Films comprising ethylene-based polymers and methods of making same

Patent metadata

Field	Value
Publication number	US-9695290-B2
Application number	US-201314438044-A
Country	US
Kind code	B2
Filing date	Sep 30, 2013
Priority date	Nov 21, 2012
Publication date	Jul 4, 2017
Grant date	Jul 4, 2017

Abstract

Films including a Layer A comprising 50.0 to 100.0 wt. %, based on the weight of the Layer A, of an ethylene-based polymer composition having therein a hafnium:zirconium (ppm/ppm) ratio >1.0, a CDBI less than 50%, and a g′ vis ≧0.98; wherein the Layer A is substantially free of polyethylene having 0.50≦g′ vis ≦0.85 are described. Particular films are suitable as cast films for TD shrink and draw tape bag applications.

First claim

What is claimed is:

1. A film, comprising:
a Layer A comprising 50.0 to 100.0 wt. %, based on the weight of the Layer A, of an ethylene-based polymer composition, the ethylene-based polymer composition having therein a hafnium:zirconium (ppm/ppm) ratio >1.0, a CDBI<50%, and a g′ vis ≧0.98; wherein the Layer A is substantially free of a polyethylene having 0.50≦g′ vis ≦0.85.

2. The film of claim 1 , wherein the film has a TD shrink of at least 10.0%.

3. The film of claim 1 , wherein the film has a Dart A Impact Strength of 400.0 to 1400.0 g/mil and an MD Elmendorf Tear of 400.0 to 2000.0 g/mil.

4. The film of claim 1 , wherein the hafnium concentration in the ethylene-based polymer composition is <5.0 ppm.

5. The film of claim 1 , wherein the hafnium:zirconium (ppm/ppm) ratio is ≧2.0.

6. The film of claim 1 , wherein the ethylene-based polymer composition has:
i. a melt index of from about 0.1 g/10 min. to about 5.0 g/10 min.;
ii. a melt index ratio of from about 16 to about 30;
iii. a weight average molecular weight (M w ) of from about 2.00×10 4 to about 2.00×10 5 g/mol;
iv. a molecular weight distribution (M w /M n ) of from about 2.0 to about 4.5; and
v. a density of from 0.900 to 0.965 g/cm 3 .

7. The film of claim 1 , wherein the ethylene-based polymer composition has a CDBI 35.0 to 45.0%.

8. The film of claim 1 , wherein the ethylene-based polymer composition has at least a first peak and a second peak in a comonomer distribution analysis.

9. The film of claim 1 , wherein the ethylene-based polymer composition has at least a first peak and a second peak in a comonomer distribution analysis, wherein the first peak has a maximum at a log(M w ) value of 4.0 to 5.4 and a TREF elution temperature of 70.0° C. to 100.0° C. and the second peak has a maximum at a log(M w ) value of 5.0 to 6.0 and a TREF elution temperature of 40.0° C. to 70.0° C.

10. The film of claim 1 , wherein the ethylene-based polymer composition has at least a first peak and a second peak in a comonomer distribution analysis, wherein the first peak has a maximum at a log(M w ) value of 4.3 to 5.0 and a TREF elution temperature of 80.0° C. to 95.0° C. and the second peak has a maximum at a log(M w ) value of 5.3 to 5.7 and a TREF elution temperature of 45.0° C. to 60.0° C.

11. The film of claim 1 , wherein the ethylene-based polymer composition has at least a first peak and a second peak in a comonomer distribution analysis, wherein the first peak has a maximum at a log(M w ) value of 4.5 to 4.7 and a TREF elution temperature of 85.0° C. to 90.0° C. and the second peak has a maximum at a log(M w ) value of 5.4 to 5.6 and a TREF elution temperature of 48.0° C. to 54.0° C.

12. The film of claim 1 , wherein the film has a Dart A Impact Strength of 850 to about 1100 g/mil and an average of the MD and TD 1% Secant Moduli >35.0 kpsi.

