Pesticidal compositions and processes related thereto

Patent metadata

Field	Value
Publication number	US-9701620-B2
Application number	US-201514880739-A
Country	US
Kind code	B2
Filing date	Oct 12, 2015
Priority date	Dec 19, 2012
Publication date	Jul 11, 2017
Grant date	Jul 11, 2017

Abstract

This document discloses molecules having the following formula (“Formula One”):

and processes associated therewith.

First claim

We claim:

1. A composition comprising a molecule according to Formula One:

wherein:
(a) R1 is selected from the group consisting of H and Cl;
(b) R2 is selected from the group consisting of H, F, Cl, Br, and (C 1 -C 8 )alkyl;
(c) R3 is selected from the group consisting of H, F, Cl, and Br;
(d) R4 is selected from the group consisting of F, Cl, Br, CN, NO 2 , (C 1 -C 8 )alkyl, and halo(C 1 -C 8 )alkyl;
(e) R5 is selected from the group consisting of H and F;
(f) R6 is a (C 1 -C 8 )haloalkyl;
(g) R7 is H;
(h) R8 is H;
(i) R9 is H;
(j) R10 is selected from the group consisting of Cl, Br, (C 1 -C 8 )alkyl, and halo(C 1 -C 8 )alkyl;
(k) R11 is C(═X5)N(X6)(R14), wherein
X5 is selected from the group consisting of O and S, and
X6 is selected from the group consisting of halocyclo(C 3 -C 6 )alkyl and substituted cyclo(C 3 -C 6 )alkyl wherein said substituted cyclo(C 3 -C 6 )alkyl is substituted with one or more substituents selected from the group consisting of CN and C(═X5)N(R15)(R16);

(l) R12 is H;
(m) R13 is H;
(n) R14 is H;
(o) R15 is H;
(p) R16 is selected from the group consisting of (C 1 -C 8 )alkyl and halo(C 1 -C 8 )alkyl;
(r) X1 is CR12;
(s) X2 is CR13; and
(t) X3 is CR9.

2. A composition according to claim 1 wherein said molecule said R2 is selected from the group consisting of H, F, Cl, Br, and CH 3 .

3. A composition according to claim 1 wherein said molecule said R4 is selected from the group consisting of F, Cl, Br, CN, NO 2 , CH 3 , and OCF 3 .

4. A composition according to claim 1 wherein said molecule said R6 is selected from the group consisting of halomethyl, and haloethyl.

5. A composition according to claim 1 wherein said molecule said R6 is trifluoromethyl or pentafluoroethyl.

6. A composition according to claim 1 wherein said molecule said R10 is selected from the group consisting of Cl, Br, CH 3 , and CF 3 .

7. A composition according to claim 1 wherein said molecule said R11 is selected from the group consisting of (C═O)N(H)(cyclopropyl-(C═O)N(H)(CH 2 CF 3 )), (C═O)N(H)(cyclopropyl-(C═O)N(H)(CH 2 CH 2 CF 3 )), (C═O)N(H)(cyclopropyl-(C═O)N(H)(CH 2 CH 2 F)), (C═O)N(H)(cyclopropyl-(C═O)N(H)(CH 2 CH 3 )), (C═O)N(H)(cyclopropyl-(C═O)N(H)(CH 2 CHF 2 )), (C═O)N(H)(cyclopropyl-(C═S)N(H)(CH 2 CF 3 )), (C═O)N(H)(cyclobutyl-(C═O)N(H)(CH 2 CF 3 )), (C═O)N(H)(cyclopropyl-CN), and (C═O)N(H)(difluorocyclopropyl).

8. A composition according to claim 1 wherein said molecule said R11 is selected from the group consisting of (C═(O)N(H)(cyclopropyl-(C═(O or S))N(H)(halo(C 1 -C 6 )alkyl)), (C═(O)N(H)(cyclobutyl-(C═(O))N(H)(halo(C 1 -C 6 )alkyl)), and (C═(O)N(H)(cyclopropyl-(C═(O))N(H)((C 1 -C 6 )alkyl)).

