Aliginates as binders for battery cathodes

Patent metadata

Field	Value
Publication number	US-9698424-B2
Application number	US-201314401015-A
Country	US
Kind code	B2
Filing date	Apr 19, 2013
Priority date	May 18, 2012
Publication date	Jul 4, 2017
Grant date	Jul 4, 2017

Abstract

A cathode unit for a battery, in which the cathode includes a viscoelastic, and a polymeric gel former selected from the group of natural polysaccharides having a proportion of carboxylate or carboxylic acid groups of greater than or equal to 0.5 and less than or equal to 2.0 in relation to the number of monomer units. Also described is a method for manufacturing the cathode units and the use of a battery including the cathode unit according to the invention for power supply.

First claim

What is claimed is:

1. A cathode unit for a battery, comprising:
a cathode having a viscoelastic, polymeric gel former selected from the group of natural polysaccharides having a proportion of carboxylate or carboxylic acid groups of greater than or equal to 0.5 and less than or equal to 2.0 in relation to the number of the monomer units;
wherein the cathode contains Li 2 MnO 3 .

2. The cathode unit of claim 1 , wherein the viscoelastic, polymeric gel former is made of a salt of an alginic acid.

3. The cathode unit of claim 1 , wherein the viscoelastic, polymeric gel former in aqueous solution has a viscosity of greater than or equal to 100 mPa and less than or equal to 15000 mPa.

4. The cathode unit of claim 1 , wherein the viscosity of the viscoelastic, polymeric gel former in solution is reduced as a result of a shear stress of 100 times the yield point by greater than or equal to 10% and less than or equal to 90%.

5. The cathode unit of claim 1 , wherein the cathode unit is an integral part of a lithium-ion battery or a lithium-polymer battery.

6. The cathode unit of claim 1 , wherein the cathode contains sulfur, carbons, and a salt of an alginic acid.

7. The cathode unit of claim 1 , wherein the cathode contains nickel-cobalt-manganese oxide, a salt of an alginic acid, and optionally carbon, or the cathode contains a composite material made of nickel-cobalt-manganese oxide, Li 2 MnO 3 , a salt of an alginic acid, and optionally carbon.

8. The cathode unit of claim 1 , wherein the cathode includes:
greater than 0 wt.-% and less than or equal to 70 wt.-% Li 2 MnO 3 ,
greater than or equal to 15 wt.-% and less than or equal to 98 wt.-% nickel-cobalt-manganese oxide,
greater than or equal to 2 wt.-% and less than or equal to 25 wt.-% salt of an alginic acid, and
greater than 0 wt.-% and less than or equal to 25 wt.-% carbon.

9. The cathode unit of claim 1 , wherein the cathode contains a composite material made of nickel-cobalt-manganese oxide, the Li 2 MnO 3 , a salt of an alginic acid, and carbon.

10. A method for manufacturing a cathode unit for a battery, the method comprising:
a) a viscoelastic polymeric gel former is added under shear stress to a solvent;
b) an active material under shear stress is added to the dispersion from a); and
c) a dispersion obtained in b) is applied to a metallic conductor;
wherein the viscoelastic, polymeric gel former is selected from the group of natural polysaccharides having a proportion of carboxylate or carboxylic acid groups of greater than or equal to 0.5 and less than or equal to 2.0 in relation to the number of the monomer units.

11. A battery, comprising:
cathode unit for a battery, including a cathode having a viscoelastic, polymeric gel former selected from the group of natural polysaccharides having a proportion of carboxylate or carboxylic acid groups of greater than or equal to 0.5 and less than or equal to 2.0 in relation to a number of the monomer units, wherein the cathode contains Li 2 MnO 3 .

12. A cathode unit for a battery, comprising:
a cathode having a viscoelastic, polymeric gel former selected from the group of natural polysaccharides having a proportion of carboxylate or carboxylic acid groups of greater than or equal to 0.5 and less than or equal to 2.0 in relation to the number of the monomer units;
wherein the cathode contains nickel-cobalt-manganese oxide, a salt of an alginic acid, and carbon.

Assignees

• Bosch Gmbh Robert

Inventors

• Rolff Malte

Classifications

• H01M4/131

  Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title

• H01M4/5815

  Sulfides · CPC title

• H01M4/525

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/0404

  by coating on electrode collectors · CPC title