Method for preparing difluoroallylboronate and application thereof
US-10494383-B2 · Dec 3, 2019 · US
US9701606B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9701606-B2 |
| Application number | US-201214350508-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 11, 2012 |
| Priority date | Oct 11, 2011 |
| Publication date | Jul 11, 2017 |
| Grant date | Jul 11, 2017 |
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A process of forming methoxymelonal comprising the steps of treating a solution of citronellene to ozonolysis, and hydrogenating the product formed to provide methoxymelonal.
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The invention claimed is: 1. A process of forming methoxymelonal comprising the steps of subjecting methoxy citronellene (2) to ozonolysis, followed by a reductive work-up to give methoxymelonal, and the synthesis is set out in the scheme below: 2. The process according to claim 1 wherein the ozonolysis is carried out in a solvent selected from methanol or water. 3. The process according to claim 1 wherein the reductive work-up step is a hydrogenation carried out using palladium as a catalyst. 4. The process according to claim 1 wherein the reduction step is carried out using sulfites as reducing agents.
by oxidation with ozone; by ozonolysis · CPC title
containing oxygen as the only heteroatom · CPC title
containing ether groups, [IMAGE cpc-sch-C07C-0958.gif] groups,[IMAGE cpc-sch-C07C-0959.gif] groups, or[IMAGE cpc-sch-C07C-0960.gif] groups · CPC title
Palladium · CPC title
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