9. A composition according to claim 1 wherein said molecule said R16 is selected from the group consisting of methyl, ethyl, halomethyl, haloethyl, and halo(C 3 )alkyl.

10. A composition according to claim 1 wherein said molecule said R16 is selected from the group consisting of CH 2 CH 3 , CH 2 CF 3 , CH 2 CHF 2 , CH 2 CH 2 F, and CH 2 CH 2 CF 3 .

11. A composition according to claim 1 further comprising:
(a) one or more compounds having acaricidal, algicidal, avicidal, bactericidal, fungicidal, herbicidal, insecticidal, molluscicidal, nematicidal, rodenticidal, or virucidal properties; or
(b) one or more compounds that are antifeedants, bird repellents, chemosterilants, herbicide safeners, insect attractants, insect repellents, mammal repellents, mating disrupters, plant activators, plant growth regulators, or synergists; or
(c) both (a) and (b).

12. A composition according to claim 1 further comprising one or more compounds selected from the group consisting of: (3-ethoxypropyl)mercury bromide, 1,2-dichloropropane, 1,3-dichloropropene, 1-methylcyclopropene, 1-naphthol, 2-(octylthio)ethanol, 2,3,5-tri-iodobenzoic acid, 2,3,6-TBA, 2,3,6-TBA-dimethylammonium, 2,3,6-TBA-lithium, 2,3,6-TBA-potassium, 2,3,6-TBA-sodium, 2,4,5-T, 2,4,5-T-2-butoxypropyl, 2,4,5-T-2-ethylhexyl, 2,4,5-T-3-butoxypropyl, 2,4,5-TB, 2,4,5-T-butometyl, 2,4,5-T-butotyl, 2,4,5-T-butyl, 2,4,5-T-isobutyl, 2,4,5-T-isoctyl, 2,4,5-T-isopropyl, 2,4,5-T-methyl, 2,4,5-T-pentyl, 2,4,5-T-sodium, 2,4,5-T-triethylammonium, 2,4,5-T-trolamine, 2,4-D, 2,4-D-2-butoxypropyl, 2,4-D-2-ethylhexyl, 2,4-D-3-butoxypropyl, 2,4-D-ammonium, 2,4-DB, 2,4-DB-butyl, 2,4-DB-dimethylammonium, 2,4-DB-isoctyl, 2,4-DB-potassium, 2,4-DB-sodium, 2,4-D-butotyl, 2,4-D-butyl, 2,4-D-diethylammonium, 2,4-D-dimethylammonium, 2,4-D-diolamine, 2,4-D-dodecylammonium, 2,4-DEB, 2,4-DEP, 2,4-D-ethyl, 2,4-D-heptylammonium, 2,4-D-isobutyl, 2,4-D-isoctyl, 2,4-D-isopropyl, 2,4-D-isopropylammonium, 2,4-D-lithium, 2,4-D-meptyl, 2,4-D-methyl, 2,4-D-octyl, 2,4-D-pentyl, 2,4-D-potassium, 2,4-D-propyl, 2,4-D-sodium, 2,4-D-tefuryl, 2,4-D-tetradecylammonium, 2,4-D-triethylammonium, 2,4-D-tris(2-hydroxypropyl)ammonium, 2,4-D-trolamine, 2iP, 2-methoxyethylmercury chloride, 2-phenylphenol, 3,4-DA, 3,4-DB, 3,4-DP, 4-aminopyridine, 4-CPA, 4-CPA-potassium, 4-CPA-sodium, 4-CPB, 4-CPP, 4-hydroxyphenethyl alcohol, 8-hydroxyquinoline sulfate, 8-phenylmercurioxyquinoline, abamectin, abscisic acid, ACC, acephate, acequinocyl, acetamiprid, acethion, acetochlor, acetophos, acetoprole, acibenzolar, acibenzolar-S-methyl, acifluorfen, acifluorfen-methyl, acifluorfen-sodium, aclonifen, acrep, acrinathrin, acrolein, acrylonitrile, acypetacs, acypetacs-copper, acypetacs-zinc, alachlor, alanycarb, albendazole, aldicarb, aldimorph, aldoxycarb, aldrin, allethrin, allicin, allidochlor, allosamidin, alloxydim, alloxydim-sodium, allyl