Polymeric blends and methods of using same

Patent metadata

Field	Value
Publication number	US-9701823-B2
Application number	US-201213664118-A
Country	US
Kind code	B2
Filing date	Oct 30, 2012
Priority date	Nov 16, 2011
Publication date	Jul 11, 2017
Grant date	Jul 11, 2017

Abstract

A composition comprising a low density polyethylene (LDPE) and a metallocene-catalyzed linear low density polyethylene (mLLDPE) wherein the composition when extruded as a molten resin displays a neck-in value that is about equal to or increased by less than about 10% of the neck-in value observed when using the LDPE alone. A method comprising blending a LDPE and a mLLDPE of this disclosure to form a polymer blend having a miscibility factor of 1; extruding the polymer blend onto a substrate wherein the extruded polymer blend has a neck-in that is about equal to or increased by less than about 10% of the neck-in value observed when using the LDPE alone and wherein an amount of trim waste produced is equal to or about 10% less trim waste than the amount of trim waste produced when utilizing an extrusion coating using LDPE alone.

First claim

What is claimed is:

1. A composition comprising:
(i) a low density polyethylene homopolymer (LDPE), wherein the LDPE has a melt index of about 5.1 g/10 min, a melting point of about 108° C., a Vicat softening temperature of about 100° C., and a density of about 0.923 g/cc; and
(ii) a metallocene-catalyzed linear low density copolymer of ethylene and hexene (mLLDPE), wherein the mLLDPE has a density of about 0.914 g/cc, and a melt index of 0.9 g/10 min;
wherein the composition comprises from about 5 wt. % to about 50 wt. % of the mLLDPE based on the total weight of the composition, and when extruded as a molten resin displays a neck-in value that is about equal to or increased by less than 10% of the neck-in value observed when using the LDPE alone.

2. The composition of claim 1 wherein the LDPE homopolymer has a water vapor transmission rate (WVTR) of about 18 g/m 2 /day and an oxygen transmission rate of about 7200 cm 3 /m 2 /day.

3. The composition of claim 1 wherein the mLLDPE is produced using a single site metallocene.

4. The composition of claim 1 wherein the composition has a compatibility rating of 1.

5. The composition of claim 1 wherein the mLLDPE has a melting point of from about 112° C. to about 120° C.

6. The composition of claim 1 wherein the mLLDPE has a Vicat softening temperature of from about 100° C. to about 106° C.

7. An extrusion coating prepared from the composition of claim 1 .

8. The coating of claim 7 having a heat seal strength of from about 5.0 lbs./inch to about 6.0 lbs./inch.

9. The coating of claim 7 having a hot tack window of from about 100° C. to about 105° C. and a seal initiation temperature of from about 90° C. to about 100° C.

10. The coating of claim 7 having a thickness of from about 0.60 mil to about 4.0 mil.

11. The composition of claim 1 having a miscibility rating of about 1.

12. The composition of claim 1 which can be extruded as a molten resin up to a temperature of 320° C.

13. The composition of claim 1 wherein the composition displays a neck-in value that is about equal to or increased by less than about 7% of the neck-in value observed when using the LDPE alone.

14. The composition of claim 1 wherein the composition displays a neck-in value that is about equal to or increased by less than about 5% of the neck-in value observed when using the LDPE alone.

15. The composition of claim 1 wherein the composition displays a neck-in value that is about equal to or increased by less than about 3% of the neck-in value observed when using the LDPE alone.

16. The composition of claim 1 wherein the composition displays a neck-in value that is about equal to or increased by less than about 1% of the neck-in value observed when using the LDPE alone.

17. The composition of claim 13 wherein the mLLDPE in the form of a film having a thickness of 1 mil has a tensile strength at yield of 1480 psi in the machine direction and 1350 psi in the transverse direction, a tensile strength at break of 8800 psi in the machine direction and 7300 psi in the transverse direction, and a 1% secant modulus of 21200 psi in the machine direction and 23900 psi in the transverse direction, each when measured in accordance with ASTM D882 at 1 mil.

18. flexible packaging container comprising the composition of claim 1 .

19. A composition comprising:
(i) a low density polyethylene homopolymer (LDPE), wherein the LDPE has a melt index of about 5.1 g/10 min, a melting point of about 108° C., a Vicat softening temperature of about 100° C., a density of about 0.923 g/cc, a water vapor transmission rate (WVTR) of about 18 g/m 2 /day and an oxygen transmission rate of about 7200 cm 3 /m 2 /day; and
(ii) a metallocene-catalyzed linear low density copolymer of ethylene and hexene (mLLDPE), wherein the mLLDPE has a density of about 0.914 g/cc, a melt index of 0.9 g/10 min, and further wherein the mLLDPE in the form of a film having a thickness of 1 mil has a tensile strength at yield of 1480 psi in the machine direction and 1350 psi in the transverse direction, a tensile strength at break of 8800 psi in the machine direction and 7300 psi in the transverse direction, and a 1% secant modulus of 21200 psi in the machine direction and 23900 psi in the transverse direction, each when measured in accordance with ASTM D882 at 1 mil;
wherein the composition comprises from about 5 wt. % to about 50 wt. % of the mLLDPE based on the total weight of the composition, and when extruded as a molten resin displays a neck-in value that is about equal to or increased by less than 10% of the neck-in value observed when using the LDPE alone.

Assignees

• Chevron Phillips Chemical Co Lp

Inventors

• Landry Jr Darrell W
• Frey Kelly R

Classifications

• C08L2314/06

  Metallocene or single site catalysts · CPC title

• C08L23/0815

  with aliphatic 1-olefins containing one carbon-to-carbon double bond · CPC title

• C09D123/0815

  Copolymers of ethene with aliphatic 1-olefins · CPC title

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C09D123/06

  Polyethylene · CPC title