Method for fractionating dioxins

Patent metadata

Field	Value
Publication number	US-9696290-B2
Application number	US-201314768327-A
Country	US
Kind code	B2
Filing date	May 27, 2013
Priority date	May 27, 2013
Publication date	Jul 4, 2017
Grant date	Jul 4, 2017

Abstract

The interior of a fractionating tool for fractionating dioxins is packed with a purification layer and an adsorption layer. The adsorption layer includes a first adsorption layer including an activated carbon-containing silica gel layer and a graphite-containing silica gel layer, and a second adsorption layer including an alumina layer. When a solution of dioxins is injected into the purification layer and is supplied with an aliphatic hydrocarbon solvent, the solvent dissolves dioxins in the solution of dioxins and passes through the purification layer and the adsorption layer. In this process, non-ortho PCBs, PCDDs and PCDFs among dioxins are adsorbed to the first adsorption layer, and mono-ortho PCBs among dioxins are adsorbed to the second adsorption layer. As a result, dioxins are fractionated into a group including non-ortho PCBs, PCDDs and PCDFs, and mono-ortho PCBs.

First claim

The invention claimed is:

1. A method for fractionating dioxins, comprising the step of:
passing an aliphatic hydrocarbon solvent solution of dioxins comprising mono-ortho PCBs and one or more selected from the group consisting of non-ortho PCBs, PCDDs and PCDFs through an activated carbon-containing silica gel layer and a graphite-containing silica gel layer in this order to separate the mono-ortho PCBs from the one or more selected from the group consisting of non-ortho PCBs, PCDDs and PCDFs,
wherein the ratio between the activated carbon-containing silica gel and the graphite-containing silica gel is 1:1 to 1:12 by volume.

2. The method for fractionating dioxins according to claim 1 , wherein the aliphatic hydrocarbon solvent solution having passed through the graphite-containing silica gel layer is further passed through an alumina layer.

3. The method for fractionating dioxins according to claim 2 , further comprising the steps of:
supplying the activated carbon-containing silica gel layer and the graphite-containing silica gel layer through which the aliphatic hydrocarbon solvent solution has passed with a solvent capable of dissolving dioxins, to secure the solvent having passed through the activated carbon-containing silica gel layer and the graphite-containing silica gel layer; and
supplying the alumina layer through which the aliphatic hydrocarbon solvent solution has passed with a solvent capable of dissolving dioxins, to secure the solvent having passed through the alumina layer.

4. A method for preparing a sample for analyzing dioxins contained in a solution of dioxins comprising mono-ortho PCBs and one or more selected from the group consisting of non-ortho PCBs, PCDDs and PCDFs, the method comprising the steps of:
adding the solution of dioxins to a purification layer including a silver nitrate silica gel layer and a sulfuric acid silica gel layer;
supplying the purification layer to which the solution of dioxins has been added with an aliphatic hydrocarbon solvent;
passing the aliphatic hydrocarbon solvent having passed through the purification layer through an activated carbon-containing silica gel layer and a graphite-containing silica gel layer in this order to separate the mono-ortho PCBs from the one or more selected from the group consisting of non-ortho PCBs, PCDDs and PCDFs;
passing the aliphatic hydrocarbon solvent having passed through the graphite-containing silica gel layer through an alumina layer;
supplying the alumina layer through which the aliphatic hydrocarbon solvent has passed with a solvent capable of dissolving dioxins, to secure the solvent having passed through the alumina layer as a first analytical sample; and
supplying the activated carbon-containing silica gel layer and the graphite-containing silica gel layer through which the aliphatic hydrocarbon solvent has passed with a solvent capable of dissolving dioxins, to secure the solvent having passed through the activated carbon-containing silica gel layer and the graphite-containing silica gel layer as a second analytical sample,
wherein the ratio between the activated carbon-containing silica gel and the graphite-containing silica gel is 1:1 to 1:12 by volume.

5. The method for preparing a sample for analyzing dioxins according to claim 4 , wherein the solution of dioxins is added to the silver nitrate silica gel layer of the purification layer.

6. A method for analyzing dioxins contained in a solution of dioxins, comprising the step of:
analyzing a first analytical sample and a second analytical sample prepared by the method for preparing a sample for analyzing dioxins according to claim 4 , by a gas chromatography method or a bioassay method.

Assignees

• Miura Kogyo Kk

Inventors

• Fujita Hiroyuki
• Nakamura Hirofumi

Classifications

• B01J20/08

  comprising aluminium oxide or hydroxide; comprising bauxite · CPC title

• B01J20/20

  comprising free carbon; comprising carbon obtained by carbonising processes · CPC title

• B01J20/103

  comprising silica · CPC title

• B01J20/3236

  containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts · CPC title

• B01D15/206

  Packing or coating · CPC title