Stabilized aqueous water clarifier composition and methods of use

Patent metadata

Field	Value
Publication number	US-9695367-B2
Application number	US-201314423157-A
Country	US
Kind code	B2
Filing date	Aug 20, 2013
Priority date	Aug 27, 2012
Publication date	Jul 4, 2017
Grant date	Jul 4, 2017

Abstract

Oil-water dispersions and emulsions derived from petroleum industry operations are demulsified and clarified using an aqueous water clarifier composition. Formation of such oil-water dispersion and emulsions is inhibited and mitigated using the aqueous water clarifier composition comprising a latex dispersion of an anionic polymer, an alcohol, and a base. The latex dispersion of an anionic polymers comprise an anionic polymer comprising: A) 2-80% by weight of at least one C 3 -C 8 α,β-ethylenically unsaturated carboxylic acid monomer; B) 15-80% by weight of at least one nonionic, copolymerizable α,β-ethylenically unsaturated monomer; C) 0-50% by weight of one or more of the following monomers: C1) at least one nonionic vinyl surfactant ester; or C2) at least one nonionic, copolymerizable α,β-ethylenically unsaturated monomer having longer polymer chains than monomer B), or C3) at least one nonionic urethane monomer; and, optionally, D) 0-5% by weight of at least one crosslinker.

First claim

What is claimed is:

1. An aqueous water clarifier composition comprising:
i) a latex dispersion of an anionic polymer wherein the anionic polymer comprises:
A) at least one C 3 -C 8 α,β-ethylenically unsaturated carboxylic acid monomer;
B) at least one nonionic, copolymerizable α,β-ethylenically unsaturated monomer having the formula:
CH 2 ═CYZ  (II)

where
Y is H and Z is —COOR, —C 6 H 4 R′, CN, Cl,

or —CH═CH 2 ;
Y is CH 3 and Z is —COOR, —C 6 H 4 R′, CN or —CH═CH 2 ; or
Y and Z are Cl; and
R is C 1 -C 8 alkyl or C 2 -C 8 hydroxyalkyl;
R′ is H, Cl, Br, or C 1 -C 3 alkyl; and
R″ is C 1 -C 8 alkyl;

C) optionally, one or more of the following:
1) at least one nonionic vinyl surfactant ester,
2) at least one nonionic, copolymerizable α,β-ethylenically unsaturated monomer having the formula:
CH 2 ═CYZ  (IV)

where Y is H and Z is —COOR, —C 6 H 4 R′, or

 Y is CH 3 and Z is —COOR, —C 6 H 4 R′ and R is C 10 -C 20 alkyl hydroxyalkyl; R′ is C 4 -C 8 alkyl; and R″ is C 9 -C 20 alkyl,

and
3) at least one nonionic urethane monomer; and

D) optionally, at least one crosslinker;

ii) an alcohol;
and
iii) a base,

wherein the aqueous water clarifier composition demonstrates no polymer precipitation or gelling between −40° C. to 60° C. and cycling between −40° C. to 60° C., and wherein:
a) the latex dispersion of an anionic polymer is present in an amount of from 20 to 80 weight percent;
b) the alcohol is present in an amount of from 5 to 70 weight percent;
c) the base present in an amount of greater than 0.05 mmol/g to less than 0.22 mmol/g based on the dry weight of the anionic polymer;
and
d) the balance of the composition is water,
wherein weight percents of a), b), c) and d) total 100 and are based on the total weight of the aqueous water clarifier composition.

2. The composition of claim 1 , wherein the carboxylic acid monomer A) is methacrylic acid, acrylic acid or a mixture thereof and the unsaturated monomer B) is a monovinyl ester.

