Color stable red-emitting phosphors

US9698314B2 · US · B2

Patent metadata
FieldValue
Publication numberUS-9698314-B2
Application numberUS-201414208592-A
CountryUS
Kind codeB2
Filing dateMar 13, 2014
Priority dateMar 15, 2013
Publication dateJul 4, 2017
Grant dateJul 4, 2017

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  1. Title

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  2. Abstract

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Abstract

Official abstract text for this publication.

A process for synthesizing a color stable Mn 4+ doped phosphor includes contacting a precursor of formula I, in gaseous form at an elevated temperature with a fluorine-containing oxidizing agent to form the color stable Mn 4+ doped phosphor A x [MF y ]:Mn 4+   I wherein A is Li, Na, K, Rb, Cs, NR 4 or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; R is H, lower alkyl, or a combination thereof; x is the absolute value of the charge of the [MF y ] ion; and y is 5, 6 or 7.

First claim

Opening claim text (preview).

The invention claimed is: 1. A lighting apparatus comprising a semiconductor light source; and a color stable Mn 4+ doped phosphor of formula K 2 SiF 6 :Mn 4+ , wherein % intensity loss of the phosphor after exposure to light flux of at least 80 w/cm 2 at a temperature of at least 50° C. for at least 21 hours is ≦4%. 2. A lighting apparatus according to claim 1 , wherein % intensity loss of the phosphor is ≦3%. 3. A lighting apparatus according to claim 1 , wherein % intensity loss of the phosphor is ≦1%. 4. A backlight device comprising a semiconductor light source; and a color stable Mn 4+ doped phosphor of formula K 2 SiF 6 :Mn 4+ , wherein % intensity loss of the phosphor after exposure to light flux of at least 80 w/cm 2 at a temperature of at least 50° C. for at least 21 hours is ≦4%. 5. A backlight device according to claim 4 , wherein % intensity loss of the phosphor is ≦3%. 6. A backlight device according to claim 4 , wherein % intensity loss of the phosphor is ≦1%. 7. A color stable Mn 4+ doped phosphor of formula K 2 SiF 6 :Mn 4+ , wherein % intensity loss of the phosphor after exposure to light flux of at least 80 w/cm 2 at a temperature of at least 50° C. for at least 21 hours is ≦4%. 8. A color stable Mn 4+ doped phosphor according to claim 7 , wherein the % intensity loss of the phosphor is ≦3%. 9. A color stable Mn 4+ doped phosphor according to claim 7 , wherein the % intensity loss of the phosphor is ≦1.5%.

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Classifications

  • between a chip and a stacked lead frame, conducting package substrate or heat sink · CPC title

  • Encapsulations, e.g. protective coatings · CPC title

  • with alkali or alkaline earth metals · CPC title

  • with alkali or alkaline earth metals · CPC title

  • C09K11/616Primary

    with alkali or alkaline earth metals · CPC title

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What does patent US9698314B2 cover?
A process for synthesizing a color stable Mn 4+ doped phosphor includes contacting a precursor of formula I, in gaseous form at an elevated temperature with a fluorine-containing oxidizing agent to form the color stable Mn 4+ doped phosphor A x [MF y ]:Mn 4+   I wherein A is Li, Na, K, Rb, Cs, NR 4 or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, N…
Who is the assignee on this patent?
Gen Electric
What technology area does this patent fall under?
Primary CPC classification C09K11/616. Mapped technology areas include Chemistry & Metallurgy.
When was this patent published?
Publication date Tue Jul 04 2017 00:00:00 GMT+0000 (Coordinated Universal Time) (B2). Legal status and post-grant events are not shown on this page.
What related patents are in patentsdb?
We list 1 related publication on this page (citations in our corpus or others sharing the same primary CPC).