Complex for acid gas separation, module for acid gas separation, and method for manufacturing module for acid gas separation

Patent metadata

Field	Value
Publication number	US-9700833-B2
Application number	US-201514819492-A
Country	US
Kind code	B2
Filing date	Aug 6, 2015
Priority date	Feb 22, 2013
Publication date	Jul 11, 2017
Grant date	Jul 11, 2017

Abstract

A complex for acid gas separation includes an acid gas separation membrane, a permeated gas flow path member, and a sealing portion. The acid gas separation membrane includes a porous support with pores having an average pore diameter of 0.5 μm or less, and an acid gas separation layer disposed on the porous support. The permeated gas flow path member allows acid gas, which has permeated through the acid gas separation layer, to pass therethrough. The sealing portion seals a region required to be sealed with resin, the region being on the periphery of the permeated gas flow path member and the porous support. The sealing portion is made of epoxy resin, the Tg of epoxy resin is 90° C. or higher and the content of an inorganic filling material is less than or equal to 30% by mass.

First claim

What is claimed is:

1. A complex for acid gas separation, comprising:
an acid gas separation membrane including:
a porous support with pores having an average pore diameter of 0.5 μm or less; and
an acid gas separation layer disposed on the porous support, the acid gas separation layer including water-absorbing polymers and acid gas carriers that react with acid gas in a raw material gas;

a permeated gas flow path member that allows acid gas, which has reacted with the acid gas carriers and permeated through the acid gas separation layer, to pass therethrough; and
a sealing portion that seals a region on the periphery of the permeated gas flow path member and the porous support with resin, the region being required to be sealed, wherein
the resin is made of epoxy resin,
the Tg of the resin of the sealing portion is 90° C. or higher, and
the content of an inorganic filling material is less than or equal to 30% by mass.

2. A module for acid gas separation, comprising:
an acid gas separation membrane including:
a porous support with pores having an average pore diameter of 0.5 μm or less; and
an acid gas separation layer disposed on the porous support, the acid gas separation layer including water-absorbing polymers and acid gas carriers that react with acid gas in a raw material gas;

a permeated gas flow path member that allows acid gas, which has reacted with the acid gas carriers and has permeated through the acid gas separation layer, to pass therethrough;
a sealing portion that seals both ends in the width direction and one end in the longitudinal direction of the porous support and the permeated gas flow path member, with resin;
a feed gas flow path member, into which raw material gas containing the acid gas is fed; and
a permeated gas collecting pipe having open holes on the wall thereof, wherein
the acid gas separation membrane, the permeated gas flow path member, and the feed gas flow path member are wound around the permeated gas collecting pipe,
the resin is made of epoxy resin,
the Tg of the resin in the sealing portion is 90° C. or higher, and
the content of an inorganic filling material is less than or equal to 30% by mass.

3. A method for manufacturing the module for acid gas separation, comprising:
forming an acid gas separation membrane including a porous support and an acid gas separation layer support by providing the acid gas separation layer on the porous support, the acid gas separation layer having water-absorbing polymers and acid gas carriers that react with acid gas in raw material gas,
forming a sealing portion by causing resin to penetrate both ends in the width direction and one end in the longitudinal direction of the porous support and the permeated gas flow path member that allows acid gas, which has reacted with the acid gas carriers and permeated through the acid gas separation layer, to flow therethrough, and
winding the acid gas separation membrane, the permeated gas flow path member, and a feed gas flow path member around a permeated gas collecting pipe, the feed gas flow path member being a member into which raw material gas containing the acid gas is fed and the permeated gas collecting pipe having open holes on the wall thereof, wherein
the viscosity of the resin is within a range from 5 to 60 Pa·s,
the Tg of the resin after being cured is 90° C. or higher, and
the content of an inorganic filling material is less than or equal to 30% by mass.

4. The method for manufacturing the module for acid gas separation of claim 3 , wherein the resin is epoxy resin.

5. The method for manufacturing the module for acid gas separation of claim 3 , wherein the resin is a two-component mixed resin.

6. The method for manufacturing the module for acid gas separation of claim 4 , wherein the usable time of the resin is within a range from 60 to 240 minutes.

7. The method for manufacturing the module for acid gas separation of claim 5 , wherein the usable time of the resin is within a range from 60 to 240 minutes.

Assignees

• Fujifilm Corp

Inventors

• Ouchi Ryo

Classifications

• B01D69/142

  with "carriers" · CPC title

• B01D2325/28

  Degradation or stability over time · CPC title

• B01D71/38

  Polyalkenylalcohols; Polyalkenylesters; Polyalkenylethers; Polyalkenylaldehydes; Polyalkenylketones; Polyalkenylacetals; Polyalkenylketals · CPC title

• B01D69/125

  In situ manufacturing by polymerisation, polycondensation, cross-linking or chemical reaction · CPC title

• B01D69/12

  Composite membranes; Ultra-thin membranes · CPC title