13. The film of claim 1 , wherein the polyethylene has 0.60≦g′ vis ≦0.80.

14. The film of claim 1 , wherein the polyethylene is a polyethylene formed by a high-pressure process.

15. The film of claim 1 , wherein the Layer A is substantially free of one or more of:
a) a heterogeneously branched linear polyethylene having a g′ vis ≧0.98, preferably 0.99 or above;
b) an ethylene copolymer comprising ≧50.0 wt. % ethylene-derived units and ≦50.0 wt. % of a C 3 to C 20 comonomer-derived units, based upon the weight of the copolymer, a CDBI of 60% or more, and density of 0.910 to 0.950 g/cm 3 ; and
c) an ethylene copolymer comprising units derived from ethylene and at least one alpha olefin having at least 5 carbon atoms, having a Melt Index of from 0.1 to 15; a CDBI of at least 70%, and a density of from 0.910 to 0.930 g/cm 3 .

16. The film of claim 1 , wherein the film is a blown, cast or coextruded film.

17. The film of claim 1 , wherein the film is a cast film.

18. The film of claim 1 , wherein the film is a monolayer film.

19. The film of claim 1 , further comprising a Layer B in surface contact with a first side of Layer A; and Layer C in surface contact with a second side of Layer A.

20. A method of increasing TD shrink, the method comprising:
a) providing a polyethylene composition comprising 50.0 to 100.0 wt. % of an ethylene-based polymer, the ethylene-based polymer composition having a hafnium:zirconium (ppm/ppm) ratio >1.0, a CDBI less than 50%, and a g′ vis ≧0.98; and 0 to 50.0 wt. % of a second ethylene-based polymer, the second ethylene-based polymer composition having a hafnium:zirconium (ppm/ppm) ratio <1.0 and a g′ vis ≧0.98; all wt. % values based on the weight of the composition;
b) forming the polyethylene composition into a film; and
c) orienting the film in at least the transverse direction;
wherein the film has a TD shrink at least 10% greater than the TD shrink of a reference film, the reference film consisting essentially of the second ethylene-based polymer.

21. The method of claim 20 , wherein the polyethylene composition comprises 90.0 to 100.0 wt. %, of the ethylene-based polymer.

22. The method of claim 21 , wherein the film consists essentially of the ethylene-based polymer.

23. A film, consisting essentially of:
a) a Layer A comprising 90.0 to 100.0 wt. %, based on the weight of the film, of an ethylene-based polymer, the ethylene-based polymer composition having a hafnium:zirconium (ppm/ppm) ratio >1.0, a CDBI less than 50%, a density of 0.940 to 0.965 g/cm 3 , a melt index of 3.0 to 5.0 g/10 min., and a g′ vis ≧0.98; wherein the film is substantially free of a polyethylene having 0.50≦g′ vis ≦0.85, wherein the film has a TD shrink of at least 10.0% greater than a reference film consisting essentially of a second ethylene-based polymer, the second ethylene-based polymer composition having a hafnium:zirconium (ppm/ppm) ratio <1.0 and a g′ vis ≧0.98.

24. The film of claim 23 , wherein the film is a cast film.

25. A cast film, consisting essentially of:
a) a Layer A comprising 90.0 to 100.0 wt. %, based on the weight of the film of an ethylene-based polymer, the ethylene-based polymer composition having a hafnium:zirconium (ppm/ppm) ratio >1.0, a CDBI less than 50%, and a g′ vis ≧0.98; wherein the film is substantially free of a polyethylene having 0.50≦g′ vis ≦0.85, and wherein the film has a Dart A Impact Strength of 400.0 to 1400.0 g/mil and an MD Elmendorf Tear of 400.0 to 2000.0 g/mil.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Malakoff Alan M

Classifications

• B32B2307/54

  Yield strength; Tensile strength · CPC title

• B32B2439/46

  Bags · CPC title

• B32B2307/558

  Impact strength, toughness · CPC title

• C08F2500/05

  Bimodal or multimodal molecular weight distribution · CPC title

• C08F210/14

  Monomers containing five or more carbon atoms · CPC title