functional group of a first type of capping molecules comprises a metal ion having a coordinating functionality, and wherein the first functional group of a second type of capping molecules has a Lewis base functionality.

14. A luminescent material comprising a plurality of nano particles,
wherein the nano particles comprise quantum dot particles, the quantum dot particles comprising outer surfaces coated with capping molecules,
wherein the capping molecules comprise —[—Si(R) 2 —O—] n ,
wherein n=1-20,
wherein R is selected from the group consisting of methyl and phenyl,
wherein the capping molecules comprise a first type and a second type of capping molecules,
wherein capping molecules of the first type further comprise a functional group including a metal ion having a coordinating functionality, and
wherein the capping molecules of the second type further comprises a functional group having a Lewis base functionality.

15. The luminescent material according to claim 14 , wherein the molar ratio of the first type of capping molecules to the second type of capping molecules is in the range of 0.8-1.2.

16. The process of claim 1 , wherein the luminescent nano particles comprise quantum dots.

17. The lighting unit of claim 13 , wherein the second functional group of the capping molecules has one or more functions selected from the group consisting of being miscible with a precursor of the solid polymer or a polymeric article and being able to react with the precursor.

Assignees

• Koninklijke Philips Nv

Inventors

• Xu Shu
• Hikmet Rifat Ata Mustafa

Classifications

• F21S13/00

  Non-electric lighting devices or systems employing a point-like light source; Non-electric lighting devices or systems employing a light source of unspecified shape · CPC title

• C09K11/025 Primary

  non-luminescent particle coatings or suspension media · CPC title

• C08K3/00

  Use of inorganic substances as compounding ingredients · CPC title

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title

• Y10S977/779

  Possessing nanosized particles, powders, flakes, or clusters other than simple atomic impurity doping · CPC title