Methods for operating polyethylene reactor systems
US-2024392119-A1 · Nov 28, 2024 · US
US9700865B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9700865-B2 |
| Application number | US-201414485563-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 12, 2014 |
| Priority date | Sep 12, 2014 |
| Publication date | Jul 11, 2017 |
| Grant date | Jul 11, 2017 |
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Apparatuses and methods for cooling catalyst are provided. In one embodiment, an apparatus for cooling catalyst includes a catalyst cooler vessel having a catalyst inlet for receiving catalyst. The apparatus includes a gas distributor lance positioned in the catalyst cooler vessel and having a gas outlet configured for injecting gas into the catalyst. The apparatus also includes a heat exchange tube positioned in the catalyst cooler vessel and having an outer surface. The heat exchange tube is configured to transfer heat from the catalyst to a heat exchange fluid. The apparatus further includes a hard surfacing material located on the outer surface of the heat exchange tube.
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What is claimed is: 1. An apparatus for cooling catalyst, the apparatus comprising: a catalyst cooler vessel having a catalyst inlet for receiving the catalyst; a gas distributor lance positioned in the catalyst cooler vessel and having a gas outlet configured for injecting gas into the catalyst; a heat exchange tube positioned in the catalyst cooler vessel and having an outer surface, the heat exchange tube being configured to transfer heat from the catalyst to a heat exchange fluid; and a hard surfacing material located on and welded to the outer surface of the heat exchange tube. 2. The apparatus of claim 1 wherein the hard surfacing material is located on the outer surface of the heat exchange tube adjacent the gas outlet of the gas distributor lance. 3. The apparatus of claim 1 wherein the hard surfacing material surrounds the outer surface of the heat exchange tube to form a substantially cylindrical hard surfacing sleeve. 4. The apparatus of claim 1 wherein the hard surfacing material surrounds the outer surface of the heat exchange tube to form a substantially cylindrical hard surfacing sleeve having a thickness of from about 1 mm to about 5 mm. 5. The apparatus of claim 1 wherein the hard surfacing material surrounds the outer surface of the heat exchange tube to form a substantially cylindrical hard surfacing sleeve having a thickness of from about 2 mm to about 4 mm. 6. The apparatus of claim 1 wherein the hard surfacing material surrounds the outer surface of the heat exchange tube to form a substantially cylindrical hard surfacing sleeve having a length of from about 200 mm to about 500 mm. 7. The apparatus of claim 1 wherein the hard surfacing material surrounds the outer surface of the heat exchange tube to form a substantially cylindrical hard surfacing sleeve having a length of from about 300 mm to about 400 mm. 8. The apparatus of claim 1 wherein: the heat exchange tube has a proximal portion, a protected portion, and a distal portion; and the hard surfacing material surrounds the outer surface of the protected portion of the heat exchange tube, wherein the outer surface of the proximal portion and the distal portion of the heat exchange tube is in contact with the catalyst. 9. The apparatus of claim 1 wherein: the vessel defines a chamber; the heat exchange tube has a proximal portion, a protected portion, and a distal portion, wherein the proximal portion, the protected portion, and the distal portion are positioned in the chamber; and the hard surfacing material surrounds the outer surface of the protected portion of the heat exchange tube, wherein the outer surface of the proximal portion and the distal portion of the heat exchange tube is in contact with the catalyst. 10. The apparatus of claim 1 wherein the gas distributor lance and the heat exchange tube are substantially parallel. 11. The apparatus of claim 1 wherein the gas outlet of the gas distributor lance is separated from the heat exchange tube by a distance of from about 50 mm to about 200 mm. 12. The apparatus of claim 1 wherein the gas outlet of the gas distributor lance is separated from the heat exchange tube by a distance of from about 80 mm to about 120 mm. 13. An apparatus for processing catalyst, the apparatus comprising: a regeneration vessel configured to receive spent catalyst and to regenerate the spent catalyst to form regenerated catalyst; and a catalyst cooler in fluid communication with the regeneration vessel for receiving the catalyst therefrom, wherein the catalyst cooler includes a heat exchange tube having an outer surface and a hard surfacing material located on the outer surface of the heat exchange tube, wherein the hard surfacing material surrounds the outer surface of the heat exchange tube to form a cylindrical hard surfacing sleeve. 14. The apparatus of claim 13 wherein the catalyst cooler includes a gas distributor lance having a gas outlet configured for injecting gas into the catalyst. 15. The apparatus of claim 14 wherein the hard surfacing material is located on the outer surface of the heat exchange tube adjacent the gas outlet of the gas distributor lance. 16. The apparatus of claim 13 wherein the hard surfacing material surrounds the outer surface of the heat exchange tube to form a substantially cylindrical hard surfacing sleeve having a thickness of from about 1 mm to about 5 mm. 17. The apparatus of claim 16 wherein the substantially cylindrical hard surfacing sleeve has a length of from about 200 mm to about 500 mm. 18. The apparatus of claim 13 wherein: the catalyst cooler includes a vessel defining a chamber; the heat exchange tube has a proximal portion, a protected portion, and a distal portion, wherein the proximal portion, the protected portion, and the distal portion are positioned in the chamber; and the hard surfacing material surrounds and is welded to the outer surface of the protected portion of the heat exchange tube, wherein the outer surface of the proximal portion and the distal portion of the heat exchange tube is in contact with the catalyst. 19. A method for cooling catalyst, the method comprising the steps of: delivering the catalyst into a catalyst cooler vessel; transferring heat from the catalyst to a heat exchange tube positioned in the catalyst cooler vessel, wherein the heat exchange tube has an outer surface; injecting gas into the catalyst within the catalyst cooler vessel to cause back-mixing of the catalyst; and preventing impingement of the outer surface of the heat exchange tube by the gas with a hard surfacing material located on and welded to the outer surface of the heat exchange tube.
Regeneration or reactivation · CPC title
in a heat exchanger for the heat exchange medium separate from the reactor · CPC title
Treating with free oxygen-containing gas · CPC title
Heating and cooling the reactor (B01J8/42 takes precedence) · CPC title
Disengagement zone in fluidised-bed reactors · CPC title
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