Method for enhanced fracture cleanup using redox treatment

Patent metadata

Field	Value
Publication number	US-9701894-B2
Application number	US-201514689901-A
Country	US
Kind code	B2
Filing date	Apr 17, 2015
Priority date	Apr 17, 2014
Publication date	Jul 11, 2017
Grant date	Jul 11, 2017

Abstract

A method for improved hydrocarbon recovery from a formation due to cleanup of a residual viscous material is provided. The method comprising the steps of fracturing the formation with a fracturing fluid to generate fractures, the fracturing fluid comprising a viscous fluid component operable to fracture the formation leaving behind residual viscous material in the fractures, the viscous fluid having a viscosity; a proppant component comprising a proppant, the proppant operable to hold open the fractures, wherein the proppant component is carried to the fractures by the viscous fluid component; and a cleanup fluid, the cleanup fluid comprising: an acid precursor operable to trigger an exothermic reaction component, and the exothermic reaction component operable to generate heat, where the generated heat is operable to reduce a viscosity of the residual viscous material to create a reduced viscosity material operable to flow from the formation.

First claim

What is claimed is:

1. A method for improved hydrocarbon recovery from a formation due to cleanup of a residual viscous material, the method comprising the steps of:
fracturing the formation with a fracturing fluid to generate fractures, the fracturing fluid comprising:
a viscous fluid component, the viscous fluid component operable to fracture the formation to create the fractures leaving behind the residual viscous material in the fractures, the viscous fluid component having a viscosity;
a proppant component, the proppant component operable to hold open the fractures,
wherein the proppant component is carried to the fractures by the viscous fluid component; and

after fracturing the formation, reducing a viscosity of the residual viscous material with a cleanup fluid, the cleanup fluid comprising:
an acid precursor, the acid precursor operable to trigger an exothermic reaction component, and the acid precursor comprising at least one component selected from the group consisting of: triacetin, methyl acetate, hydrochloric acid, and acetic acid; and
the exothermic reaction component operable to generate heat after the proppant component has been placed in the fractures, and the exothermic reaction component comprising at least one component selected from the group consisting of: urea, sodium hypochlorite, ammonium chloride, ammonium bromide, ammonium nitrate, ammonium sulfate, ammonium carbonate, ammonium hydroxide, sodium nitrite, and potassium nitrite,
wherein the heat is operable to reduce the viscosity of the residual viscous material to create a reduced viscosity material, the reduced viscosity material operable to flow from the formation, and wherein the method for improved hydrocarbon recovery generates substantially no foam.

2. The method of claim 1 , wherein the exothermic reaction component comprises an ammonium containing compound and a nitrite containing compound.

3. The method of claim 2 , wherein the ammonium containing compound comprises NH 4 Cl and the nitrite containing compound comprises NaNO 2 .

4. The method of claim 1 , wherein the acid precursor comprises triacetin.

5. The method of claim 1 , wherein the step of fracturing the formation with a fracturing fluid to generate fractures further comprises the step of forming auxiliary fractures and a fracture network.

6. A method to cleanup fractures in hydraulic fracturing operations, the method comprising the steps of:
fracturing a formation in a hydraulic fracturing operation to generate fractures, wherein the step of fracturing the formation comprises the step of fracturing the formation with a fracturing fluid to generate fractures, the fracturing fluid comprising:
a viscous fluid component, the viscous fluid component operable to fracture the formation to create the fractures leaving behind residual viscous material in the fractures, the viscous fluid component having a viscosity;
a proppant component, the proppant component operable to hold open the fractures, wherein the proppant component is carried to the fractures by the viscous fluid component; and

injecting a cleanup fluid into the fractures to reduce a viscosity of the residual viscous material by generation of heat produced from an exothermic reaction, wherein the exothermic reaction is triggered to react at least in part by heat of the formation, the cleanup fluid operable to reduce the viscosity of the residual viscous material after the proppant component has been placed in the fractures, wherein the method to cleanup fractures generates substantially no foam.

7. The method of claim 6 , wherein the cleanup fluid comprises:
an acid precursor, the acid precursor operable to trigger an exothermic reaction component, and the acid precursor comprising at least one component selected from the group consisting of: triacetin, methyl acetate, hydrochloric acid, and acetic acid; and
the exothermic reaction component operable to generate heat, and the exothermic reaction component comprising at least one component selected from the group consisting of: urea, sodium hypochlorite, ammonium chloride, ammonium bromide, ammonium nitrate, ammonium sulfate, ammonium carbonate, ammonium hydroxide, sodium nitrite, and potassium nitrite,
wherein the heat is operable to reduce the viscosity of the residual viscous material to create a reduced viscosity material, the reduced viscosity material operable to flow from the fractures.

8. The method of claim 7 , wherein the exothermic reaction component comprises an ammonium containing compound and a nitrite containing compound.

9. The method of claim 8 , wherein the ammonium containing compound comprises NH 4 Cl and the nitrite containing compound comprises NaNO 2 .

10. The method of claim 7 , wherein the acid precursor comprises triacetin.

11. The method of claim 7 , wherein the step of fracturing the formation with a fracturing fluid to generate fractures further comprises the step of forming auxiliary fractures and a fracture network.

12. The method of claim 7 , further comprising the step of triggering the exothermic reaction component with a trigger selected from the group consisting of: a release of hydrogen ions, an increase in temperature of the exothermic reaction component, and combinations thereof.

13. The method of claim 6 , where the step of fracturing the formation comprises adding a base to the fracturing fluid to increase pH of the fracturing fluid and the formation.

14. The method of claim 6 , where the step of injecting the cleanup fluid into the fractures to reduce the viscosity of the residual viscous material reduces the viscosity of the residual viscous material to a reduced viscosity, the reduced viscosity being about 1/10 of the viscosity of the residual viscous material.

15. The method of claim 6 , further comprising the step of triggering an exothermic reaction component in the cleanup fluid by allowing an internal formation temperature of the formation to reach about 120° F.

16. The method of claim 6 , further comprising the steps of: initially raising pH of the fracturing fluid to between about pH 9 and about pH 12, and after injecting the cleanup fluid into the fractures, lowering pH of the cleanup fluid to below about 6.

Assignees

• Saudi Arabian Oil Co

Inventors

• Al-Nakhli Ayman R
• Abass Hazim H
• Al-Otaibi Ahmad S

Classifications

• E21B43/26

  by forming crevices or fractures · CPC title

• C09K8/52 Primary

  Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning · CPC title

• E21B43/267

  reinforcing fractures by propping · CPC title

• C09K8/80

  Compositions for reinforcing fractures, e.g. compositions of proppants used to keep the fractures open · CPC title

• C09K8/592

  Compositions used in combination with generated heat, e.g. by steam injection · CPC title