Preparation method of superabsorbent polymer

Patent metadata

Field	Value
Publication number	US-9701796-B2
Application number	US-201415103552-A
Country	US
Kind code	B2
Filing date	Dec 5, 2014
Priority date	Dec 10, 2013
Publication date	Jul 11, 2017
Grant date	Jul 11, 2017

Abstract

Provided is a method of preparing a superabsorbent polymer. According to the method of preparing the superabsorbent polymer of the present invention, provided is a superabsorbent polymer having improved physical properties, in which the superabsorbent polymer has improved absorption rate and liquid permeability without reduction in centrifuge retention capacity or absorbency under load.

First claim

What is claimed is:

1. A method of preparing a superabsorbent polymer, the method comprising the steps of:
performing thermal polymerization or photo-polymerization of a monomer composition comprising a water-soluble ethylene-based unsaturated monomer, an internal crosslinking agent, and a polymerization initiator to prepare a hydrogel polymer having a gel strength of 10,000 Pa to 13,000 Pa,
wherein the internal crosslinking agent includes polyethyleneglycol diacrylate, and hexanediol diacrylate at a concentration of 4,000 ppm to 7,500 ppm, based on the total weight of the water-soluble ethylene-based unsaturated monomer comprised in the monomer composition;
coarsely pulverizing the hydrogel polymer by extruding the hydrogel polymer through an outlet having holes;
drying the coarsely pulverized hydrogel polymer;
pulverizing the dried polymer; and
mixing the pulverized polymer and a surface crosslinking agent to perform a surface crosslinking reaction of the mixture.

2. The method of claim 1 , wherein the diameter of the holes and the gel strength of the hydrogel polymer satisfy the following Formula 1:
1140* x+ 730< y< 600* x+ 8400  [Formula 1]

wherein x is the diameter of the hole (unit: mm) and y is the gel strength (unit: Pa) of the hydrogel polymer before coarse pulverization.

3. The method of claim 1 , wherein the internal crosslinking agent is a compound having a cure dose of 80% to 200%, relative to a cure dose of the water-soluble ethylene-based unsaturated monomer.

4. The method of claim 1 , wherein the internal crosslinking agent is a compound having a cure dose of 160 to 400 mJ/cm 2 .

5. The method of claim 1 , further comprising the step of classifying the pulverized polymer according to a particle size of 150 to 850 μm, before the step of performing surface crosslinking reaction of the pulverized polymer.

6. The method of claim 1 , wherein the superabsorbent polymer has centrifuge retention capacity (CRC) of 25 g/g or more, absorbency under load (AUL) of 20 g/g or more, absorption rate (FSR) of 0.25 g/g/s or more, and liquid permeability (SFC) of 70*10 −7 cm 3 *sec/g or more.

Assignees

• Lg Chemical Ltd

Inventors

• Jung Hwayoon
• Han Chang Sun
• Ryu Chul Hee
• Kim Mi Young
• Ahn Tae Bin

Classifications

• C08F6/008

  Treatment of solid polymer wetted by water or organic solvents, e.g. coagulum, filter cakes · CPC title

• C08J3/12

  Powdering or granulating · CPC title

• C08F220/06

  Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof · CPC title

• A61L15/60

  Liquid-swellable gel-forming materials, e.g. super-absorbents · CPC title

• C08F2/10

  Aqueous solvent · CPC title