3. The composition of claim 1 wherein the alcohol is propylene glycol or ethylene glycol.

4. A method for inhibiting and mitigating the formation of oil-water emulsions generated during petroleum industry operations from oil and aqueous precursors which become mixed during said operations, said method comprising providing to the oil precursor, the aqueous precursor, or both, prior to, during or after mixing of the precursors, a demulsifying effective amount of an aqueous water clarifier composition comprising:
i) a latex dispersion of an anionic polymer comprising:
A) at least one C 3 -C 8 α,β-ethylenically unsaturated carboxylic acid monomer;
B) at least one nonionic, copolymerizable α,β-ethylenically unsaturated monomer having the formula:
CH 2 ═CYZ  (II)

where
Y is H and Z is —COOR, —C 6 H 4 R′, CN, Cl,

or —CH═CH 2 ;
Y is CH 3 and Z is —COOR, —C 6 H 4 R′, CN or —CH═CH 2 ; or
Y and Z are Cl; and
R is C 1 -C 8 alkyl or C 2 -C 8 hydroxyalkyl;
R′ is H, Cl, Br, or C 1 -C 3 alkyl; and
R″ is C 1 -C 8 alkyl;

C) optionally, one or more of the following:
1) at least one nonionic vinyl surfactant ester,
2) at least one nonionic, copolymerizable α,β-ethylenically unsaturated monomer having the formula:
CH 2 ═CYZ  (IV)

where Y is H and Z is —COOR, —C 6 H 4 R′, or

Y is CH 3 and Z is —COOR, —C 6 H 4 R′ and R is C 10 -C 20 alkyl hydroxyalkyl; R′ is C 4 -C 8 alkyl; and R″ is C 9 -C 20 alkyl,

and
3) at least one nonionic urethane monomer; and

D) optionally, at least one crosslinker;

ii) an alcohol;
and
iii) a base,

wherein the aqueous water clarifier composition demonstrates no polymer precipitation or gelling between −40° C. to 60° C. and cycling between −40° C. to 60° C., and wherein:
a) the latex dispersion of an anionic polymer is present in an amount of from 20 to 80 weight percent;
b) the alcohol is present in an amount of from 5 to 70 weight percent;
c) the base present in an amount of greater than 0.05 mmol/g to less than 0.22 mmol/g based on the dry weight of the anionic polymer;
and
d) the balance of the composition is water,

wherein weight percents of a), b), c) and d) total 100 and are based on the total weight of the aqueous water clarifier composition.

5. The aqueous water clarifier composition of claim 1 wherein
i) the latex dispersion of an anionic polymer comprises:
A) 15-80% by weight of at least one C 3 -C 8 α,β-ethylenically unsaturated carboxylic acid monomer of the formula:

where R is H, and R′ is H, C 1 -C 4 alkyl, or —CH 2 COOX;
R is —COOX and R′ is H or —CH 2 COOX; or
R is CH 3 and R′ is H; and
X is H or C 1 -C 4 alkyl;
B) 15-80% by weight of at least one nonionic, copolymerizable α,β-ethylenically unsaturated monomer of the formula (II);
and
C) 0-50% by weight of one or more of the following monomers:
1) at least one nonionic vinyl surfactant ester of the formula:

where
R is H or CH 3 , each R′ is C 1 -C 4 alkyl,
R″ is C 8 -C 20 alkyl or C 8 -C 16 alkylphenyl,
n is an average number from 6-100, and m is an average number from about 0-50 provided that n≧m and (n+m) is about 6-100; and
2) at least one nonionic, copolymerizable α,β-ethylenically unsaturated monomer having the formula (IV);
and
3) at least one nonionic urethane monomer which is the urethane reaction product of a monohydric non-ionic surfactant with a monoethylenically unsaturated monoisocyanate

wherein weight percents are based on the total weight of the latex dispersion of an anionic polymer.

6. The method according to claim 4 , wherein the oil-water dispersion or emulsion is an oil in water dispersion or emulsion.

7. The method according to claim 4 , wherein the oil-water dispersion or emulsion is a water in oil dispersion or emulsion.

8. The method according to claim 4 , wherein the aqueous water clarifier composition is provided to the aqueous precursor.

9. The method according to claim 4 , wherein the demulsifying effective amount of the aqueous water clarifier composition is 1 to 10,000 ppm.

Assignees

• Dow Global Technologies Llc

Inventors

• Hoyles Stephen M
• Ayers Callie M

Classifications

• C08K5/05

  Alcohols; Metal alcoholates · CPC title

• C10G33/04 Primary

  with chemical means · CPC title

• C08L33/02

  Homopolymers or copolymers of acids; Metal or ammonium salts thereof · CPC title

• C08K3/22

  of metals · CPC title