Rubber mixture and vehicle tire

Patent metadata

Field	Value
Publication number	US-9701809-B2
Application number	US-201615185485-A
Country	US
Kind code	B2
Filing date	Jun 17, 2016
Priority date	Dec 20, 2013
Publication date	Jul 11, 2017
Grant date	Jul 11, 2017

Abstract

A rubber mixture for vehicle tires which exhibits improved rolling resistance behavior and improved wear properties. The rubber mixture includes: 5 to 100 phr of at least one polymer A of the formula I): 1) F-(P-Y-P-S x ) z -P-Y-P-F, wherein S is sulfur, P is an elastomer polymer chain obtained by the anionic polymerization of a conjugated diene and, optionally, a vinyl aromatic compound in the presence of a diinitiator, Y is a dicarbanion group derived from the diinitiator, x is an integer greater than or equal to 1 independently for each S x group, on the condition that x is selected from the numbers 2, 3, and 4 for at least one Sx group, z is an integer from 1 to 160, each F is a terminal group independently selected from —H, —SH, —SOH, —SCl, —SO 2 H and —SO 3 H, and at least one filler.

First claim

What is claimed is:

1. A rubber mixture, comprising:
from 5 to 100 phr of at least one polymer A of the formula I) below:
F-(P-Y-P-S x ) z -P-Y-P-F  I)

where
S is a sulfur atom;
P is an elastomeric polymer chain which has been obtained by anionic polymerization of at least one conjugated diene and, optionally, at least one vinylaromatic compound, in the presence of a diinitiator;
Y is a dicarbanion group derived from the diinitiator;
x is independently for each S x group an integer equal to or greater than 1, with the proviso that x is selected from among the numbers 2, 3, and 4 for at least one S x group;

z is an integer from 1 to 160;
each F is independently an end group selected from the group consisting of —H, —SH, —SOH, —SCl, —SSCl, —SO 2 H, and —SO 3 H; and,
at least one filler.

2. The rubber mixture as claimed in claim 1 , wherein the at least one conjugated diene is selected from the group consisting of 1,3-butadiene, isoprene, 2,3-dimethyl-1,3-butadiene, 1,3-pentadiene, 2,4-hexadiene, 1,3-hexadiene, 1,3-heptadiene, 1,3-octadiene, 2-methyl-2,4-pentadiene, cyclopentadiene, 2,4-hexadiene, and 1,3-cyclooctadiene.

3. The rubber mixture as claimed in claim 2 , wherein the at least one conjugated diene is 1,3-butadiene.

4. The rubber mixture as claimed in claim 1 , wherein the vinylaromatic compound is selected from the group consisting of styrene, 2-methylstyrene, 3-methylstyrene, 4-methylstyrene, 2,4-dimethylstyrene, 2,4,6-trimethylstyrene, alpha-methylstyrene, 2,4-diisopropylstyrene, 4-tert-butylstyrene, stilbene, vinylbenzyldimethylamine, 4-vinylbenzyl dimethylaminoethyl ether, N,N-dimethylaminoethylstyrene, tert-butoxystyrene, vinylpyridine, 1,2-divinylbenzene, 1,3-divinylbenzene, and 1,4-divinylbenzene.

5. The rubber mixture as claimed in claim 4 , wherein the vinylaromatic compound is styrene.

6. The rubber mixture as claimed in claim 1 , wherein the polymer A has the formula II) below:
F-(SBR-Y-SBR-S x ) z -SBR-Y-SBR-F,  II)

where
S is a sulfur atom;
SBR is an elastomeric polymer chain which has been obtained by anionic polymerization of 1,3-butadiene and styrene in the presence of a diinitiator;
Y is a dicarbanion group derived from the diinitiator;
x is independently for each S x group an integer equal to or greater than 1, with the proviso that x is selected from among the numbers 2, 3 and 4 for at least one S x group;
z is an integer from 1 to 160; and
each F is independently an end group selected from the group consisting of —H, —SH, —SOH, —SCl, —SSCl, —SO 2 H, and —SO 3 H.

7. The rubber mixture as claimed in claim 1 , wherein the diinitiator is at least one organolithium compound.

8. The rubber mixture as claimed in claim 1 , wherein the polymer A has a sulfur content of from 0.1 to 30 g per kg of polymer.

9. The rubber mixture as claimed in claim 1 , wherein the filler is at least one silica and/or at least one carbon black.

10. A vehicle tire, comprising at least one rubber mixture as claimed in claim 1 in at least one component of the vehicle tire.

Assignees

• Continental Reifen Deutschland Gmbh

Inventors

• Herzog Katharina
• Recker Carla
• Grosse Julia

Classifications

• C08F236/06 Primary

  Butadiene · CPC title

• C08L9/06

  Copolymers with styrene · CPC title

• C08F236/10

  with vinyl-aromatic monomers · CPC title

• C08K3/36 Primary

  Silica · CPC title

• C08F297/042

  using a polyfunctional initiator · CPC title