Method for removing rare earth impurities from nickel-electroplating solution

Patent metadata

Field	Value
Publication number	US-9695524-B2
Application number	US-201214346058-A
Country	US
Kind code	B2
Filing date	Sep 21, 2012
Priority date	Sep 28, 2011
Publication date	Jul 4, 2017
Grant date	Jul 4, 2017

Abstract

[Object] When rare earth magnets are plated, components of the rare earth magnets are dissolved in the plating solution, causing plating defects. Thus, an easy method for removing rare earth impurities has been necessary.
[Means for Solution] A nickel-electroplating solution containing rare earth impurities is kept at 60° C. or higher for a predetermined period of time to precipitate rare earth impurities for separation by sedimentation or filtration. Rare earth impurities can be precipitated further efficiently by adding precipitate to the nickel-electroplating solution, or by concentrating the nickel-electroplating solution by heating.

First claim

What is claimed is:

1. A method for removing rare earth impurities from a nickel-electroplating solution, consisting essentially of the steps of keeping a nickel-electroplating solution containing rare earth impurities at a temperature of 60° C. or higher for a predetermined period of time such that some components in the nickel-electroplating solution are not precipitated, and then removing precipitate of the rare earth impurities generated by heating from said nickel-electroplating solution by sedimentation and/or filtration.

2. The method for removing rare earth impurities from a nickel-electroplating solution according to claim 1 , wherein said nickel-electroplating solution is stirred during heating.

3. The method for removing rare earth impurities from a nickel-electroplating solution according to claim 2 , wherein said stirring is conducted by air stirring, the rotation of a stirring blade or circulation by a pump.

4. A method for removing rare earth impurities from a nickel-electroplating solution, wherein the operation recited in claim 1 for removing rare earth impurities from a nickel-electroplating solution is repeated plural times, the heating of the nickel-electroplating solution being conducted with precipitate generated by the previous operation existing in the nickel-electroplating solution.

5. The method for removing rare earth impurities from a nickel-electroplating solution according to claim 1 , wherein said nickel-electroplating solution is concentrated by heating.

6. The method for removing rare earth impurities from a nickel-electroplating solution according to claim 5 , wherein said nickel-electroplating solution from which rare earth impurities are removed is up to 3 times as concentrated as a nickel-electroplating solution in which plating is conducted.

7. A method for producing a sintered rare earth magnet having a plating layer, consisting essentially of the steps of preparing a nickel-electroplating solution containing rare earth impurities, keeping said plating solution at 60° C. or higher for a predetermined period of time such that some components in the nickel-electroplating solution are not precipitated, removing precipitate of the rare earth impurities by sedimentation and/or filtration from said nickel-electroplating solution heated for a predetermined period of time, and electroplating the sintered rare earth magnet with nickel in said precipitate-removed nickel-electroplating solution.

Assignees

• Hitachi Metals Ltd

Inventors

• Kamachi Masanao

Classifications

• C25D21/18

  of electrolytes (C25D21/22 takes precedence) · CPC title

• C25D3/12

  of nickel or cobalt · CPC title

• C25D7/001

  Magnets · CPC title

• C25D21/06 Primary

  Filtering {particles other than ions (filtering ions C25D21/22)} · CPC title