Adhesive composition

Patent metadata

Field	Value
Publication number	US-9701787-B2
Application number	US-201415035783-A
Country	US
Kind code	B2
Filing date	Nov 17, 2014
Priority date	Nov 18, 2013
Publication date	Jul 11, 2017
Grant date	Jul 11, 2017

Abstract

Provided is a two-part composition. The first part is an epoxy terminated polyester having the structure
wherein R 1 - is

G- is

-A- is a divalent alkyl group, -CA- is a divalent cycloalkyl group, and -R 2 - is a divalent organic group.

The second part is an epoxy curing agent.

First claim

The invention claimed is:

1. A two-part composition comprising
A) One or more epoxy terminated polyester having the structure wherein R 1 - is

 G- is

 -A- is a divalent alkyl group, -CA- is a divalent cycloalkyl group, and -R 2 - is

wherein said -R 4 - is a divalent organic group, and wherein said p is 0 to 20, and wherein said -R 3 - and -R 5 - is each independently selected from the group consisting of aliphatic groups having 12 or fewer carbon atoms and aromatic groups. and
B) one or more epoxy curing agent, each molecule of which comprises two or more active hydrogen atoms that are each capable of reacting with an epoxy group.

2. The composition of claim 1 , wherein each of said active hydrogen atoms is part of a primary or secondary amine group.

3. The composition of claim 1 , wherein said curing agent is selected from the group consisting of phenalkamines, Mannich bases, phenalkamides, amine terminated amide resins, aminoimidazolines, and mixtures thereof.

4. The composition of claim 1 , wherein said curing agent has number-average molecular weight of 750 or greater, and wherein the amount of said curing agent having molecular weight of less than 500 is 25% or less by weight based on the weight of said curing agent.

5. The composition of claim 1 , wherein said -A- is —(CH 2 ) n — wherein n is 1 to 6.

6. The composition of claim 1 , wherein said -CA- is

7. The composition of claim 1 , wherein said -R 3 - is either —(CH 2 ) q — or

wherein q is 1 to 8.

8. The composition of claim 1 , wherein said -R 4 - is either —CH 2 —CH 2 — or —CH 2 —CH 2 —O—CH 2 —CH 2 —.

Assignees

• Rohm & Haas

Inventors

• Zupancic Joseph J
• Marine Amira A
• Vietti David E

Classifications

• C08G59/50

  Amines · CPC title

• C09J167/02

  Polyesters derived from dicarboxylic acids and dihydroxy compounds (C09J167/06 takes precedence) · CPC title

• C08G59/24

  carbocyclic · CPC title

• C08G63/916 Primary

  Dicarboxylic acids and dihydroxy compounds · CPC title

• C09J163/00

  Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins · CPC title