Anti-UV nanoparticles

Patent metadata

Field	Value
Publication number	US-9696460-B2
Application number	US-201113521642-A
Country	US
Kind code	B2
Filing date	Jan 11, 2011
Priority date	Jan 11, 2010
Publication date	Jul 4, 2017
Grant date	Jul 4, 2017

Abstract

The invention relates to nanoparticles having a core that is fully or partially formed by at least one UV-absorbing organic compound in crystallized form and coated with an outer layer formed by at least one hydrophilic polymer, said UV-absorbing organic compound(s) and hydrophilic polymer(s) being associated in a weight ratio of organic compound(s) to hydrophilic polymer(s) varying between 0.2 and 0.4.

First claim

The invention claimed is:

1. A nanoparticle comprising a core consisting of one or more UV-absorbing organic compound(s), in crystalline form, the core is coated with an outer layer formed of one or more hydrophilic polymer(s), said UV-absorbing organic compound(s) and hydrophilic polymer(s) being combined in an organic compound(s)/hydrophilic polymer(s) ratio by weight varying from 0.2 to 0.4, wherein said hydrophilic polymer(s) comprises at least one of a polyvinyl alcohol having a molecular weight ranging from 25,000 to 100,000 g/mole, a polyacrylic acid having a molecular weight ranging from 100,000 to 600,000 g/mole, or a combination thereof.

2. The nanoparticle of claim 1 , wherein the nanoparticle is water-dispersible.

3. The nanoparticle of claim 1 , wherein the outer layer comprises at least one polyvinyl alcohol with a molecular weight varying from 25,000 to 50,000 g/mol.

4. The nanoparticle of claim 1 , having a mean size of less than 500 nm.

5. The nanoparticle of claim 1 , having a mean size of less than 300 nm.

6. The nanoparticle of claim 1 , wherein said UV-absorbing compound is chosen from substituted benzotriazoles, hydroxybenzophenones, and pyrene and its derivatives.

7. The nanoparticle of claim 1 , wherein the nanoparticle is comprised within a composition.

8. The nanoparticle of claim 7 , wherein the composition includes a polymeric material.

9. The nanoparticle of claim 7 , wherein the composition includes a textile.

10. A process for making a nanoparticle of claim 1 , comprising:
obtaining an organic phase comprising at least one UV-absorbing organic compound in the solute state;
obtaining an aqueous phase comprising at least one hydrophilic polymer, wherein said hydrophilic polymer is a polyvinyl alcohol having a molecular weight ranging from 25,000 to 100,000 g/mole or a polyacrylic acid having a molecular weight ranging from 100,000 to 600,000 g/mole;
adding the organic phase to the aqueous phase under conditions propitious to the formation of an emulsion, wherein the organic phase is dispersed in the aqueous phase, and wherein the emulsion includes at least one surfactant capable of stabilizing the emulsion;
carrying out a thermal quenching of the emulsion thus obtained in order to form said nanoparticles; and
isolating said nanoparticles,

wherein the amounts of polymer(s) and organic compound(s) are adjusted in order for the nanoparticle to have an organic compound(s)/hydrophilic polymer(s) ratio by weight varying from 0.2 to 0.4.

11. The process of claim 10 , wherein the isolated nanoparticles are lyophilized.

12. The process of claims 10 , wherein the organic phase comprises, as solvent, cyclohexane, methyl ethyl ketone or isobutyraldehyde.

13. The process of claim 10 , wherein the thermal quenching is carried out by bringing the emulsion into contact with liquid nitrogen.

14. A process for stabilizing a material with regard to UV degradation, comprising adding to the material or to a precursor of the material, at least one nanoparticle of claim 1 as an agent for absorbing ultraviolet light radiation, wherein addition of the nanoparticle to the material or precursor of the material stabilizes the material or precursor with regard to UV degredation.

15. A process for increasing the sun protection factor of a textile fiber, comprising immobilizing on the fiber at least one nanoparticle of claim 1 , wherein immobilization of the nanopartile on the fiber increases the sun protection factor of the fiber.

Assignees

• Poncelet Olivier
• Renard Olivier
• Commissariat Energie Atomique

Inventors

• Poncelet Olivier
• Renard Olivier

Classifications

• D06M23/08

  Processes in which the treating agent is applied in powder or granular form (adhesives for multi-layer textile fabrics D06M17/00) · CPC title

• Y10T442/2607

  Radiation absorptive · CPC title

• D06M2200/25

  Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments · CPC title

• G02B1/04 Primary

  made of organic materials, e.g. plastics (G02B1/08 takes precedence) · CPC title

• D06M23/12

  Processes in which the treating agent is incorporated in microcapsules (making microcapsules B01J13/02) · CPC title