Active energy ray-curable composition, and ink composition for inkjet recording use which is prepared using said composition

Patent metadata

Field	Value
Publication number	US-9701857-B2
Application number	US-201414893169-A
Country	US
Kind code	B2
Filing date	May 27, 2014
Priority date	May 27, 2013
Publication date	Jul 11, 2017
Grant date	Jul 11, 2017

Abstract

There are provided an active energy ray-curable composition containing a polymerizable compound represented by General Formula (1), a polymerizable compound represented by General Formula (2), and a photopolymerization initiator, and an ink composition for inkjet recording use.

CH 2 ═CR 1 —CO—O—R 2 —O—CH═CH—R 3   (1)

(In Formula (1), R 1 represents a hydrogen atom or a methyl group, R 2 represents an organic residue having 2 to 20 carbon atoms, and R 3 represents a hydrogen atom or an organic residue having 1 to 11 carbon atoms.)

(In Formula (2), each of R 4 and R 5 independently represents a hydrogen atom or a methyl group, each of R 6a , R 6b , and R 6c independently represents a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, or an alkoxy group having 1 to 4 carbon atoms, and m+n represents an integer of 0 to 4.).

First claim

The invention claimed is:

1. An active energy ray-curable composition, comprising:
a polymerizable compound which is 2-(2-vinyloxyethoxy)ethyl (meth)acrylate;
a polymerizable compound which is 3-methyl-1,5-pentanediol di(meth)acrylate; and
a photopolymerization initiator which is 2,4,6-trimethyl benzoyl-diphenyl-phosphineoxide.

2. The active energy ray-curable composition according to claim 1 , further comprising:
a photopolymerization initiator represented by General Formula (4),

wherein each of R 20 to R 30 independently represents hydrogen or an alkyl group having 1 to 12 carbon atoms, a cyclic aliphatic hydrocarbon group, a phenyl group, or an alkoxy group having 1 to 12 carbon atoms.

3. The active energy ray-curable composition according to claim 2 , further comprising:
a photopolymerization initiator represented by General Formula (5); and/or
a photopolymerization initiator represented by General Formula (7),

wherein each of R 31 , R 32 , and R 33 independently represents a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, a halogen atom, a cyano group, a phenyl group, a nitro group, —SCH 3 , —O—CO—R 35 , —CO—O—R 35 , or —CO—R 35 (wherein R 35 represents an alkyl group having 1 to 4 carbon atoms), and R 34 represents an alkyl group having 1 to 10 carbon atoms or a group represented by General Formula (6),

wherein each of R 36 , R 37 , R 38 , R 39 , and R 40 independently represents a hydrogen atom, an alkyl group having 1 to 12 carbon atoms, an alkoxyl group having 1 to 6 carbon atoms, a halogen atom, a cyano group, a phenyl group, a nitro group, —SCH 3 , —O—CO—R 41 , —CO—O—R 41 , or —CO—R 41 (wherein R 41 represents an alkyl group having 1 to 4 carbon atoms), and

wherein each of R 42 to R 49 independently represents a hydrogen atom, an alkyl group, a halogen atom, a hydroxy group, a cyano group, a nitro group, an amino group, an alkylthio group, an alkylamino group (which includes cases of being monosubstituted and disubstituted), an alkoxy group, an alkoxycarbonyl group, an acyloxy group, an acyl group, a carboxy group, or a sulfo group.

4. A cured product formed by curing the active energy ray-curable composition according to claim 1 .

5. An ink composition for inkjet recording use,
wherein the active energy ray-curable composition according to claim 1 is used.

Assignees

• Dainippon Ink & Chemicals
• Dic Corp (Tokyo)

Inventors

• Yamada Tomokazu
• Tanimoto Yoichi

Classifications

• C08F2/50

  with sensitising agents · CPC title

• C09D133/14

  of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen · CPC title

• C09D11/101

  Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing · CPC title

• C08F218/06

  Vinyl formate · CPC title

• C09D11/322

  Pigment inks · CPC title