alcohol, allyxycarb, alorac, alpha-cypermethrin, alpha-endosulfan, ametoctradin, ametridione, ametryn, amibuzin, amicarbazone, amicarthiazol, amidithion, amidoflumet, amidosulfuron, aminocarb, aminocyclopyrachlor, aminocyclopyrachlor-methyl, aminocyclopyrachlor-potassium, aminopyralid, aminopyralid-potassium, aminopyralid-tris(2-hydroxypropyl)ammonium, amiprofos-methyl, amiprophos, amisulbrom, amiton, amiton oxalate, amitraz, amitrole, ammonium sulfamate, ammonium α-naphthaleneacetate, amobam, ampropylfos, anabasine, ancymidol, anilazine, anilofos, anisuron, anthraquinone, antu, apholate, aramite, arsenous oxide, asomate, aspirin, asulam, asulam-potassium, asulam-sodium, athidathion, atraton, atrazine, aureofungin, aviglycine, aviglycine hydrochloride, azaconazole, azadirachtin, azafenidin, azamethiphos, azimsulfuron, azinphos-ethyl, azinphos-methyl, aziprotryne, azithiram, azobenzene, azocyclotin, azothoate, azoxystrobin, bachmedesh, barban, barium hexafluorosilicate, barium polysulfide, barthrin, BCPC, beflubutamid, benalaxyl, benalaxyl-M, benazolin, benazolin-dimethylammonium, benazolin-ethyl, benazolin-potassium, bencarbazone, benclothiaz, bendiocarb, benfluralin, benfuracarb, benfuresate, benodanil, benomyl, benoxacor, benoxafos, benquinox, bensulfuron, bensulfuron-methyl, bensulide, bensultap, bentaluron, bentazone, bentazone-sodium, benthiavalicarb, benthiavalicarb-isopropyl, benthiazole, bentranil, benzadox, benzadox-ammonium, benzalkonium chloride, benzamacril, benzamacril-isobutyl, benzamorf, benzfendizone, benzipram, benzobicyclon, benzofenap, benzofluor, benzohydroxamic acid, benzoximate, benzoylprop, benzoylprop-ethyl, benzthiazuron, benzyl benzoate, benzyladenine, berberine, berberine chloride, beta-cyfluthrin, beta-cypermethrin, bethoxazin, bicyclopyrone, bifenazate, bifenox, bifenthrin, bifujunzhi, bilanafos, bilanafos-sodium, binapacryl, bingqingxiao, bioallethrin, bioethanomethrin, biopermethrin, bioresmethrin, biphenyl, bisazir, bismerthiazol, bispyribac, bispyribac-sodium, bistrifluron, bitertanol, bithiono

Assignees

• Dow Agrosciences Llc

Inventors

• Lo William C
• Hunter James E
• Watson Gerald B
• Patny Akshay
• Iyer Pravin S
• Boruwa Joshodeep

Classifications

• C07C327/46

  having carbon atoms of thiocarboxamide groups bound to carbon atoms of rings other than six-membered aromatic rings · CPC title

• C07C275/24

  containing six-membered aromatic rings · CPC title

• C07C271/24

  with the nitrogen atom of at least one of the carbamate groups bound to a carbon atom of a ring other than a six-membered aromatic ring · CPC title

• C07C271/22

  to carbon atoms of hydrocarbon radicals substituted by carboxyl groups · CPC title

• C07C259/08

  having carbon atoms of hydroxamic groups bound to carbon atoms of rings other than six-membered aromatic rings · CPC title