Use of dispersions of iron particles as fuel additive

Patent metadata

Field	Value
Publication number	US-9695375-B2
Application number	US-201113996590-A
Country	US
Kind code	B2
Filing date	Dec 19, 2011
Priority date	Dec 22, 2010
Publication date	Jul 4, 2017
Grant date	Jul 4, 2017

Abstract

A fuel additive is formed from dispersions including an organic phase, at least one amphiphlic agent and solid objects based on particles of an iron compound in the crystallized form with a small size, as a fuel additive. The particles have an average size D DRX of less than or equal to 7 nm measured by X-ray diffraction, and at least 80% by number of the particles have a size D MET of less than or equal to 7 nm measured by transmission electron microscopy.

First claim

The invention claimed is:

1. A fuel additive for internal combustion engines, said additive being a dispersion consisting of:
an organic phase;
at least one amphiphilic agent selected from the group consisting of: stearic acid and its isomers, isostearic acid, pelargonic acid, capric acid, lauric acid, myristic acid, dodecylbenzenesulfonic acid, ethyl-2-hexanoic acid and hexoic acid; and
solid objects dispersed in the organic phase, in the form of individualized particles or aggregates of particles, consisting of an iron compound in crystallized form, such that:
said particles have an average size D DRX of less than or equal to 7 nm measured by X-ray diffraction; and
at least 80% by number of said particles have a size D MET of less than or equal to 7 nm measured by transmission electron microscopy.

2. The fuel additive according to claim 1 , wherein the solid objects have a hydrodynamic diameter D h measured by dynamic scattering of light of less than or equal to 30 nm.

3. The fuel additive according to claim 1 , wherein the particles have an average size D DRX of less than or equal to 6 nm.

4. The fuel additive according to claim 1 , wherein the particles have a size D MET of less than or equal to 6 nm.

5. The fuel additive according to claim 1 , wherein the organic phase comprises a polar solvent.

6. The fuel additive according to claim 1 , wherein the organic phase comprises an apolar solvent.

7. A fuel additive for internal combustion engines, said additive being a dispersion comprising:
an organic phase;
at least one amphiphilic agent; and
solid objects dispersed in the organic phase, in the form of individualized particles or aggregates of particles, consisting of an iron compound in crystallized form, such that:
said particles have an average size D DRX of less than or equal to 7 nm measured by X-ray diffraction; and
at least 80% by number of said particles have a size D MET of less than or equal to 7 nm measured by transmission electron microscopy,

wherein the dispersion comprises particles of an iron compound in amorphous form.

8. An additived fuel for internal combustion engines comprising a fuel and a fuel additive for internal combustion engines, said additive being a dispersion comprising:
an organic phase;
at least one amphiphilic agent; and
solid objects dispersed in the organic phase, in the form of individualized particles or aggregates of particles, consisting of an iron compound in crystallized form, such that:
said particles have an average size D DRX of less than or equal to 7 nm measured by X-ray diffraction; and
at least 80% by number of said particles have a size D MET of less than or equal to 7 nm measured by transmission electron microscopy.

9. The additived fuel according to claim 8 , wherein the fuel is selected from the group consisting of gas oils and biofuels.

10. The additived fuel according to claim 8 , wherein the iron content, expressed in ppm by weight of metal iron based on the total weight of said fuel, is comprised from 1 to 30 ppm of metal iron.

11. A method for preparing an additived fuel, wherein the fuel is selected from the group consisting of gas oils and biofuels, comprising a step of contacting and mixing a fuel with the fuel additive for internal combustion engines, said additive being a dispersion comprising:
an organic phase;
at least one amphiphilic agent; and
solid objects dispersed in the organic phase, in the form of individualized particles or aggregates of particles, consisting of an iron compound in crystallized form, such that:
said particles have an average size D DRX of less than or equal to 7 nm measured by X-ray diffraction; and
at least 80% by number of said particles have a size D MET of less than or equal to 7 nm measured by transmission electron microscopy.

12. The fuel additive according to claim 1 , wherein organic phase is an apolar solvent selected from the group consisting of hexane, heptane, octane, nonane, cycloaliphatic hydrocarbons such as cyclohexane, cyclopentane, cycloheptane and petroleum cuts containing isoparaffinic and paraffinic C-11 and C-12 hydrocarbons.

13. The fuel additive according to claim 1 , wherein organic phase is a polar solvent selected from the group consisting of benzene, toluene, ethyl benzene, xylenes, liquid naphthenes, dimethyl benzene, tetraethyl benzene, chloro-benzene, dichloro-benzene, chlorotoluene, diisopropyl ether, dibutyl ether, methylisobutylketone, diisobutylketone, mesityl oxide and 2-ethylhexanol.

14. The fuel additive according to claim 1 , wherein the particles are formed from (γ-Fe 2 O 3 ) or (Fe 3 O 4 ).

15. A fuel additive for internal combustion engines, said additive being a dispersion of particles consisting of:
an organic phase;
at least one amphiphilic agent selected from the group consisting of stearic acid and its isomers, isostearic acid, pelargonic acid, capric acid, lauric acid, myristic acid, dodecylbenzenesulfonic acid, ethyl-2-hexanoic acid and hexoic acid; and
solid objects dispersed in the organic phase, in the form of individualized particles or aggregates of particles, consisting of an iron compound in crystallized form, such that:
said particles have an average size D DRX of less than or equal to 7 nm measured by X-ray diffraction; and
at least 80% by number of said particles have a size D MET of less than or equal to 7 nm measured by transmission electron microscopy,

wherein the dispersion of particles is stabilized by the amphiphilic agent.

16. The fuel additive according to claim 7 , wherein the solid objects have a hydrodynamic diameter D h measured by dynamic scattering of light of less than or equal to 30 nm.

17. The fuel additive according to claim 7 , wherein the particles have an average size D DRX of less than or equal to 6 nm.

18. The fuel additive according to claim 7 , wherein the organic phase comprises an apolar solvent.

19. The fuel additive according to claim 7 , wherein the organic phase comprises a polar solvent.

20. The fuel additive according to claim 7 , wherein the amphiphilic agent is a carboxylic acid including from 10 to 50 carbon atoms.

21. The fuel additive according to claim 7 , wherein the particles are formed from (γ-Fe 2 O 3 ) or (Fe 3 O 4 ).

22. The additived fuel according to claim 8 , wherein the solid objects have a hydrodynamic diameter D h measured by dynamic scattering of light of less than or equal to 30 nm.

23. The additived fuel according to claim 8 , wherein the particles have an average size D DRX of less than or equal to 6 nm.

24. The additived fuel according to claim 8 , wherein the organic phase comprises an apolar solvent.

25. The additived fuel according to claim 8 , wherein the organic phase comprises a polar solvent.

26. The additived fuel according to claim 8 , wherein the amphiphilic agent is a carboxylic acid including from 10 to 50 carbon atoms.

27. The additived fuel according to claim 8 , wherein the particles are formed from (γ-Fe 2 O 3 ) or (Fe 3 O 4 ).

Assignees

• D'Alencon Lauriane
• Lallemand Michael
• Harle Virginie
• Rhodia Operations

Inventors

• D'Alencon Lauriane
• Lallemand Michael
• Harle Virginie

Classifications

• C10L1/1883

  polycarboxylic acid · CPC title

• C10L1/1881

  carboxylic group attached to an aliphatic carbon atom · CPC title

• C10L1/1616

  fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine · CPC title

• C10L1/1608

  Well defined compounds, e.g. hexane, benzene · CPC title

• C10L1/10 Primary

  containing additives · CPC title